平行板静电场法离子引出的对称收集

离子引出的研究在AVLIS工程中有重要的意义，离子引出量和引出时间直接关系到整个系统 的离子收集效率. 在静电场中，由于等离子体屏蔽效应的存在，等离子体电位要高于正、负 极板的电位，而且在靠近正、负极板的两侧均存在鞘层. 理论模拟表明在正极板一边也可以 引出离子. 选取铯（Cs）作为实验对象，研究静电场对Cs等离子体的离子引出，使用安装在 两个极板上的法拉第筒收集离子引出信号. 实验结果表明，正极板确实可以引出离子，随着 外加电压的升高，从正极板一边引出离子的比率降低. 关键词： AVLIS 离子引出 等离子体     

Ferrocenecarbaldehyde isonicotinyl hydrazide

The chiral structure of ferrocenecarbaldehyde isonicotinyl hydrazide, [Fe(η⁵‐C₅H₅)(η⁵‐C₁₂H₁₀N₃O)], shows the molecule exhibits an E configuration, has a CN bond length of 1.284(4) Å and an N N bond length of 1.388(3) Å. Copyright © 2004 John Wiley & Sons, Ltd.     

Crystallographic report: Crystal structure of a two‐dimensional coordination polymer: tetraaqua‐1,2,4,5‐benzenetetracarboxylato(pyrazine)dizinc(II) dihydrate

The structure of {[Zn₂(1,2,4,5‐btc)(pz)(H₂O)₄]·2(H₂O)}_n (1,2,4,5‐btc = 1, 2, 4, 5‐benzenetetracarboxylate, pz = pyrazine) is a two‐dimensional coordination network. The zinc(II) center is in a distorted octahedral NO₅ coordination environment that is defined by one nitrogen atom of pyrazine, three oxygen atoms of carboxyl groups from 1,2,4,5‐benzenetetracarboxylate tetraanions and two water molecules. Copyright © 2003 John Wiley & Sons, Ltd.     

二阶中立型逐段常变量微分方程概周期解的存在性

通过构造差分方程的概周期序列解,研究了二阶中立型逐段常变量微分方程 d²/dt²(x(t)+px(t-1))=qx(2[t+1/2])+g(t,x(t),x([t]))概周期解的存在性.     

Efficient Amide Based Halogenide Anion Receptors

In this paper, we present the synthesis and anion recognition properties of the amide based phenanthroline derivatives 1, 2 and 3. In all cases 1:1 receptor : anion complexes were observed. The receptors were found to be selective for fluoride and chloride respectively over other putative anionic guest species.     

醋酸乙烯酯种子乳液聚合动力学研究

用装有红外跟踪器和计算机记录监控系统的膨胀计进行了醋酸乙烯酯的种子乳液聚合。聚合直接从乳液聚合的阶段Ⅱ开始，避开了复杂的成核阶段和成核阶段粒度变化对动力学参数的影响。在引发剂浓度５．０３０×１０＾－５￣１．００２×１０＾－３ｍｏｌ／Ｌ范围内，依据转化率随时间的变化关系，求出了准稳态聚合速率、自由基进入乳胶粒子的速率、自由基从乳胶粒子解吸的速率和ｋｐｎ＾－。结果表明：聚合速率、自由基进入乳胶粒子的速     

序Banach空间中一类算子方程的可解性

利用改进的Mnch紧性条件,研究了一类算子方程Lx=Nx的解的存在性．本文结果并没有要求算子L和N的连续性．作为应用,讨论了右端项不连续的隐式椭圆偏微分方程的边值问题的解的存在性．     

Fish otolith trace element maps: new approaches with synchrotron microbeam x‐ray fluorescence

Otoliths, the carbonate earstones of fishes, take up minor and trace amounts of elements as they accrete through a fish's life. We apply synchrotron microbeam x‐ray fluorescence methods to establish a breakthrough in high‐resolution, simultaneous area mapping of multiple trace elements in otoliths, with spatial resolution down to 20 µm and trace element detection down into the part per million range for multiple elements. Concentration maps of Ca, Sr, Zn and, for the first time, Ba, Mn, and Se are obtained simultaneously. Combinations of these elemental maps provide new insights into the environmental history of fishes and their lifetime movements, illustrated by several case studies. This method helps pave the way toward improved spatial analysis of otolith microchemistry. Copyright © 2007 John Wiley & Sons, Ltd.     

Synthesis,Spectroscopic Characterization and Antitumor Activity in vitro of Organometallo Substituted Polyoxotungstates（RM）3P2W15—O59^n—（RM=CpTi,CpZr,C4H7O2Sn or C5H9O2Sn）

Tetrabutylammonium or potassium salts of organometalllic derivatives of lacunary polyanion (RM)3P2W15O59^n-(RM=CpTi,CpZr,C4H7O2Sn or C5H9O2Sn) have been prepared and structurally characterized by elemental analysis,IR,UV-Vis,^1H NMR and^183 W NMR spectroscopies.The title complexes exhibit antitumor activity in vitro.     

Set-valued increasing-along-rays maps and well-posed set-valued star-shaped optimization

In this paper we introduce a class of set-valued increasing-along-rays maps and present some properties of set-valued increasing-along-rays maps. We show that the increasing-along-rays property of a set-valued map is close related to the corresponding set-valued star-shaped optimization. By means of increasing-along-rays property, we investigate stability and well-posedness of set-valued star-shaped optimization.