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941.
Petr Vlček Miroslav Janata Petra Látalová Jiří Dybal Milena Špírková Luděk Toman 《Journal of polymer science. Part A, Polymer chemistry》2008,46(2):564-573
Graft copolymers with cellulose diacetate (CDA) backbone and both the poly(ε‐caprolactone) and polystyrene, or poly(butyl acrylate) or PMMA grafts were prepared by two‐step process. First, ε‐caprolactone (CL) was polymerized by ring‐opening polymerization (ROP) initiated with CDA, partly funcionalized with 2‐bromo‐isobutyryl groups (degree of functionalization was 0.5). The p(CDA‐g‐CL) copolymers were used in the second step as polyfunctional macroinitiators of ATRP of the vinyl monomer, giving densely grafted copolymers with polyester and PSt, or PBuA, or PMMA grafts. The prepared copolymers were characterized by SEC, some of them also by FTIR spectroscopy and atomic force microscopy (AFM). © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 564–573, 2008 相似文献
942.
Tyihk Ern Mricz gnes M. Ott Pter G. Hajnos Michal L. Gowniak Kazimierz 《平面色谱法杂志一现代薄层色谱法》2008,21(5):331-336
JPC – Journal of Planar Chromatography – Modern TLC - The accumulation of hydrogen peroxide (H2O2) is an early and crucial step in paclitaxel-induced cancer cell death before commitment... 相似文献
943.
The main result of the present note states that it is consistent with the ZFC axioms of set theory (relying on Martin's Maximum MM axiom), that every Asplund space of density character ω1 has a renorming with the Mazur intersection property. Combined with the previous result of Jiménez and Moreno (based upon the work of Kunen under the continuum hypothesis) we obtain that the MIP renormability of Asplund spaces of density ω1 is undecidable in ZFC. 相似文献
944.
945.
946.
The ray tracing codes for flat, cylindrically bent (Johann horizontal focusing and von Hamos vertical focusing geometry), elliptically and spherically bent crystal spectrometers were developed. The codes, extended by introducing the two-dimensional source and the real shape of single crystal diffraction pattern in dependence on the radius of curvature, contribute to a proper choice of experimental configuration in x-ray plasma diagnostics. A method of ray tracing the von Hamos spectrometer is presented in detail. The use of the ray tracing code to the optimization of the spectroscopic scheme is demonstrated on the analysis of gas-puff z-pinch experiment. 相似文献
947.
948.
Two versions of an amperometric detector with a copper working electrode have been constructed and tested for high-performance liquid chromatography (HPLC). The performance of the detectors was studied using selected amino acids. The dependence of the detector response on the mobile phase flow-rate was studied in the range common in both macro- and microcolumn HPLC (5 microliter/min to 1.0 ml/min). It has been found that the detection sensitivity generally increases with decreasing flow-rate, i.e., the detector response is governed by the rate of the complexation reaction between the cupric ions and the solutes. This fact makes amperometric detection with a copper electrode especially useful for microcolumn separations. For all 20 amino acids studied, calibration curve parameters and detection limits have been determined; the latter vary from 0.4 to 18 ng in the injected volume. The amino acids can also be sensitively detected in a medium of 0.1-1.0 M ammonia, which is promising for the use of strong anion exchangers in amino acid separations. Choline can also be detected at a copper electrode, with a detection limit of 40 ng. An HPLC method with amperometric detection at a copper electrode has been developed for the determination of lysine, methionine and choline in fodder biofactors. 相似文献
949.
Michal Korenko Marián Kucharík Jozef Vincenc Oboňa Dušan Janičkovič Rosa Córdoba José María De Teresa Blanka Kubíková 《Helvetica chimica acta》2008,91(7):1389-1399
The rapid‐solidification processing (by a cooling rate of 105–106 K/s) was used for the preparation of deeply undercooled cryolite/alumina (Na3AlF6/Al2O3) melts. We found a mass of nanotubes on the surface of these undercooled melts. The nanotubes were preferentially located on the defect places of the surface with the following approximate dimensions: base≈100×100 nm, length≈1000 nm. The solidified samples with the nanotubes on the surface were analyzed by scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), X‐ray diffraction (XRD), and infrared spectroscopy (IR). 相似文献
950.
Zorica Bugarcěi? Slobodan Novokmet Zěeljko Seni? Zěivadin Bugarcěi? 《Monatshefte für Chemie / Chemical Monthly》2000,52(12):799-802
Carbonyl compounds of the type XPhCOR (R = H, Me, Ph; X = H, Me, Cl, Br) are prepared in high yields by reaction of the corresponding benzylic alcohols XPhCHOHR with KNa4 [Ag(HIO6)2]×12H2O in alkaline solution. This method allows the selective oxidation of benzylic alcohols in compounds containing other types of alcoholic functional groups. 相似文献