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41.
The clusters of Eu3+ ion in Eu(DBM)3Phen-doped polymethyl methacrylate (PMMA) have been studied by three means. The relative fluorescence intensity ratio of the 5D0 → 7F2 to 5D0 → 7F1 transitions with different concentrations of Eu3+ in Eu(DBM)3Phen-doped PMMA and metastable-state (5D0) lifetime dependence on Eu3+ concentration are analyzed. The analysis indicates that there are no clustering effects in Eu3+ ions of Eu(DBM)3Phen-doped PMMA when the Eu3+ doping concentration is up to 1.0 wt.-%. At the same time, the clustering effect has not been observed by the scanning near-field optical microscopy (SNOM) in Eu(DBM)3Phen-doped PMMA with 1.0 wt.-% of Eu3+ ions. The analysis reveals that a high concentration of Eu3+ can be incorporated into polymer optical fiber (POF) without clustering effect.OCIS codes: 180.5810, 300.6280, 250.5460, 160.5690. 相似文献
42.
The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
43.
A series of 4,6-disubstituted pyrimidines were synthesized via Suzuki and Kumada coupling reaction of 4,6-dichloropyrimidine. 相似文献
44.
Zheng Yu 《manuscripta mathematica》2003,111(2):163-186
In this paper, the negative gradient flow for the L
2-integral of Ricci curvature on a 3-manifold is considered. It is not known whether the solution to this fourth order geometric
evolution equation exists, and whether it will develop singularities in finite time. Based on the trick of De Turck and the
idea of Hamilton on the flow of Ricci curvature, the local existence on any compact Riemannian manifold is obtained. In addition,
the conditions for the occurences of singularities in finite time during the evolution and the asymptotic behavior of the
flow on a 3-manifold are discussed.
Received: 22 April 2002 / Revised version: 5 January 2003
Published online: 24 April 2003
This work is partially supported by the Foundations of NNSF of China, the Foundation for University Key Teacher by MEC and
Shanghai Priority Academic Discipline. 相似文献
45.
本在Glover—Klingman算法及最小费用支撑树对策的基础上,讨论了最小费用k度限制树对策问题.利用威胁、旁支付理论制订了两种规则,并利用优超、策略等价理论分别给出了在这两种规则下最小费用k度限制树对策核心中的解,从而证明了在这两种规则下其核心非空. 相似文献
46.
Jin Sun Yihu Song Qiang Zheng Hong Tan Jie Yu Hong Li 《Journal of Polymer Science.Polymer Physics》2007,45(18):2594-2602
The reinforcement and nonlinear viscoelastic behavior have been investigated for silica (SiO2) filled solution‐polymerized styrene butadiene rubber (SSBR). Experimental results reveal that the nonlinear viscoelastic behavior of the filled rubber is similar to that of unfilled SSBR, which is inconsistent with the general concept that this characteristic comes from the breakdown and reformation of the filler network. It is interesting that the curves of either dynamic storage modulus (G′) or loss tangent (tan δ) versus strain amplitude (γ) for the filled rubber can be superposed, respectively, on those for the unfilled one, suggesting that the primary mechanism for the Payne effect is mainly involved in the nature of the entanglement network in rubbery matrix. It is believed there exists a cooperation between the breakdown and reformation of the filler network and the molecular disentanglement, resulting in enhancing the Payne effect and improving the mechanical hysteresis at high strain amplitudes. Moreover, the vertical and the horizontal shift factors for constructing the master curves could be well understood on the basis of the reinforcement factor f(φ) and the strain amplification factor A(φ), respectively. The surface modification of SiO2 causes a decrease in f(φ), which is ascribed to weakeness of the filler–filler interaction and improvement of the filler dispersion. However, the surface nature of SiO2 hardly affects A(φ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2594‐2602, 2007 相似文献
47.
THE SCHWARZIAN DERIVATIVE IN SEVERAL COMPLEX VARIABLES(II) 总被引:1,自引:0,他引:1
THESCHWARZIANDERIVATIVEINSEVERALCOMPLEXVARIABLES(II)GONGSHENGYUQIHUANGZHENGXUEANManuscriptreceivedAugust30,1996.De... 相似文献
48.
Dao-sheng Zheng 《计算数学(英文版)》1998,(2)
1.IntroductionSince1984,severalchinesemathematicianshaveobtailledmanyresultsboutmatrixoperatornormcondition.umbe.[ll'12'18].Twokindsmatrixconditionnllmbers[9]are:(1)IfAECoxsisnonsingular,thellunlberK.(A)~IIAll.llA--'if.iscalledtheor--normconditionnumberof… 相似文献
49.
Wei‐Lie Xiao Jian‐Xin Pu Rui‐Rui Wang Liu‐Meng Yang Xiao‐Li Li Sheng‐Hong Li Rong‐Tao Li Sheng‐Xiong Huang Yong‐Tang Zheng Han‐Dong Sun 《Helvetica chimica acta》2007,90(8):1505-1513
Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1. 相似文献
50.
如果一个图G存在一个k-列表安排使得G具有一个唯一列表染色,则称 G是唯一列表可染色图,简称UkLC图.我们称图G具有M(k)性质当且仅当G不 是UkLC图.本文在借鉴θr,s,t-图概念的基础上引入θr,s,t-图的定义,并证明:除了 r=s=t=2以外,θr,s,t-图都是U2LC图.利用如上结果我们给出M.Mahdian and E.S.Mahmoodian对U2LC图所作特征化的一个简单证明. 相似文献