Composition depth profiles of Bi3.15Nd0.85Ti3O12 thin films studied by X-ray photoelectron spectroscopy

In the present work, X-ray photoelectron spectroscopy (XPS) was used to investigate the composition depth profiles of Bi_3.15Nd_0.85Ti₃O₁₂ (BNT) ferroelectric thin film, which was prepared on Pt(1 1 1)/Ti/SiO₂/Si(1 0 0) substrates by chemical solution deposition (CSD). It is shown that there are three distinct regions formed in BNT film, which are surface layer, bulk film and interface layer. The surface of film is found to consist of one outermost Bi-rich region. High resolution spectra of the O 1s peak in the surface can be decomposed into two components of metallic oxide oxygen and surface adsorbed oxygen. The distribution of component elements is nearly uniform within the bulk film. In the bulk film, high resolution XPS spectra of O 1s, Bi 4f, Nd 3d, Ti 2p are in agreement with the element chemical states of the BNT system. The interfacial layer is formed through the interdiffusion between the BNT film and Pt electrode. In addition, the Ar⁺-ion sputtering changes lots of Bi³⁺ ions into Bi⁰ due to weak Bi-O bond and high etching energy.     

Adsorption and dissociation of O2 on the Cu2O(1 1 1) surface: Thermochemistry, reaction barrier

The adsorption and dissociation of O₂ on the perfect and oxygen-deficient Cu₂O(1 1 1) surface have been systematically studied using periodic density functional calculations. Different kinds of possible modes of atomic O and molecular O₂ adsorbed on the Cu₂O(1 1 1) surface are identified: atomic O is found to prefer threefold 3Cu site on the perfect surface and O_vacancy site on the deficient surface, respectively. Cu_CUS is the most advantageous site with molecularly adsorbed O₂ lying flatly over singly coordinate Cu_CUS-Cu_CSA bridge on the perfect surface. O₂ adsorbed dissociatively on the deficient surface, which is the main dissociation pathway of O₂, and a small quantity of molecularly adsorbed O₂ has been obtained. Further, possible dissociation pathways of molecularly adsorbed O₂ on the Cu₂O(1 1 1) surface are explored, the reaction energies and relevant barriers show that a small quantity of molecularly adsorbed O₂ dissociation into two O atoms on the deficient surface is favorable both thermodynamically and kinetically in comparison with the dissociation of O₂ on the perfect surface. The calculated results suggest that the presence of oxygen vacancy exhibits a strong chemical reactivity towards the dissociation of O₂ and can obviously improve the catalytic activity of Cu₂O, which is in agreement with the experimental observation.     

纳米ZnO／石蜡复合相变材料的热物理性质研究

本文通过将纳米氧化锌（ZnO）颗粒加入熔融的石蜡（PW）并进行搅拌和超声制备了一种纳米ZnO／PW复合相变储能材料。为使纳米氧化锌在基体物质中分散均匀,在制备过程中使用了搅拌和超声以制备均匀的复合材料。使用扫描电镜观察其微观结构表明氧化锌在石蜡中分散良好。对所得ZnO／PW复合相变材料的相变温度、相变焓及导热系数等热物...     

基于三种气化炉的整体煤气化湿化燃气轮机循环热力性能分析

将燃料湿化和空气湿化应用到整体煤气化燃气轮机循环中,以降低NOx排放并有效利用系统低品位热。基于水煤浆、干煤粉及输运床三种气化炉,构建了多种整体煤气化湿化燃气轮机循环,分析了其热力性能并给出了湿化方式建议。研究表明：燃料湿化循环系统效率较高;空气湿化循环燃气轮机比功较大;整体煤气化湿化燃气轮机循环具有利用系统外部中低品...     

S变换轮廓术中消除条纹非线性影响的方法

S变换是短时傅里叶变换和小波变换的延伸和推广,是一种无损可逆的非平稳信号时频分析方法.它不仅具有线性、多分辨性和逆变换唯一性等特点,而且其反变换与傅里叶变换保持着直接的联系.在S变换中,以简谐波作为基波,以可以同时进行伸缩和平移的高斯函数作为窗函数.同短时傅里叶变换相比,S变换的时频分辨率可以同时达到最佳,同小波变换相...     

Quantum nonlocality for two-mode correlated states based on generalized pseudospin operators

In this Letter, we investigate the quantum nonlocality of two-mode correlated states. We find that the pseudospin formalism [Z.B. Chen, J.W. Pan, G. Hou, Y.D. Zhang, Phys. Rev. Lett. 88 (2002) 040406] generally fails to depict the nonlocality of the states when the photon number difference between the two modes is odd. The formalism is then generalized such that the nonlocality of a two-mode correlated state can be well revealed without regard to the difference. Later we consider the nonlocality of the two-mode intelligent SU(1,1) states in the generalized formalism and compare our results with the entanglement of the corresponding states.     

Memory effect and multifractality of cross-correlations in financial markets

We introduce an instantaneous and an average instantaneous cross-correlation function to detect the temporal cross-correlations between individual stocks based on the daily data of the United States and the Chinese stock markets. The memory effect of the instantaneous cross-correlations is investigated by applying the detrended fluctuation analysis (DFA), where the DFA exponents can be partly explained by the correlation function from the common sense. Long-range memory is observed for the average instantaneous cross-correlations, and persists up to a month magnitude of timescale for the United States stock market and half a month magnitude of timescale for the Chinese stock market. In addition, multifractal nature is investigated by a multifractal detrended fluctuation analysis.     

Effects of electromigration on copper atoms in carbon nanotube channels

The effects of electromigration on copper in carbon nanotube (CNT) channels are investigated using molecular dynamics simulations. The study shows that the potential energy of copper and the resistive forces on copper are dependent on the shape of the CNT junction, and the increase in bias voltages magnifies these effects. Bias voltages affect the density of copper in the downstream CNT. The velocity of copper in the downstream CNT is relatively lower than that in the upstream CNT when the biased voltage is high.