Sorption equilibria of CO2 on silica-gels in the presence of water

The sorption equilibria of carbon dioxide on three types of silica gel (SG) with different pore size distributions in the presence of water were studied experimentally using a volumetric method at 275?K with pressures from 0 to 3.7?MPa. Both the pore size distribution of the silica gel and the quantity of pre-sorbed water impact the formation of the CO₂ hydrates. For wet silicon gel A(SG-A) with water loading ratio of 0.75, the highest CO₂ sorption was about 2.5?mmol of CO₂ per gram of dry sorbent at 275?K. Similarly, the highest sorption was about 2.7?mmol for wet SG-B with R _w =0.81. However, CO₂ hydrate did not form on the wet surface of SG-C due to its large pore sizes.     

Interlayer shear strength of single crystalline graphite

Reported values(0.2 MPa-7.0 GPa) of the interlayer shear strength(ISS) of graphite are very dispersed.The main challenge to obtain a reliable value of the ISS using conventional measuring methods was the unavailability of sufficiently large single crystalline graphite.Here we present a novel experimental method to measure the ISS,and obtain the value as ～0.14 GPa.Our result can serve as an important basis for understanding mechanical behavior of graphite or graphene-based materials.     

Study of the structural relaxation and crystallization in amorphous Fe80P20 alloy by mössbauer effect

The structural relaxation and crystallization of amorphous Fe₈₀P₂₀ alloys have been investigated by Mössbauer spectroscopy. The result indicates that the process of the crystallization of Fe₈₀P₂₀ makes slow progress and it was occur from outside into inside. The amorphous alloys may be classified into six different stages from amorphous to crystalline state during annealing.     

光学变换中的离散取样方法

本文研究了光学变换中的离散取样问题。基于幺正变换的考虑,求得了光学变换中离散取样方法所依据的条件。导出了包含取样单元透光孔作用的光传播矩阵。最后,以自然序Walsh变换为例,具体计算了变换所需全息透镜的振幅与相位分布及相应的误差。 关键词：