全文获取类型
收费全文 | 103369篇 |
免费 | 16544篇 |
国内免费 | 9248篇 |
专业分类
化学 | 66259篇 |
晶体学 | 1164篇 |
力学 | 6599篇 |
综合类 | 515篇 |
数学 | 11411篇 |
物理学 | 43213篇 |
出版年
2024年 | 347篇 |
2023年 | 2087篇 |
2022年 | 3426篇 |
2021年 | 3683篇 |
2020年 | 4005篇 |
2019年 | 3592篇 |
2018年 | 3358篇 |
2017年 | 2990篇 |
2016年 | 4794篇 |
2015年 | 4512篇 |
2014年 | 5574篇 |
2013年 | 7316篇 |
2012年 | 8863篇 |
2011年 | 9249篇 |
2010年 | 6168篇 |
2009年 | 5985篇 |
2008年 | 6488篇 |
2007年 | 5802篇 |
2006年 | 5541篇 |
2005年 | 4431篇 |
2004年 | 3476篇 |
2003年 | 2724篇 |
2002年 | 2523篇 |
2001年 | 2555篇 |
2000年 | 2108篇 |
1999年 | 2254篇 |
1998年 | 1863篇 |
1997年 | 1859篇 |
1996年 | 1790篇 |
1995年 | 1515篇 |
1994年 | 1331篇 |
1993年 | 1139篇 |
1992年 | 1017篇 |
1991年 | 932篇 |
1990年 | 779篇 |
1989年 | 611篇 |
1988年 | 458篇 |
1987年 | 389篇 |
1986年 | 392篇 |
1985年 | 336篇 |
1984年 | 208篇 |
1983年 | 154篇 |
1982年 | 128篇 |
1981年 | 84篇 |
1980年 | 59篇 |
1979年 | 31篇 |
1976年 | 27篇 |
1975年 | 27篇 |
1974年 | 21篇 |
1957年 | 31篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
In the present paper, some types of general solutions of a first-order nonlinear ordinary differential equation with six degree are given and a new generalized algebra method is presented to find more exact solutions of nonlinear differential equations. As an application of the method and the solutions of this equation, we choose the (2 + 1) dimensional Boiti Leon Pempinelli equation to illustrate the validity and advantages of the method. As a consequence, more new types and general solutions are found which include rational solutions and irrational solutions and so on. The new method can also be applied to other nonlinear differential equations in mathematical physics. 相似文献
32.
For the linear deterministic system with unknown orders and coefficients adaptive controls are given so that the closed-loop system is stabilized and the unknown parameters are consistently estimated. Moreover, if the parameter estimation is ignored, then the system input and output can be reduced to zero with an exponential rate.This project is supported by the National Natural Science Foundation of China.In Commemoration of the 15th Anniversary of the Acta Mathematicae Applicatae Sinica. 相似文献
33.
Experiments for the determination of mono-, di and tri-butyltin (MBT, DBT and TBT) by hydride generation/gas chromatography/atomic absorption spectrometry in various matrices (sediment, suspended matter, mussel, algae and water) have revealed that poor butyltin recoveries are obtained in sediments displaying high sulphur and hydrocarbon contents; very poor recoveries were also observed for TBT in sediments with high chlorophyll pigment contents as well as in algal samples. It was however not clear whether the hydride generatin was inhibited by these infering compounds, as was previously assumed in the case of hydrocarbons, or whether interferences affected the atomization rate. Further studies were performed to solve this problem in order to validate this method in the case of analyses of, for example, oil-contaminated sediment and algae. This paper presents the results obtained. It is concluded here that the poor recoveries were due to an inhibition of hydride generation rather than to interference at the atomization stage. 相似文献
34.
35.
对水热处理后得到的USY沸石作进一步的酸处理以及采用改进的氟硅酸盐溶液骨架富硅工艺,分别得到了经XPS剖面分析证实为铝分布均匀的超稳Y沸石HAY-Ⅰ和HAY-Ⅱ。IR分析表明,在酸处理过程中从USY沸石中去掉的那部分非骨架铝类与3690cm~(-1)处羟基有关,仍残留在HAY-Ⅰ沸石中的那部分非骨架铝类与3670cm~(-1)和3600cm~(-1)处羟基有关。XRD和化学分析表明HAY-Ⅰ沸石仍含有约50%的非骨架铝类,而HAY-Ⅱ沸石则基本上不含非骨架铝类,HAY-Ⅱ沸石还显示更高的结晶保留度。DTA分析表明,HAY-Ⅰ和HAY-Ⅱ两种沸石的热稳定性均高于USY沸石。 相似文献
36.
C Z Shi Z Y Zhang L Z Zhuang 《Science in China. Series B, Chemistry, life sciences & earth sciences》1991,34(9):1098-1104
The effect of hormones on progesterone secretion by 6-8 week human trophoblast tissue cultured in serum-free medium has been investigated. GnRH at low concentration (10(-10)-10(-8) mol/L) stimulated progesterone secretion, while high dose (10(-6)-10(-5) mol/L) produced inhibitory effect. The progesterone secretion could be significantly decreased by addition of anti-hCG antiserum or monoclonal anti-hCG IgG in a dose- and time-dependent manner. Various concentrations of TRH, PGE2, PGF2 alpha, testosterone and estradiol were found to be ineffective. These data indicate clearly that progesterone production by human trophoblast tissue at early gestation stage is under the modulation of GnRH and hCG. 相似文献
37.
The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and 13C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (Tg) for the in situ blends, contrary to an increase of Tg with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007 相似文献
38.
The strategy of expert system for high performance liquid chromatography was discussed, the attentions are mainly placed on the knowledge base for selection of column system, separation modes and detection modes in the analysis of amino acids, peptides and proteins. 相似文献
39.
Jie-Fang Zhang 《Acta Mechanica Solida Sinica》1991,4(2):139-151
Based on D'Alembert's principle of a mechanical system relative to non-inertial frame and by introducing the concept of the generalized inertial potential, new forms of differential equations of motion of a mechanical system with holonomic and the non-holonomic constraints relative to the non-inertial frame are obtained. The merits and demerits between our method and the Newtonian dynamic method as well as the analytic dynamic method are discussed comparatively. Finally, two examples are given to illustrate the application of the motive differential equations in the new forms. 相似文献
40.
In this paper we formulate a theorem on the persistence of elliptic lower-dimensional invariant tori for nearly integrable analytic Hamiltonian systems under the first Melnikov condition and Rüssmann’s non-degeneracy condition, and give the measure estimates of parameters for the non-resonance conditions under Rüssmann’s non-degeneracy condition, which is essential for the proof of our result. 相似文献