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91.
Xiaoya Wang Bingbing Liu Jie Li Yunyun Zhai Haiqing Liu Lei Li Herui Wen 《Electroanalysis》2021,33(6):1484-1490
2D metal-organic framework (MOF) has potential applications in electrocatalysis owing to fast mass transfer, charge transfer and large specific surface area. Here, we had prepared three conductive 2D MOF based on Ni, NiCo and Co in a simple and rapid way. The 2D nanostructure of MOF was confirmed by SEM and TEM. The chemical composition was studied by XRD, Raman and XPS spectrum. The electrochemical oxidation and detection was investigated through cyclic voltammetry and current-time method. Their sensing performance for urea was determined by varying oxidation potentials and metal sites. The non-enzymatic Ni-, NiCo- and Co-MOF sensors had good catalytic activity for urea. Compared with NiCo- and Co-MOF, Ni-MOF had a wider linear range (0.5–832.5 μM), high sensitivity (1960 μA mM−1 cm−2), low detection limit (0.471 μM), and fast response time. The sensors had well repeatability, reproducibility, and selectivity to specific interfering species. Furthermore, Ni- and NiCo-MOF modified electrode was also applied to detection of milk samples. The results showed that the recovery was satisfactory, which further confirmed the effectiveness of non-enzyme sensor. In general, the highly-sensitive 2D Ni- and NiCo-MOF modified electrode has great potential as nonenzymatic urea sensors for real samples detection in hydrogen energy, clinical diagnostics, and environmental protection, et al. 相似文献
92.
Wang Zi-Jian Yu Yong-Ji Zhai Rui-Zhi Chen Xin-Yu Wu Chun-Ting Jin Guang-Yong 《Journal of Russian Laser Research》2016,37(1):97-101
We report a narrow pulse width optical parametric oscillator based on periodically poled MgO:LiNbO3 (PPMgLN) with a high repetition rate under quasi-phase matched conditions. When the maximum pumping power of the 1,064-nm laser was 14.57 W, the acousto-optical (A-O) Q-switch repetition rate was 100 kHz, and the PPMgLN crystal grating period was 29.5 μm. A 1,474-nm signal light output power of 4.21 W and a 3,828 nm idler light output power of 1.547 W were obtained, corresponding to a pulse width of 9.52 ns and 9.65 ns, respectively. The overall optical–optical conversion efficiency was 39.5%. Additionally, by changing the temperature from 25°C to 150°C, a tunable signal wavelength of 1,474–1,499 nm and idler wavelength at 3,676–3,828 nm of the output laser were achieved. 相似文献
93.
本文分别采用磁控溅射技术与基于密度泛函理论的平面波赝势方法两种方式, 对高价态差元素V掺杂ZnO薄膜进行研究. 实验研究结果表明: V的掺入并未改变ZnO的生长方式, 所制备的薄膜都呈(002)择优生长; 随着衬底温度增加, VZO薄膜的结晶质量逐步改善, 当衬底温度超过280 ℃时薄膜的结晶质量恶化; 在280 ℃时获得的VZO薄膜电阻率最低3.8×10-3 Ω·m, 500-2000 nm平均透过率高于85%. 理论模拟结果表明: V以替位形式掺入ZnO六角纤锌矿晶格结构中, 费米能级进入导带, 材料表现出n 型半导体的特性, 导电电子主要由V 3d及O 2p电子轨道提供. 理论计算结果与实验结果的一致性, 表明VZO薄膜具有作为高效Si基薄膜太阳电池透明导电薄膜的应用潜力. 相似文献
94.
We study a quantum phase transition between fermion superfluid (SF) and band insulator (BI) of fermions in optical lattices. The destruction of the band insulator is driven by the energy gain in promoting fermions from valance band to various conducting bands to form Cooper pairs. We show that the transition must take place in lattice height Vo/ER between 2.23 and 4.14. The latter is the prediction of mean-field theory while the former is the value for opening a band gap. As one moves across resonance to the molecule side, the SF-BI transition evolves into the SF-Mott-insulator transition of bosonic molecules. We shall also present the global phase diagram for SF-insulator transition for the BCS-BEC family. 相似文献
95.
Canik JM Anderson DT Anderson FS Likin KM Talmadge JN Zhai K 《Physical review letters》2007,98(8):085002
Differences in the electron particle and thermal transport are reported between plasmas produced in a quasihelically symmetric (QHS) magnetic field and a configuration with the symmetry broken. The thermal diffusivity is reduced in the QHS configuration, resulting in higher electron temperatures than in the nonsymmetric configuration for a fixed power input. The density profile in QHS plasmas is centrally peaked, and in the nonsymmetric configuration the core density profile is hollow. The hollow profile is due to neoclassical thermodiffusion, which is reduced in the QHS configuration. 相似文献
96.
Yu Qin Qing Guo Shengjie Wu Chenlu Huang Zhiming Zhang Li Zhang Linhua Zhang Dunwan Zhu 《中国化学快报》2021,31(12):3121-3126
Combination therapy such as photothermal therapy (PTT) enhanced chemotherapy is regarded as a promising strategy for cancer treatment. Herein, we developed redox-responsive polymeric vesicles based on the amphiphilic triblock copolymer PCL-ss-PEG-ss-PCL. To avoid the limited therapeutic effect of chemotherapeutic drugs caused by systemic exposures and drug resistance, the redox-sensitive polymeric vesicles were cargoed with two chemotherapeutics: doxorubicin (DOX) and paclitaxel (PTX). Besides, indocyanine green (ICG) was encapsulated, and cell-penetrating peptides and LHRH targeting molecule were modified on the surface of polymeric vesicles. The results indicated that the polymeric vesicles can load different kinds of drugs with high drug loading content, trigger drug release in responsive to the reductive environment, realize high cellular uptake via dual peptides and laser irradiation, and achieve higher cytotoxicity via chemo-photothermal combination therapy. Hence, the redox-responsive LHRH/TAT dual peptides-conjugated PTX/DOX/ICG co-loaded polymeric micelles exhibited great potential in tumor-targeting and chemo-photothermal therapy. 相似文献
97.
Tian Bai Kongyin Zhao Zijie Lu Xuefang Liu Ze Lin Mengmeng Cheng Ziyi Li Dunwan Zhu Linhua Zhang 《中国化学快报》2021,32(3):1051-1054
Herein,copper ion doped calcium alginate(Cu~(2+)/CaAlg) composite hydrogel filtration membranes were prepared by using natural polymer sodium alginate(NaAlg) as raw material.The thermal stability and structure of the composite membranes were characterized by thermogravimetric analysis and infrared spectroscopy.The mechanical strength,anti-fouling performance,hydrophilicity and filtration performance of the membrane were studied.The results show that Cu~(2+)/CaAlg hydrogel membrane has excelle nt mechanical properties and thermal stability.The anti-swelling ability of the membrane was greatly enhanced by doping Cu~(2+).After three alternate filtration cycles,the flux recovery rate of Cu~(2+)/CaAlg hydrogel membrane can still reach 85%,indicating that the membrane has good antipollution performance.When the operation pressure was 0.1 MPa,the rejection of coomassie brilliant blue G250 reached 99.8% with a flux of 46.3 L m ~2 h ~1,while the Na_2 SO_4 rejection was less than 10.0%.The Cu~(2+)/CaAlg membrane was recycled after 24 h in the filtration process,and its flux and rejection rate did not decrease significantly,indicating that the hydrogel membrane has long-term application potential.The Cu~(2+)/CaAlg membrane has a wide range of applications prospect in dye desalination,fine separation and biopharmaceutical technology fields. 相似文献
98.
Self-assembled lamellar nanochannels in polyoxometalate-polymer nanocomposites for proton conduction
Haibo He Gang Wang Shengchao Chai Xiang Li Liang Zhai Lixin Wu Haolong Li 《中国化学快报》2021,32(6):2013-2016
The construction of nanostructured ion-transport channels is highly desirable in the design of advanced electrolyte materials,as it can enhance ion conductivity by offering short ion-transport pathways.In this work,we present a supramolecular strategy to fabricate a nanocomposite electrolyte containing highly ordered lamellar proton-conducting nanochannels,by the electrostatic self-assembly of a polyoxometalate H_3 PW_(12)O_(4 O)(PW) and a comb copolymer poly(4-methlstyrene)-graft-poly(N-vinyl pyrrolidone).PW can effectively regulate the self-assembling order of polymer moieties to form a large-ra nge lamellar structure,meanwhile,introducing protons into the nanoscale lamellar domains to build proton transport channels.Moreover,the rigid PW clusters contribute a remarkable mechanical reinforcement to the nanocomposites.The lamellar nanocomposite exhibits a conductivity of 4.3 × 10~(-4) S/cm and a storage modulus of 1.1 × 10~7 Pa at room temperature.This study provides a new strategy to construct nanostructured ion-conductive pathways in electrolyte materials. 相似文献
99.
100.
集成模块化航空电子架构(Integrated Modular Avionic, IMA)已成为主流航空电子系统。ARINC 653作为航空电子设备IMA架构的标准应用接口,成为研究航空电子软件编程方法的入口。最新研究表明,VxWorks能够为航空电子分区管理提供最优化的平台。然而,基于VxWorks的ARINC 653高效分区调度算法依然是研究的“盲区”。由此,设计了VxWorks内核态分层ARINC 653分区实时调度算法,提高了分区调度效率,为VxWorks内核ARINC 653完整性的研究提供非常有价值的参考。实验数据说明,相较于传统用户态分区管理模型,该调度算法使分区释放开销和分区释放抖动两项指标均显著降低。 相似文献