N-Isocyaniminotriphenylphosphorane (Ph3PNNC) as a metal-free catalyst for the synthesis of functionalized isoindoline-1-ones

A novel application in the field of N-isocyaniminotriphenylphosphorane (Ph₃PNNC) chemistry has been introduced in this work. A series of substituted isoindolin-1-one ring systems has been successfully synthesized through a novel and efficient multicomponent reaction of methyl 2-formylbenzoate and primary amines in the presence of N-isocyaniminotriphenylphosphorane (Ph₃PNNC) as a catalyst. This one-pot three component reaction (3-CR) gives high yield using N-isocyaniminotriphenylphosphorane (Ph₃PNNC) as a metal-free catalyst under mild conditions.     

Vibro-acoustic response of an elliptical plate-cavity coupled system to external shock loads

A general fully coupled three-dimensional vibro-acoustic model is developed to investigate the forced non-stationary acousto-structural response of a thin elastic plate of elliptical planform which is backed by a reverberant, rigid, and finite (closed) elliptic cylindrical acoustic enclosure, while under the action of general external transverse loads of arbitrary temporal and spatial variations. The Laplace transform with respect to the time coordinate is invoked, and the classical method of separation of variables in elliptic coordinates is used to obtain the transformed solutions as a linear combination of even and odd modes in terms of products of radial and angular Mathieu functions. A linear system of coupled algebraic equations is ultimately obtained, which is truncated and then solved numerically by implementing Durbin’s numerical Laplace transform inversion scheme. Detailed numerical simulations are conducted for the temporal histories of plate center-point displacement and on-axis cavity acoustic pressure for air-coupled elliptic aluminum plates of selected aspect ratios when subjected to external loadings of practical interest (i.e., an impulsive point load, a uniformly distributed pulse load, and a blast load). Also, acoustic radiation into the backing enclosure is examined by using appropriate 2D images of the internal sound field for selected cavity depths and plate eccentricities. The presented results confirm that the acousto-elastic characteristics of the coupled plate-cavity system are significantly influenced by the plate aspect ratio, cavity depth and the transverse loading configuration. Validity of the work is established through the computations made by using a commercial finite element package.     

Almost local stability in discrete delayed chaotic systems

This work studies dynamic of delayed discrete chaotic systems with bounded and unbounded delays. The time lags appear in additive which is coupled with a smooth function and nonadditive forms. It has been shown that, in both additive and nonadditive cases, the primal (non-delayed) system is neutral to the bounded delay to possess an attractive fixed point. Nevertheless, if a nonadditive and unbounded delay is supposed to affect a chaotic and measure preserving system locally, then the delay function might be sensitive to initial states. A local stabilization to the dynamics of Logistic and Gaussian maps are made and creation of attractive fixed points is illustrated.     

Effects of minor additions of Mg and Ag on precipitation phenomena in Al–4 mass% Cu

Calorimetric measurements and transmission electron microscopy have been used to study the effects of minor additions of Mg and Ag on mechanism and kinetics of precipitation in Al–4 mass% Cu. Isothermal studies at 30°C show that the rate of Guinier–Preston (Cu) zone formation is progressively reduced by the presence of Mg, or Mg?+?Ag, which is attributed to preferential trapping of vacancies so that their ability to assist diffusion of Cu atoms is reduced. At elevated temperatures, Mg enhances precipitation of θ′, whereas Mg?+?Ag stimulates formation of the Ω phase. Precipitation of S′ follows θ′ if Mg or Mg?+?Ag are present and pre-ageing increases the quantity of θ′ precipitated at the expense of S′. It has been confirmed that secondary precipitation occurs at low temperatures if alloys are first aged at elevated temperatures.     

Synthesis,characterization and photocatalytic application of TiO2/magnetic graphene for efficient photodegradation of crystal violet

A magnetized nano‐photocatalyst based on TiO₂/magnetic graphene was developed for efficient photodegradation of crystal violet (CV). Scanning electron microscopy, X‐ray diffraction, energy‐dispersive X‐ray spectroscopy and elemental mapping were used to characterize the prepared magnetic nano‐photocatalyst. The photocatalytic activity of the synthesized magnetic nano‐photocatalyst was evaluated using the decomposition of CV as a model organic pollutant under UV light irradiation. The obtained results showed that TiO₂/magnetic graphene exhibited much higher photocatalytic performance than bare TiO₂. Incorporation of graphene enhanced the activity of the prepared magnetic nano‐photocatalyst. TiO₂/magnetic graphene can be easily separated from an aqueous solution by applying an external magnetic field. Effects of pH, magnetized nano‐photocatalyst dosage, UV light irradiation time, H₂O₂ amount and initial concentration of dye on the photodegradation efficiency were evaluated and optimized. Efficient photodegradation (>98%) of the selected dye under optimized conditions using the synthesized nano‐photocatalyst under UV light irradiation was achieved in 25 min. The prepared magnetic nano‐photocatalyst can be used in a wide pH range (4–10) for degradation of CV. The effects of scavengers, namely methanol (OH^? scavenger), p‐benzoquinone (O₂^?? scavenger) and disodium ethylenediaminetetraacetate (hole scavenger), on CV photodegradation were investigated.