化学气相沉积法制备Zn2GeO4纳米线及其发光性质的研究

利用化学气相沉积法（CVD）,气-液-固（VLS）生长法则在表面溅有金属Au催化剂层的1 cm×1 cm的Si片上制备三元Zn₂GeO₄纳米线。X射线衍射仪（XRD）测试结果表明,锌源与锗源质量比为8：1时可成功制备出Zn₂GeO₄纳米结构;扫描电子显微镜（SEM）测试结果表明,Zn₂GeO₄纳米线直径为100 nm,长度为10~11 μm;光致发光（PL）测试结果表明,Zn₂GeO₄纳米线在432和480 nm处具有两个发光峰,最后对其生长机理进行了分析。     

High-temperature impedance spectroscopy of BaFe0.5Nb0.5O3 ceramics doped with Bi0.5Na0.5TiO3

Bi_0.5Na_0.5TiO₃ (BNT)-doped BaFe_0.5Nb_0.5O₃ (BFN) ceramics were synthesized by a two-step solid-state reaction. Temperature dependence of dielectric properties measured at different frequencies was investigated over broad temperature and frequency ranges. Impedance spectroscopy and universal dielectric response were employed to study the relaxation behavior and conductivity mechanism of the ceramics in a frequency range from 40 Hz to 100 MHz and a temperature range from 300 K to 800 K. The complex plane impedance data revealed the bulk and grain boundary contributions toward conductivity processes in the form of semicircular arcs. The high-temperature conductivity of ceramics is attributable to thermally activated second ionized oxygen vacancy.     

使用PTB7作为阳极修饰层提高有机发光二极管的性能

采用poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b’]dithiophene-2,6-diyl][3-?uoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]](PTB7)作为有机发光二极管器件的阳极修饰层,制备了结构为indium tin oxide(ITO)/PTB7(不同浓度)/N,N’-Bis(naphthalen-1-yl)-N,N’-bis(phenyl)benzidine(NPB,40 nm)/8-hydroxyquinoline(Alq3,60 nm)/LiF(1 nm)/Al的系列器件,同时研究了不同浓度的PTB7对器件性能的影响.PTB7的最佳浓度为0.25 mg/mL,器件性能得到明显的改善,起亮电压为4.3 V.当驱动电压为14.6 V时,最大亮度为45800 cd/m2,最大电流效率为9.1 cd/A.与没有PTB7修饰的器件相比,其起亮电压降低了1.9 V,最高亮度提升了78.5%.器件性能提高归因于PTB7的插入使得空穴注入和传输能力大大改善.     

Robust scheme for implemention of quantum phase gates for two atoms

We propose a scheme for implementing conditional quantum phase gates for two four-state atoms trapped in a cavity. The two ground states of the atoms are coupled through two Raman processes induced by the cavity mode and two classical fields. Under certain conditions nonresonant Raman processes lead to two-atom coupling and can be used to produce conditional phase gates. The scheme is insensitive to cavity decay, thermal photons, and atomic spontaneous emission. The scheme does not require individual addressing of the atoms.     

一种新型微结构光纤的设计与数值研究

提出了一种新型双包层结构的微结构光纤(MOF),利用有限元法对其模场面积、损耗及色散系数随波长的变化规律进行了数值模拟与分析,并在相同条件下与传统的双包层MOF作了比较。结果表明,该种光纤不但结构新颖,而且较传统光纤有更优异的色散性能。通过合理优化,设计了几种在500nm波长范围内保持低平色散和较大模场面积的新型双包层MOF。这种光纤结构的提出对以后的理论研究和工艺制备具有一定的参考意义。     

Simulation of water potential for the electronic structureof serine

First-principles, all-electron, \textit{ab initio} calculations have been performed to construct an equivalent water potential for the electronic structure of serine (Ser) in solution. The calculation is composed of three steps. The first step is to search for the configuration of the Ser + NH₂O system with a minimum energy. The second step is to calculate the electronic structure of Ser with the water molecule potential via the self-consistent cluster-embedding method (SCCE), based on the result obtained in the first step. The last step is to calculate the electronic structure of Ser with the dipole potential after replacing the water molecules with dipoles. The results show that the occupied states of Ser are raised by about 0.017~Ry on average due to the effect of water. The water effect can be successfully simulated by using the dipole potential. The obtained equivalent potential can be applied directly to the electronic structure calculation of protein in solution by using the SCCE method.     

Microwave dielectric and magnetic properties of superparamagnetic 8-nm Fe3O4 nanoparticles

The superparamagnetic 8-nm Fe₃O₄ nanoparticles were successfully prepared by chemical oxidation process. For the complex permittivity, the dual dielectric relaxation processes have been proved by two overlapped Cole–Cole semicircles, and the natural resonance frequency is 3.03 GHz for the complex permeability. The maximum reflection loss value reaches −55.5 dB at 6.11 GHz with 3.85 mm in the thickness of the absorbers for the superparamagnetic 8-nm Fe₃O₄ nanoparticles which is better than that of 150 nm and 30 nm Fe₃O₄ nanoparticles. It is believed that the superparamagnetic 8-nm Fe₃O₄ nanoparticles can be used as a kind of candidate for microwave absorber.     

Incoherently coupled Hermite-Gaussian breather and soliton pairs in strongly nonlocal nonlinear media

We theoretically investigate the propagation of incoherently coupled Hermite-Gaussian breather and soliton pairs in strongly nonlocal nonlinear media. It is found that multipole-mode soliton pairs with arbitrary different orders of Hermite-Gaussian shape can exist when the total power of two beams equals the critical power and the ratio of the beam widths for the Gaussian part is inversely proportional to the square root of the ratio of the wave numbers. When the total power does not equal the critical power, the Hermite-Gaussian breather pair exists and their beam widths evolve analogously. For general cases where the ratio of the beam widths is arbitrary, soliton-breather pairs or breather-breather pairs can be formed and their beam widths evolve synchronously in-phase or out-of-phase. Numerical simulations directly based on the nonlocal nonlinear Schrödinger equation are conducted for comparison with our theoretical predictions. The numerical stability analysis shows the higher-order Hermite-Gaussian solitons can not be stable for small nonlocality or for some media like liquid crystals.     

雷达回波资料反演海洋波导中观测值权重的确定

提出采用一种与电磁波传播损耗相类似的指数衰减形式来描绘观测值权重随距离的变化,结合标准的统计反演算法来测试不同的观测值权值对反演速度与精度的影响.结果表明,指数衰减形式能较好地描绘观测值权值随距离的变化情况;其中衰减指数的选取是关键.合理地选取衰减指数可较好地改进反演的速度与精度.对于不同频率的电磁波,最优衰减指数是各不相同的. 关键词： 海洋波导 观测值权重 衰减指数 反演算法     

Accuracy analysis and stabilization design of the Fabry–Perot frequency discriminator in double-edge wind lidars

The measurement error of a double-edge wind lidar caused by a disturbed Fabry–Perot interferometer (FPI) is analyzed. Several error sources such as air pressure variations, temperature changes, and mechanical vibrations are considered in the measurement-error model. The simulation results show that a double-edge wind lidar is so sensitive to environmental variations that the measurement error reaches ±60 m/s if the FPI is not stabilized. In order to compensate the external disturbance acting on the FPI, a nonlinear proportional–integral–derivative (PID) control scheme is designed based on the transmission measurement of the calibration channel. An arc tangent function is used to improve the feedback gain of the usual PID control design. The results show that with the new controller the measurement accuracy of the wind lidar can be improved 4–5 times in comparison with the usual control design, and the range of the measurement error is only ±3 m/s.