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The first α‐diimine nickel(I) complex having a chloro bridge is reported. The centrosymmetric dinuclear structure of {[ArN?C(Me)C(Me)?NAr]NiCl}2[Ar?2,6?C6H3(i‐Pr)2] features two chelating α‐diimine ligands and two bridged chlorine atoms, so that a distorted tetrahedral N2Cl2 coordination geometry for nickel results. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
54.
Wang Qing-Lun Zhao Bin Liao Dai-Zheng Yan Shi-Ping Cheng Peng Jiang Zong-Hui 《Transition Metal Chemistry》2003,28(3):326-330
The copper(II) complex Na2[Cu(pba)] · 6H2O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na+ bridge in the same layer. 相似文献
55.
Jihua Zhang Xi WangWeidong Yu Tao FengFumin Zhang Zhihong ZhengQiong Li Xianghuai Liu 《Solid State Communications》2003,127(4):289-293
Effects of ion impinging on the microstructure and field electron emission properties of screen-printed carbon nanotube films were investigated. We observed that the plasma treatment modified the microstructure of CNTs along with the remarkable increase of emission site density. With the prolongation of ion impinging time, the emission current falls down first, and then rises up to higher than that of the untreated films. It is proposed that the change of emission characteristics is due to the different emission mechanisms. After the treatment, electrons are emitted predominantly from the nano-nodes on the tube wall instead from the nanotube tips. 相似文献
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Fei Chang Dongheng Zhang Haijian Yang Haibin Song 《Journal of organometallic chemistry》2004,689(5):936-946
The synthesized 1-aryliminomethylenylnaphthalen-2-ol derivatives reacted with nickel chloride to form bis(1-aryliminomethylenylnaphthalen-2-oxy)nickel complexes. All resultant compounds were structurally characterized by elemental analyses, IR and H NMR, and the structures of the formed complexes were elucidated by X-ray crystal structure analysis. The complexes show high catalytic activities for the vinyl polymerization of norbornene in the presence of methylaluminoxane. The catalytic activity variations have been followed by gas chromatography through monitoring the conversion of norbornene. 相似文献
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Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis.
The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate
activities for ethylene oligomerization.
Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714.
This article was submitted by the authors in English. 相似文献
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