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911.
912.
Metal-organic frameworks (MOFs) have attracted much attention as adsorbents for the separation of CO2 from flue gas or natural gas. Here, a typical metal-organic framework HKUST-I(also named Cu-BTC or MOF-199) was chemically reduced by doping it with alkali metals (Li, Na and K) and they were further used to investigate their CO2 adsorption capacities. The structural information, surface chemistry and thermal behavior of the prepared adsorbent samples were characterized by X-ray powder diffraction (XRD), thermo-gravimetric analysis (TGA) and nitrogen adsorption-desorption isotherm analysis. The results showed that the CO2 storage capacity of HKUST-1 doped with moderate quantities of Li+, Na+ and K+, individually, was greater than that of unmodified HKUST-1. The highest CO2 adsorption uptake of 8.64 mmol/g was obtained with 1K-HKUST-1, and it was ca. 11% increase in adsorption capacity at 298 K and 18 bar as compared with HKUST- 1. Moreover, adsorption tests showed that HKUST-1 and 1K-HKUST-1 displayed much higher adsorption capacities of CO2 than those of N2. Finally, the adsorption/desorption cycle experiment revealed that the adsorption performance of 1K-HKUST-1 was fairly stable, without obvious deterioration in the adsorption capacity of CO2 after 10 cycles. 相似文献
913.
On the Criteria of Instability for Electrochemical Systems 总被引:7,自引:0,他引:7
Both cyclic-voltammetry-based and impedance-based experimental criteria that have been developed recently for the oscillatory electrochemical systems are critically appraised with two typical categories of oscillators.Consistent conclusions can be drawn by the two criteria for the category of oscillators that involve the coupling of charge transfer mainly with surface steps(e.g.ad-and desorption)such as in the electrooxidation of C1 organic molecules.Whereas,impedance-based criterion is not applicable to the category of oscillators that involve the coupling of charge transfer mainly with mass transfer(e.g.diffusion and convection) such as in the Fe(CN)6^3- reduction accompanying periodic hydrogen evolution.The reason is that the negative impedance cannot include the feedback information of convection mass transfer induced by the hydrogen evolution.However,both positive and negative nonlinear feedbacks,i.e., the diffusion-limited depletion and convection-enhanced replenishment of the Fe(CN)6^3- surface concentration,that coexist between the bistability,i.e.,Fe(CN)6^3- reduction with and without hydrogen evolution at lower and higher potential sides respectively,are all reflected in the crossed cyclic voltammogram(CCV).It can be concluded that the voltammetry-based criterion(in time domain)is more intuitive,less time-consuming and has a wider range of applications than the impedancebased one (in frequency domain). 相似文献
914.
Xian-Ci Zhong Xian-Fang Li Kang Yong Lee 《International Journal of Solids and Structures》2009,46(6):1456-1463
The elastostatic problem of a mode-I crack embedded in a bimaterial with an imperfect interface is investigated. The crack is in proximity to and perpendicular to the imperfect interface, which is governed by linear spring-like relations. The Fourier transform is applied to reduce the associated mixed-boundary value problem to a singular integral equation with Cauchy kernel. By numerically solving the resulting equation, stress intensity factors near both crack tips are evaluated. Obtained results reveal that the stress intensity factors in the presence of the imperfect interface vary between that with a perfect interface and that with a completely debonding interface. Moreover, an increase in the interface parameters decreases the stress intensity factors. In particular, when crack approaches to the weakened interface closer, the stress intensity factors become larger for a sliding interface, and become larger or smaller for a Winkler interface, depending on the crack lying in a stiffer or softer material. The influences of the imperfection of the interface on the stress intensity factors for a bimaterial composed of aluminum and steel are presented graphically. 相似文献
915.
采用MonteCarlo方法对由异类自旋组成混合Heisenberg自旋体系进行了数值计算,以模拟和预测基于交换耦合模型纳米双相(硬磁软磁)磁性体系的磁性.区别于以往所报道的那些直接针对硬磁NdFeB与软磁纳米αFe复合磁体的微磁学计算工作,着眼于符合Heisenberg模型的两类完全不同的原子自旋集团(硬磁自旋和软磁自旋)之间的直接交换耦合作用,模拟计算了由这两类自旋组成的复合自旋体系的内禀矫顽力Hc、剩余磁化强度Mr、最大磁能级(M×H)max等宏观磁性参量随软磁自旋集团的尺度和体积百分比、两类自旋集
关键词:
Heisenberg模型
MonteCarlo模拟
纳米复合磁体
Nd-Fe-B 相似文献
916.
917.
An approximate resonance wavelength equation that varies with metal antenna structure size is developed to design a bowtie
gold metal antenna working at near-infrared (IR) wavelength. Bowtie antenna structures with resonance wavelength of 1.06 μm,
1.55 μm and 10.6 μm are designed based on this equation. A finite-difference time domain (FDTD) algorithm with total field
scattered field (TFSF) source simulation shows the resonance wavelength of the designed structures being precisely in agreement
with the expected wavelengths from the equation. Planar integration of the metal bowtie antennas is discussed as well. Gold
nanohole bowtie antenna arrays are fabricated and the near-field optical transmission properties of the nanohole array are
investigated with a near-field scanning optical microscope (NSOM). Our experimental results verify the near-field optical
transmission performance and further demonstrate that they are in agreement with the theoretical calculation results. The
high enhancement efficiency and integration of the metal bowtie antennas open the possibility of a wide application in IR
optoelectronics detection and imaging. 相似文献
918.
A new fluorescence probe, CdSe nanocrystal has been prepared and modified with 11-mercaptoundecanoic acid [HS-(CH2)10-COOH]. The functionalized nanoparticles were characterized using transmission electron microscopy (TEM), ultraviolet-visible (UV-vis) spectroscopy and photoluminescence (PL) spectroscopy. The results demonstrate that CdSe is dispersed homogeneously in aqueous solution and well protected from the environmental oxygen. They can be used as a new fluorescence probe for lysozyme, which was simple, rapid and specific. Under the optimum condition, the response is linearly proportional to the amount of lysozyme from 0.20 to 26.0 μg ml−1, and the limit of detection is 0.115 μg ml−1. The proposed method has been applied to the determination of lysozyme in egg white, with the recovery of 96-105%. 相似文献
919.
Morelos A Albuquerque IF Bondar NF Carrigan RA Chen D Cooper PS Lisheng D Denisov AS Dobrovolsky AV Dubbs T Endler AM Escobar CO Foucher M Golovtsov VL Gottschalk H Gouffon P Grachev VT Khanzadeev AV Kubantsev MA Kuropatkin NP Lach J Lang Pengfei Li Chengze Li Yunshan Luksys M Mahon JR McCliment E Newsom C Pommot Maia MC Samsonov VM Schegelsky VA Shi Huanzhang Smith VJ Tang Fukun Terentyev NK Timm S Tkatch II Uvarov LN Vorobyov AA Yan Jie Zhao Wenheng Shuchen Z Zhong Yuanyuan 《Physical review letters》1993,71(21):3417-3420
920.
建立微波消解–ICP–OES法测定陶土中铅和镉含量的方法。采用氢氟酸–硝酸作为消解液,微波消解法处理样品,消解液定容后直接进入耐氢氟酸的进样系统,用ICP–OES法测定陶土中重金属铅和镉的含量。结果表明,Pb和Cd检出限分别为0.027μg/m L和0.011μg/m L,回收率分别为90.5%~98.8%和95.0%~98.4%,测定结果相对标准偏差分别为1.38%和2.17%(n=7)。该方法具有快速、准确、灵敏度高等优点,适用于陶土中铅和镉含量的检测。 相似文献