Anodic stripping coulometry with collection for absolute trace analysis of lead, using flow-through electrochemical cells with porous working electrodes

Summary Flow-through electrochemical cells with porous working electrodes made of crushed reticulated vitreous carbon and plated with mercury were used for absolute analysis of trace amounts of lead by anodic stripping coulometry with collection (ASCWC) in a flow system. The role of mercury coating, flow rate and pH were investigated. The coulombic content of the collection peak corresponded to the theoretical values calculated by Faraday's law in a concentration range from about 10^–9 to 10^–6 mol/l. The relative error and the relative standard deviation was +0.15% and 0.8%, respectively for 2×10^–6 mol/l analyte concentration. The absolute detection limit (3 s) was 0.1 ng of Pb, the linear response range 7×10⁴. One leave from: Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava, Czechoslovakia     

REGULAR RELATIONS AND MONOTONE NORMAL ORDERED SPACES

In this paper the classical theorem of Zareckii about regular relations is generalized and an intrinsic characterization of regularity is obtained. Based on the generalized Zareckii theorem and the intrinsic characterization of regularity, the authors give a characterization of monotone normality of ordered spaces. A new proof of the Urysohn-Nachbin lemma is presented which is quite different from the classical one.     

ESTIMATE OF THE UPPER CRITICAL FIELD AND CONCENTRATION FOR SUPERCONDUCTOR

The effect of an applied magnetic field on an inhomogeneous superconductor is studied and the value of the upper critical magnetic field Hc3 at which superconductivity can nucleate is estimated. In addition, the authors locate the concentration of the order parameter, which depends on the inhomogeneous term a(x). Unlikely to the homogeneous case, the order parameter may concentrate in the interior of the superconducting material, due to the influence of the inhomogeneous term a(x).     

α-FUZZY PAIRWISE RETRACT OF L-VALUED PAIRWISE STRATIFICATION SPACES

The notion of a fuzzy retract was introduced by Rodabaugh (1981). The notion of a fuzzy pairwise retract was introduced in 2001. Some weak forms and some strong forms of α-continuous mappings were introduced in 1988 and 1997. The authors extend some of these forms to the L-fuzzy bitopological setting and construct various α-fuzzy pairwise retracts. The concept of weakly induced spaces in the case L = [0,1] was introduced by Martin (1980). Liu and Luo (1987) generalized this notion to the case that L is an arbitrary F-lattice and introduced the notion of induced L-fts. Several results are obtained, especially, for L-valued pairwise stratification spaces.     

FORWARD-BACKWARD STOCHASTIC DIFFERENTIAL EQUATIONS WITH STOPPING TIME

The existence and uniqueness results of fully coupled forward-backward stochastic differential equations with stopping time (unbounded) is obtained. One kind of comparison theorem for this kind of equations is also proved.     

A new alternating‐direction finite element method for hyperbolic equation

A modified backward difference time discretization is presented for Galerkin approximations for nonlinear hyperbolic equation in two space variables. This procedure uses a local approximation of the coefficients based on patches of finite elements with these procedures, a multidimensional problem can be solved as a series of one‐dimensional problems. Optimal order H₀¹ and L² error estimates are derived. © 2007 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2007     

A new generalized algebra method and its application in the (2 + 1) dimensional Boiti–Leon–Pempinelli equation

In the present paper, some types of general solutions of a first-order nonlinear ordinary differential equation with six degree are given and a new generalized algebra method is presented to find more exact solutions of nonlinear differential equations. As an application of the method and the solutions of this equation, we choose the (2 + 1) dimensional Boiti Leon Pempinelli equation to illustrate the validity and advantages of the method. As a consequence, more new types and general solutions are found which include rational solutions and irrational solutions and so on. The new method can also be applied to other nonlinear differential equations in mathematical physics.     

Discrete global descent method for discrete global optimization and nonlinear integer programming

A novel method, entitled the discrete global descent method, is developed in this paper to solve discrete global optimization problems and nonlinear integer programming problems. This method moves from one discrete minimizer of the objective function f to another better one at each iteration with the help of an auxiliary function, entitled the discrete global descent function. The discrete global descent function guarantees that its discrete minimizers coincide with the better discrete minimizers of f under some standard assumptions. This property also ensures that a better discrete minimizer of f can be found by some classical local search methods. Numerical experiments on several test problems with up to 100 integer variables and up to 1.38 × 10¹⁰⁴ feasible points have demonstrated the applicability and efficiency of the proposed method.     

Oligomeric guanidine synthesis assisted by TFA-sensitive arylsulfonylthiourea

Through arylsulfonyl activation of thiourea, efficient synthesis of oligomeric guanidines can be achieved in either solution or solid-phase. Incorporation of TFA-sensitive arylsulfonyl groups, such as Pbf, during the synthesis greatly simplifies deprotection procedures for obtaining the final oligomeric guanidine products.