眼模型下的投影式头盔物镜设计及视空间评价

进一步完善了投影式头盔系统的视空间评价方法,应用接近实际情况的眼模型来模拟人眼对头盔物镜系统进行评价。由视空间的评价结果出发,从眼模型的成像效果反过来进一步指导头盔系统的设计工作。设计结果显示,轴上视场和大视场的调制传递函数特性良好,在轴上视场可以达到1′的人眼最小分辨角,在大视场可以达到微显示器单个像素确定的视锐度,表明此系统在视空间的分辨力满足实际使用需要。系统最大畸变小于5%,色差不会对人眼分辨产生影响。     

新型吡啶环液晶化合物的合成及性能

以2-溴-5-吡啶甲醛和5-溴-2-吡啶甲醛为起始原料,合成出4种新型含吡啶环二联芳基和三联芳基化合物,总收率20%~30%。 热性能研究结果表明,二联芳基化合物未呈现出液晶相,而三联芳基化合物在加热和冷却过程中均表现向列相液晶态,且当氮原子位于正丁基的间位时,其与不含氮原子的三联苯化合物(2c)相比,熔点降低了11.7 ℃,清亮点升高6.3 ℃,液晶相区拓宽了18 ℃,表现出了良好的热性能。 光电性能测试结果表明,用吡啶环替代苯环后,化合物的光学各向异性值均较参比化合物(1c或2c)增大;当N原子位于正丁基的邻位的化合物,介电各向异性值较参比化合物增大,且液晶的阈值电压、饱和电压均降低。 通过对三环同分异构体化合物的不同构象能量态的计算分析,解释了介电各向异性的变化规律。     

Design and synthesis of catenated rings based on toroidal DNA structures

Strand proximity and self-crossing that occur intrinsically in the relaxed forms of toroidal DNA are utilized unprecedentedly in our investigations for creating catenated DNA rings. In addition, our current studies show that the geometrical shapes of our newly obtained catenated DNA circles as well as their topological arrangements are vividly visible under atomic force microscopic examination.     

彩色编码投影光栅三维轮廓术中分色问题的研究

针对彩色编码投影栅三维轮廊术所需的分色技术要求,根据光度学的原理,提出了一种由RGB格式到HIS格式的变换关系,同时给出了逆变换关系式,亮度I定义为R,G,B三个分量的平均值,白度S定义为R,G,B三个分量中最小的分量除以亮度值。用R．G．B三个分量中的最小值去减另外两个分量,得到该像素所对应的光谱色,然后由这两个分量的比值来确定色度H。在HIS格式中将亮度与颜色信息分离开,在进行分色处理时可以不受亮度变化的影响,通过设定固定的阈值,可以将红,绿,蓝,青,品,黄几种颜色有效地区分开来。     

Characterizations of perturbations of spectra of 2×2 upper triangular operator matrices

When $A\in B\left(H\right)$ and $B\in B\left(K\right)$ are given, we denote by $M_C$ the operator acting on the infinite dimensional separable Hilbert space $H\oplus K$ of the form $M_C=\left(\begin{array}{cc}\hfill A\hfill & \hfill C\hfill \\ \hfill 0\hfill & \hfill B\hfill \end{array}\right)$. In this paper, we first give some necessary and sufficient conditions for $M_C$ to be a left invertible operator (an upper semi-Weyl, upper semi-Fredholm) operator for some $C\in B(K,H)$, which extend the corresponding results in Cao et al. (2006) [4], Cao and Meng (2005) [5], Hwang and Lee (2001) [12] and Li and Du (2006) [15]. Then we present some counter-examples.     

Ce:KNSBN光折变类光纤简并四波混频特性研究

研究了Ce:KNSBN光折变类光纤在泵浦光和信号光夹角分别为小角度和大角度两种情况下简并四波混频的基本特性.当夹角较大时,在光折变类光纤内部形成了两个四波混频作用区域,获得了比小角度情况提高4倍的大相位共轭反射率.给出了Ce:KNSBN光折变类光纤中,在入射夹角分别为小角度和大角度两种情况下,相位共轭光反射率分别随信号光光强、两束泵浦光光强比变化的实验结果,并用理论公式进行了拟合,理论分析和实验结果相符.还研究了Ce:KNSBN光折变类光纤四波混频光栅模式和相位共轭光时间响应特性.光折变类光纤的相位共轭响应时间较快,可为秒量级.     

Solid-phase microextraction combined with gas chromatography/triple quadrupole tandem mass spectrometry for determination of nitrated polycyclic aromatic hydrocarbons in sediments

Nitro-polycyclic aromatic hydrocarbons have been detected in various environmental media. However, determination in sediment matrix is challenging due to the lack of a suitable method. In this study, a reliable method for determining 15 nitro-polycyclic aromatic hydrocarbons in sediments was developed based on accelerated solvent extraction and solid-phase microextraction coupled with gas chromatography–tandem mass spectrometry. The accelerated solvent extraction and solid-phase microextraction are sample pre-treatment techniques that have advantages, such as rapid operation and minimal sample volume. Initially, the solid-phase microextraction was optimized using five commercial fibers and from that 65 μm polydimethylsiloxane/divinylbenzene fiber was selected as the best fiber. Further, the accelerated solvent extraction conditions were optimized by Taguchi experimental design, such as extraction temperature (120℃), extraction solvent (dichloromethane), number of cycles (two), static extraction period (4 min), and rinse volume (90%). The method parameters, such as limits of quantitation, and intraday and interday accuracy and precision, were in the range of 0.067–1.57 ng/g, 75.2–115.2%, 69.9–115.4%, and 1.0–16.5%, respectively. Upon meeting all the quality criteria, the method was applied successfully to analyze real sediment samples. Therefore, our study creates a new prospect for the future application of direct immersion solid-phase microextraction in sediment analysis.     

以2,2,5,5-四氟-2,5-二氢呋喃桥连的1,2-二噻吩乙烯类光致变色分子的合成

设计并合成了新型的以2,2,5,5-四氟-2,5-二氢呋喃桥连的1,2-二噻吩乙烯类光致变色分子1,从廉价易得的六氯丁二烯出发,经醇解、氯化、关环和氟化反应合成了关键中间体全氟2,5-二氢呋喃(2),并通过与化合物3'-溴-[2,2':5',2']三噻吩(3)的偶合反应得到含氟光致变色分子1.     

折/衍混合微光夜视头盔显示器光学系统设计

设计了穿透式双通道单目微光夜视头盔的光学系统。其中微光物镜视场角为± 14°,f数为 1.4 ,含有一个衍射面。设计结果可兼容输入面尺寸为18mm ,面型为平面的二代和三代微光像增强器 ;最大畸变小于 0 .5 % ,可用于夜间精确瞄准与测量。考虑黑暗环境使用的安全问题 ,显示系统采用穿透式双通道单目光学系统 ,实现内部图像和外部真实世界的同时观察。显示系统的特性参量为 :出瞳尺寸为 15mm (H)× 10mm (V)、视场为[± 14°(H) ]× [± 10° (V) ]、出瞳距离为 2 5mm。采用全息组合器大大提高能量利用率。设计结果系统角分辨力为0 .6mrad ,最大畸变为 3%。显示系统结构紧凑 ,可与输出面尺寸为18mm的图像源相连。     

Effect of solution concentrations on crystal structure,surface topographies and photoluminescence properties of ZnO thin films

Zinc oxide thin films were deposited on silicon substrates via hydrothermal method. Microstructures, surface topographies and optical properties of ZnO thin films were systematically investigated by X-ray diffraction, atomic force microscopy and fluorescence spectrophotometer. The mean grain size and surface roughness of the thin films decrease first and then increase with increasing the concentration of zinc nitrate hexahydrate. The photoluminescence spectra of ZnO thin films, excited by the 240, 320, 360, 380 and 400 nm excitation wavelength, were investigated in detail. Based on our analysis, it can be noted that mechanisms of the ultraviolet, violet and blue emissions are attributed to the transitions from the localized levels below the conduction band, zinc vacancy, interstitial zinc and extended interstitial zinc levels to the valance band, respectively. Blue–violet emissions of ZnO have great potential in light emitting and biological fluorescence labeling applications.