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11.
The first α‐diimine nickel(I) complex having a chloro bridge is reported. The centrosymmetric dinuclear structure of {[ArN?C(Me)C(Me)?NAr]NiCl}2[Ar?2,6?C6H3(i‐Pr)2] features two chelating α‐diimine ligands and two bridged chlorine atoms, so that a distorted tetrahedral N2Cl2 coordination geometry for nickel results. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
12.
Jihua Zhang Xi WangWeidong Yu Tao FengFumin Zhang Zhihong ZhengQiong Li Xianghuai Liu 《Solid State Communications》2003,127(4):289-293
Effects of ion impinging on the microstructure and field electron emission properties of screen-printed carbon nanotube films were investigated. We observed that the plasma treatment modified the microstructure of CNTs along with the remarkable increase of emission site density. With the prolongation of ion impinging time, the emission current falls down first, and then rises up to higher than that of the untreated films. It is proposed that the change of emission characteristics is due to the different emission mechanisms. After the treatment, electrons are emitted predominantly from the nano-nodes on the tube wall instead from the nanotube tips. 相似文献
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15.
Guobao Zhang Jianming Zhang Shenguo Wang Deyan Shen 《Journal of Polymer Science.Polymer Physics》2003,41(1):23-30
Blends of amorphous poly(DL‐lactide) (DL‐PLA) and crystalline poly(L‐lactide) (PLLA) with poly(methyl methacrylate) (PMMA) were prepared by both solution/precipitation and solution‐casting film methods. The miscibility, crystallization behavior, and component interaction of these blends were examined by differential scanning calorimetry. Only one glass‐transition temperature (Tg) was found in the DL‐PLA/PMMA solution/precipitation blends, indicating miscibility in this system. Two isolated Tg's appeared in the DL‐PLA/PMMA solution‐casting film blends, suggesting two segregated phases in the blend system, but evidence showed that two components were partially miscible. In the PLLA/PMMA blend, the crystallization of PLLA was greatly restricted by amorphous PMMA. Once the thermal history of the blend was destroyed, PLLA and PMMA were miscible. The Tg composition relationship for both DL‐PLA/PMMA and PLLA/PMMA miscible systems obeyed the Gordon–Taylor equation. Experiment results indicated that there is no more favorable trend of DL‐PLA to form miscible blends with PMMA than PLLA when PLLA is in the amorphous state. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 23–30, 2003 相似文献
16.
激光晶体YAG中Er3+的辐射跃迁 总被引:2,自引:0,他引:2
本文讨论和分析了激光晶体YAG中Er3+离子的激光上能级的4S3/2、4I11/2和4I13/2辐射跃迁的有关因素。 相似文献
17.
J.J. Pan Xiangdong Qiu Kejian Guan Liang Dong FengQing Zhou Wei Wang Mingjie Zhang James Guo Jun Yang Chunmeng Wu 《光学学报》2003,23(Z1)
A low cost, coolerless 980nm diode pumped, gain flattened L band EDFA with fast transient control, high pump efficiency and gain clamping effect was realized by using FBGs as C band seed generators. 相似文献
18.
A method for fabricating well-dispersed nanowire suspension has been demonstrated in the paper. Thin gold nanowires were prepared by template synthesis, and then functionalized with sulphonate group-terminated thiols before suspended in different solvents. The degree of aggregation of the obtained suspension was evaluated with transmission electron microscopy (TEM) and UV-vis spectroscopy. It was found that the degree of aggregation was predominated by the solvents, and the best degree of dispersion was obtained when isopropyl alcohol (IPA) was used as the solvent. The gold nanowires from the suspension can be selectively assembled onto chemically patterned substrates. This well-dispersed nanowire suspension is potentially useful for fabricating novel nanodevices. 相似文献
19.
A novel and simple two-frequency Brillouin fiber laser is presented. It is based on a fiber Fabry-Perot cavity with fiber Bragg gratings as reflectors. The model of stimulated Brillouin scattering in fiber grating-based Fabry-Perot resonator is investigated. The laser allows conversion efficiency of close to 100% and suppresses the higher-order Stokes waves. The theoretical prediction is presented and the experimental demonstration is realized. 相似文献
20.
Aiqing Zhang Xiangdan Li Changwoon Nah Keejun Hwang Myong‐Hoon Lee 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):22-29
A soluble aromatic polyimide was chloromethylated via a reaction with chloromethyl methyl ether in the presence of tin(IV) chloride to produce a new starting material for the modification of aromatic polyimides. The chemical structure of the resulting polymer was confirmed by 1H NMR and Fourier transform infrared spectroscopy. The maximum number of chloromethyl groups per repeat unit was 1.81. The chloromethylated polyimide was stable up to 250 °C and soluble in both chloroform and tetrahydrofuran. So that its utilization for further modification could be demonstrated, cinnamic acid was reacted with the formed polyimide, and it produced a new photosensitive polyimide with a cinnamoyl side chain. The photosensitivity of the resulting polyimide was investigated with ultraviolet spectroscopic methods. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 22–29, 2003 相似文献