全文获取类型
收费全文 | 748篇 |
免费 | 28篇 |
国内免费 | 4篇 |
专业分类
化学 | 438篇 |
晶体学 | 6篇 |
力学 | 61篇 |
数学 | 132篇 |
物理学 | 143篇 |
出版年
2023年 | 7篇 |
2022年 | 30篇 |
2021年 | 26篇 |
2020年 | 10篇 |
2019年 | 23篇 |
2018年 | 22篇 |
2017年 | 16篇 |
2016年 | 36篇 |
2015年 | 29篇 |
2014年 | 31篇 |
2013年 | 46篇 |
2012年 | 49篇 |
2011年 | 58篇 |
2010年 | 35篇 |
2009年 | 30篇 |
2008年 | 57篇 |
2007年 | 46篇 |
2006年 | 41篇 |
2005年 | 34篇 |
2004年 | 30篇 |
2003年 | 21篇 |
2002年 | 22篇 |
2001年 | 13篇 |
2000年 | 10篇 |
1999年 | 6篇 |
1998年 | 13篇 |
1997年 | 9篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有780条查询结果,搜索用时 15 毫秒
71.
We consider higher-order QCD corrections to the production of colorless high-mass systems (lepton pairs, vector bosons, Higgs bosons, etc.) in hadron collisions. We propose a new formulation of the subtraction method to numerically compute arbitrary infrared-safe observables for this class of processes. To cancel the infrared divergences, we exploit the universal behavior of the associated transverse-momentum (qT) distributions in the small-qT region. The method is illustrated in general terms up to the next-to-next-to-leading order in QCD perturbation theory. As a first explicit application, we study Higgs-boson production through gluon fusion. Our calculation is implemented in a parton level Monte Carlo program that includes the decay of the Higgs boson into two photons. We present selected numerical results at the CERN Large Hadron Collider. 相似文献
72.
Summary In classical plasticity dissipation postulates on cycles, such as those proposed by Drucker, Martin e Il'yushin, rule the evolution of elastic-plastic deformation processes. In this paper, within the framework of the infinitesimal theory of isotropic materials with elastic range of [7], each one of those three postulates is given an equivalent local formulation; moreover, they are shown to be all equivalent.
Sommario In plasticitá classica l'evoluzione dei processi elasto-plastici é regolata da postulati di dissipazione su cicli quali quelli proposti da Drucker, Martin e Il'yushin. In questo lavoro, nell'ambito della teoria infinitesima dei materiali isotropi con dominio elastico proposta in [7], si fornisce una formulazione locale equivalent per ciascuno di quei tre postulati e si mostra che essi sono tutti tra loro equivalenti.相似文献
73.
74.
Direct On‐Surface Patterning of a Crystalline Laminar Covalent Organic Framework Synthesized at Room Temperature 下载免费PDF全文
Alejandro de la Peña Ruigómez David Rodríguez‐San‐Miguel Dr. Kyriakos C. Stylianou Dr. Massimiliano Cavallini Dr. Denis Gentili Dr. Fabiola Liscio Prof. Silvia Milita Dr. Otello Maria Roscioni Dr. Maria Luisa Ruiz‐González Carlos Carbonell Prof. Daniel Maspoch Dr. Rubén Mas‐Ballesté Dr. José Luis Segura Dr. Félix Zamora 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(30):10666-10670
We report herein an efficient, fast, and simple synthesis of an imine‐based covalent organic framework (COF) at room temperature (hereafter, RT‐COF‐1 ). RT‐COF‐1 shows a layered hexagonal structure exhibiting channels, is robust, and is porous to N2 and CO2. The room‐temperature synthesis has enabled us to fabricate and position low‐cost micro‐ and submicropatterns of RT‐COF‐1 on several surfaces, including solid SiO2 substrates and flexible acetate paper, by using lithographically controlled wetting and conventional ink‐jet printing. 相似文献
75.
Massimiliano Berti Riccardo Montalto 《Journal of Fixed Point Theory and Applications》2017,19(1):129-156
We present the result and the ideas of the recent paper (Berti and Montalto, Quasi-periodic standing wave solutions of gravity-capillary water waves, http://arxiv.org/abs/1602.02411, 2016) concerning the existence of Cantor families of small-amplitude time quasi-periodic standing wave solutions (i.e. periodic and even in the space variable x) of a 2-dimensional ocean, with infinite depth, in irrotational regime, under the action of gravity and surface tension at the free boundary. These quasi-periodic solutions are linearly stable. 相似文献
76.
This paper deals with the stochastic response of structures loaded by non-Gaussian random fields. A finite element model is used to describe a cantilever beam assuming both linear and non-linear behavior. The cross-correlated stochastic field is generated by a numerical procedure based on the translation processes theory. The marginal distribution of the load is assumed to be lognormal and the correlation structure is based on the second-order Markov process. The statistical analysis of the results highlights the effects of the involved non-linearity and non-Gaussianity properties on the structures response. 相似文献
77.
A. P. Brylyakov G. M. Zharkova B. Yu. Zanin V. N. Kovrizhina D. S. Sboev 《Journal of Applied Mechanics and Technical Physics》2004,45(4):510-516
The flow structure behind wire grids is studied for flows with a low subsonic velocity, and the effect of grids on the boundarylayer flow structure is considered. It is shown that the meanvelocity inhomogeneity induced by the grid does not disappear until a distance of 925 calibers downstream of the grid is reached. Liquidcrystal thermography combined with hotwire measurements made it possible to find the source of steady largescale streamwise vortex structures in the boundary layer on a wedge and on an airfoil and to determine the parameters of these structures. 相似文献
78.
Massimiliano CordaroGiovanni Grassi Antonio RescifinaUgo Chiacchio Francesco RisitanoAngela Scala 《Tetrahedron》2011,67(3):608-611
Mesoionic 1,3-oxazolium-5-olates (münchnones) react with thiocoumarins having an electron-withdrawing group at the 3-position to afford stereodefined fused polycyclic thienopyrroles. The reaction sequence seems to be triggered by a regiospecific dipolar cycloaddition followed by ring opening of the initial 1:1 cycloadduct and intramolecular rearrangement with an unusual ring contraction. 相似文献
79.
Deniz E Tomasulo M Cusido J Sortino S Raymo FM 《Langmuir : the ACS journal of surfaces and colloids》2011,27(19):11773-11783
The stringent limitations imposed by diffraction on the spatial resolution of fluorescence microscopes demand the identification of viable strategies to switch fluorescence under optical control. In this context, the photoinduced and reversible transformations of photochromic compounds are particularly valuable. In fact, these molecules can be engineered to regulate the emission intensities of complementary fluorophores in response to optical stimulations. On the basis of this general design logic, we assembled a functional molecular construct consisting of a borondipyrromethene fluorophore and a nitrospiropyran photochrome and demonstrated that the emission of the former can be modulated with the interconversion of the latter. This fluorophore-photochrome dyad, however, has a slow switching speed and poor fatigue resistance. To improve both parameters, we developed a new family of photochromic switches based on the photoinduced opening and thermal closing of an oxazine ring. These compounds switch back and forth between ring-closed and -open isomers on nanosecond-microsecond timescales and tolerate thousands of switching cycles with no sign of degradation. In addition, the attachment of appropriate chromophoric fragments to their switchable oxazine ring can be exploited to either deactivate or activate fluorescence reversibly in response to illumination with a pair of exciting beams. Specifically, we assembled three dyads, each based on either a borondipyrromethene or a coumarin fluorophore and an oxazine photochrome, and modulated their fluorescence in a few microseconds with outstanding fatigue resistance. The unique photochemical and photophysical properties of our fluorophore-photochrome dyads can facilitate the development of switchable fluorophores for superresolution imaging and, ultimately, provide valuable molecular probes for the visualization of biological samples on the nanometer level. 相似文献
80.
Silver nanoparticles as potential antiviral agents 总被引:1,自引:0,他引:1
Galdiero S Falanga A Vitiello M Cantisani M Marra V Galdiero M 《Molecules (Basel, Switzerland)》2011,16(10):8894-8918
Virus infections pose significant global health challenges, especially in view of the fact that the emergence of resistant viral strains and the adverse side effects associated with prolonged use continue to slow down the application of effective antiviral therapies. This makes imperative the need for the development of safe and potent alternatives to conventional antiviral drugs. In the present scenario, nanoscale materials have emerged as novel antiviral agents for the possibilities offered by their unique chemical and physical properties. Silver nanoparticles have mainly been studied for their antimicrobial potential against bacteria, but have also proven to be active against several types of viruses including human imunodeficiency virus, hepatitis B virus, herpes simplex virus, respiratory syncytial virus, and monkey pox virus. The use of metal nanoparticles provides an interesting opportunity for novel antiviral therapies. Since metals may attack a broad range of targets in the virus there is a lower possibility to develop resistance as compared to conventional antivirals. The present review focuses on the development of methods for the production of silver nanoparticles and on their use as antiviral therapeutics against pathogenic viruses. 相似文献