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141.
Let θ be a family of graphs. By a θ-decomposition of a graph G we mean a partition λ of the edge set of G such that every F ? π spans in G a subgraph isomorphic to a graph in θ. In this paper we state the following conjecture: If T1 and T2 are two trees having relatively prime sizes then there exists c = c(T1 T2) such that every graph G satisfying the condition δ(G) ? c has a {T1, T2}-decom-position. We prove this conjecture for some special pairs of trees. In particular, we prove it in the following cases: (i) T1 and T2 are stars having relatively prime sizes; (ii) T1 and T2 are paths having relatively prime sizes; and. (iii) T1 = T2 - {v}, where v is a terminal vertex in T 2.  相似文献   
142.
Rate constants and activation parameters of direct reaction of oxirane with certain alkyl-2-hydroxyethyl sulfides and/or successive oxyethylene adducts in the presence of basic catalyst were studied at temperatures 323–353 K. The reactions were found to be of the first order with respect to oxirane, sulfide, and catalyst concentrations. The kinetics are consistent with a termolecular mechanism.  相似文献   
143.
We show that for positive integers n, m with n(n−1)/2≥mn−1, the graph Ln,m having n vertices and m edges that consists of an (nk)-clique and k−1 vertices of degree 1 has the fewest spanning trees among all connected graphs on n vertices and m edges. This proves Boesch’s conjecture [F.T. Boesch, A. Satyanarayana, C.L. Suffel, Least reliable networks and reliability domination, IEEE Trans. Commun. 38 (1990) 2004-2009].  相似文献   
144.
2-Mercapto-1,3-benzothiazole (mbztH) may act as a chelating or bridging ligand. In this study, reactions of mbztH with Me3Ga and Me3In were examined. The products were characterized by NMR spectroscopy, elemental analyses, melting point, and molecular weight determinations. Formation of mononuclear chelating complexes Me2M(mbzt) (M = Ga, In) was observed in solutions. Crystallization of Me2M(mbzt) yielded uncommon non-symmetrical dinuclear complexes Me4M2(mbzt)2, in which one metal is bonded to two sulfurs and the other to two nitrogens.  相似文献   
145.
The concept of a chiral coupling reagent for the enantioselective synthesis of peptides with a predictable configuration and enantiomeric purity from racemic substrates is presented. The reagent was prepared by treatment of strychninium tetrafluoroborate with 2-chloro-4,6-dimethoxy-1,3,5-triazine in the presence of sodium bicarbonate yielding N-(4,6-dimethoxy-1,3,5-triazin-2-yl)strychninium tetrafluoroborate in high yield, which is stable at room temperature, and in a broad range of solvents gave enriched Z-Ala-Phe-OMe (dr from 95/5 to 60/40) in high yield with d-configuration on the alanine residue starting from rac-Z-Ala-OH.  相似文献   
146.
A combination of pyrolysis and gas chromatography were used to investigate thermal degradation products formed from acrylic copolymers containing alkyl acrylate and methacrylate. The method provided an analytical tool for characterizing the chemical composition and structure of the degradation products. Thermal degradation of the synthesized copolymers was analyzed using isothermal (250 °C) pyrolysis–gas chromatography. The degradation process, and the nature and amount of pyrolysis products, provides relevant information about the thermal degradation of acrylic copolymers and the mechanism of pyrolysis. During pyrolysis, the formation of corresponding olefins, alcohols, acrylates and methacrylate was observed.  相似文献   
147.
Plate impact experiments on the (210), (100), and (111) planes were performed to examine the role of crystalline anisotropy on the shock-induced decomposition of cyclotrimethylenetrinitramine (RDX) crystals. Time-resolved emission spectroscopy was used to probe the decomposition of single crystals shocked to peak stresses ranging between 7 and 20 GPa. Emission produced by decomposition intermediates was analyzed in terms of induction time to emission, emission intensity, and the emission spectra shapes as a function of stress and time. Utilizing these features, we found that the shock-induced decomposition of RDX crystals exhibits considerable anisotropy. Crystals shocked on the (210) and (100) planes were more sensitive to decomposition than crystals shocked on the (111) plane. The possible sources of the observed anisotropy are discussed with regard to the inelastic deformation mechanisms of shocked RDX. Our results suggest that, despite the anisotropy observed for shock initiation, decomposition pathways for all three orientations are similar.  相似文献   
148.
New determinations of the ground-state electric dipole moments of acrylonitrile and propionitrile have been made from Stark effect measurements at conditions of supersonic expansion. The measurements were made on selected Stark lobes of fully resolved hyperfine components of several lowest-J rotational transitions. The results are μa = 3.821(3) D, μb = 0.687(8) D, μtot = 3.882(3) D for acrylonitrile, and μa = 3.816(3) D, μb = 1.235(1) D, μtot = 4.011(3) D for propionitrile. The new value of μb for acrylonitrile is appreciably different from those reported previously and it has been substantiated by both ab initio calculations and relative intensity measurements. The new dipole moment implies a considerable revision in the calculated intensities of the strongest THz-region rotational transitions of acrylonitrile, to 59% of previous values.  相似文献   
149.
Molecular structures of the isolated tetrahedral oxovanadium(IV) and bridged μ-oxo-divanadium(IV) complexes hosted by the clusters mimicking surfaces of amorphous silica-based materials were investigated using density functional theory (DFT) calculations. Principal values of the g and A tensors for the monomer vanadyl species were obtained using the coupled-perturbed DFT level of theory and the spin–orbit mean-field approximation (SOMF). Magnetic exchange interaction for the μ-oxo bridged vanadium(IV) dimer was investigated within the broken symmetry approach. An antiferromagnetic coupling of the individual magnetic moments of the vanadium(IV) centers in the [VO–O–VO]2+ bridges was revealed and discussed in detail. The coupling explains pronounced decrease of the electron paramagnetic resonance signal (EPR) intensity, observed for the reduced VO x /SiO2 samples with the increasing coverage of vanadia, in terms of transformation of the paramagnetic monomer species into the dimers with S = 0 ground state.  相似文献   
150.
We prove the Wiener–Hopf factorization for Markov additive processes. We derive also Spitzer–Rogozin theorem for this class of processes which serves for obtaining Kendall’s formula and Fristedt representation of the cumulant matrix of the ladder epoch process. Finally, we also obtain the so-called ballot theorem.  相似文献   
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