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41.
采用固源Si分子束外延,在较高的生长温度于Si(100)衬底上制备出Si1-xGex/Si量子阱发光材料。发光样品的质量和特性通过卢瑟福背散射、X射线双晶衍射及光致发光评估。背散射实验中观察到应变超晶格的反常沟道效应;X射线分析表明材料的生长是共度的、无应力释放的,结晶完整性好。低温光致发光主要是外延合金量子阱中带边激子的无声发射和横光学声子参与的激子复合。并讨论了生长温度对量于阱发光的影响。 相似文献
42.
43.
Sang Kyu Lee Min Ju Cho Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):531-542
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007 相似文献
44.
Alp E. E. Sturhahn W. Toellner T. S. Zhao J. Hu M. Brown D. E. 《Hyperfine Interactions》2002,144(1-4):3-20
Nuclear resonant inelastic X-ray scattering of synchrotron radiation is being applied to ever widening areas ranging from
geophysics to biophysics and materials science. Since its first demonstration in 1995 using the 57Fe resonance, the technique has now been applied to materials containing 83Kr, 151Eu, 119Sn, and 161Dy isotopes. The energy resolution has been reduced to under a millielectronvolt. This, in turn, has enabled new types of
measurements like Debye velocity of sound, as well as the study of origins of non-Debye behavior in presence of other low-energy
excitations. The effect of atomic disorder on phonon density of states has been studied in detail. The flux increase due to
the improved X-ray sources, crystal monochromators, and time-resolved detectors has been exploited for reducing sample sizes
to nano-gram levels, or using samples with dilute resonant nuclei like myoglobin, or even monolayers. Incorporation of micro-focusing
optics to the existing experimental setup enables experiments under high pressure using diamond-anvil cells. In this article,
we will review these developments.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
45.
In this paper we discuss thermodynamics parameters of black hole horizon and cosmological horizon in general high-dimensional space-time. We obtain that the entropy of a cosmological horizon can be described by the Cardy-Verlinde formula. However, the entropy of black hole horizon will be expressed in a form of the Cardy-Verlinde formula, if one adopts the methods given by Abbott and Deser to compute the mass of a black hole in general high-dimensional space-time. Through discussion, relation among various thermodynamics parameters of the black hole in general high-dimensional space-time is given. That is, differential formula of the first law of thermodynamics is obtained. Because we discuss the general high-dimensional space-time, our result has universality.
PACS: 04.20.Dw, 97.60.Lf 相似文献
46.
The phase boundary theory and the contact rule of phase regions are compared, and some weaknesses of the latter are manifested.
The comparison between the Gupta’s method and the boundary theory method for constructing multicomponent isobaric sections
is also presented. 相似文献
47.
In this paper, we first reduce the problem of finding a minimum parity (g,f)-factor of a graph G into the problem of finding a minimum perfect matching in a weighted simple graph G*. Using the structure of G*, a necessary and sufficient condition for the existence of an even factor is derived.
This paper was accomplished while the second author was visiting the Center for Combinatorics, Nankai University.
The research is supported by NSFC 相似文献
48.
49.
Zhong‐Zhen Yu Mingshu Yang Qingxin Zhang Chungui Zhao Yiu‐Wing Mai 《Journal of Polymer Science.Polymer Physics》2003,41(11):1234-1243
Nylon‐66 nanocomposites were prepared by melt‐compounding nylon‐66 with an alkyl ammonium surfactant pretreated montmorillonite (MMT). The thermal stability of the organic MMT powders was measured by thermogravimetric analysis. The decomposition of the surfactant on the MMT occurred from 200 to 500 °C. The low onset decomposition temperature of the organic MMT is one shortcoming when it is used to prepare polymer nanocomposites at high melt‐compounding temperatures. To provide greater property enhancement and better thermal stability of the polymer/MMT nanocomposites, it is necessary to develop MMT modified with more thermally stable surfactants. The dispersion and spatial distribution of the organic MMT layers in the nylon‐66 matrix were characterized by X‐ray diffraction. The organic MMT layers were exfoliated but not randomly dispersed in the nylon‐66 matrix. A model was proposed to describe the spatial distribution of the organic MMT layers in an injection‐molded rectangular bar of nylon‐66/organic MMT nanocomposites. Most organic MMT layers were oriented in the injection‐molding direction. Layers near the four surfaces of the bar were parallel to their corresponding surfaces; whereas those in the bulk differed from the near‐surface layers and rotated themselves about the injection‐molding direction. The influence of the spatial distribution of the organic MMT on crystallization of nylon‐66 was also investigated. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1234–1243, 2003 相似文献
50.
Shu Fen Wang Wen Guo Zou Su Wen Liu Dong Xu Duo Rong Yuan Guang Jun Zhou 《Journal of Physics and Chemistry of Solids》2004,65(7):1243-1245
The photoluminescence properties of the Bi3+ in sol-gel derived ZnTiO3 nanocrystals have been investigated. An ultra-violet emission at 360 nm and a visible emission band at 506 nm have been observed, originating from two kinds of emission centers. The former is ascribed to the 3P1-1S0 transition of Bi3+ and the latter to the recombination of the electrons with the photo-generated holes trapped in the zinc vacancies. In all cases the latter contribution is predominant. 相似文献