不对称加氢制备手性3′-氯-苯丙醇的反应液的气相色谱分析

用不对称催化还原法以3’-氯-苯丙醇（CPNL）为原料制备了手性3’-氯-1-苯丙酮（CPNL）,并用气相色谱法测定反应液中产品及剩留的原料的含量。选用2-甲基-苯丙醇为内标物,并用化学键合β-环糊精为固定相的手性毛细管色谱柱CP-Chirasil-Dex-CB对产品及原料进行分离。在所选条件下,不仅使CPNN与CPNL,还可使CPNL的右、左旋对映体相互有效分离。由于采有内标法,因进样不准而产生的误差得以克服,测得CPNN及（S）CPNL的检出限（3S/N）依次为13.14,18.75 mg·L^-1。上述两种化合物的加标回收率依次为99.5%～101.8%及96.5%～100.4%范围内;两者测定值的相对标准偏差（n=6）分别为0.39%,0.74%（左、右旋对映体相同）。     

Application of EDXRF Method in Measurement of Fe Content in Aqueous Fe Sample

介绍了能量色散X荧光分析方法在含水Fe样品测量中的应用.用ANTG -2000型海底X荧光探测系统对含Fe为10％～60％的Fe样进行测量,建立水分对Fe元素特征K α射线影响的校正模型.结果表明,通过该模型校正,对含饱和水情况下Fe样品的分析相对误差小于4％,具有良好的分析效果.     

Dipole bands in nucleus ~(139)Pm

High-spin states in nucleus 139Pm have been studied using the reaction 116Cd(27Al,4n)139Pm.Two dipole cascades have been found.Spin and parity assignments were based on the Directional Correlation of Oriented Nuclei(DCO) ratios and systematic behavior in neighboring odd-proton nuclei.The level structures of 139Pm are compared with those of the N =78 isotone 141Eu in which two dipole bands have been confirmed as magnetic rotational bands.The close similarity between them suggests that the dipole bands in 139...     

Tesla微混合器结构参数对混合强度的影响

针对Tesla微混合器混合原理,利用计算流体力学(CFD)模拟与分析软件对其进行了三维数值模拟.模型采用有限体积法离散、SIMPLEC算法进行层流计算.分析了结构参数的改变对该混合器混合效果的影响,并采用混合强度值作为衡量指标.分析结果显示,不同通道高宽比和分离通道入流角度等结构参数对该微混合器的混合效果有重要影响.模...     

用于闪光照相的1MV Rod-Pinch二极管辐射特性

Rod-Pinch二极管(RPD)在小尺度闪光照相方面具有良好的应用前景.根据理论方面的研究结果以及实验室具备的驱动源装置水平,设计了相应结构的RPD,并在1MV工作电压下开展了较为详细的性能实验研究.最终在二极管轴向(0.方向)lm处得到的x光剂量为1.21rad-1.45rad.对于阳极直径为lmm的二极管,其X光焦斑直径仅为0.8mm-1.1mm.X光信号的脉宽为18.1ns-27.5ns.研究表明RPD将是一种用于小尺度闪光照相的理想的X光源.     

Alpha decay energies and half-lives for possibly synthesized superheavy elements

We investigate the ground state properties of some superheavy nuclei, which may be synthesized in future experiments. Special emphases are placed on the alpha decay energies and half-lives. The alpha decay energies and half-lives from different theoretical models are compared and discussed comprehensively. Through these calculations and comparisons, the optimal superheavy elements to be synthesized in future experiments are proposed theoretically.     

高血压性脑出血再发生因素的Logistic分析

根据问题的特点 ,选择 Logistic判别模型 ,并借鉴普通线性回归的逐步向前法 ,用似然比统计量 ( Deviance)来筛选自变量 (因素 ) .结果显示 :在 1 1个因素中 ,有 3个是作用显著的 ,而其中舒张压值极为重要 .为降低再出血率 ,将其控制在 85 mm Hg以下是有效而可行的     

VIBRATIONAL POWER TRANSMISSION FROM A MACHINE TO ITS SUPPORTING CYLINDRICAL SHELL

Power flows from a vibratory machine to its supporting structure are of primary concern in a passive or active isolation system design. Although in the literature there is a fair number of investigations on the power inputs to beams, plates or the like, few attempts have been made for other commonly used structures such as cylindrical shells. In this paper, the vibratory power flows from a rigid-body machine to an elastic cylindrical shell are studied considering the contributions of the non-radial (tangential and axial) displacements and forces. In particular, it is argued that the notion that the motion of a thin shell is primarily radial does not necessarily dictate that the power transmissions are predominantly carried out by the radial displacement. This point is subsequently illuminated through numerical examples. Another issue discussed here is concerned with the effects on the power flows of the cross couplings of the (different) displacement components. It is shown that even though the contributions of the cross couplings are usually insignificant, they may become important if the vibration isolators are substantially hard as compared with the local shell stiffness or impedance. This assertion is particularly useful when an experimental technique is used to measure the vibratory power flows into a supporting structure.     

在实验室建设中深化近代物理实验教学体系改革

介绍了南开大学物理科学学院近代物理实验室通过“基地”、“211工程”和“世行贷款”等实验室建设,对近代物理实验教学体系进行改革的概况。     

120 W的二极管泵浦Nd:YAG绿光激光器

对激光二极管泵浦的NdYAG声光调Q腔内倍频固体激光器的折叠腔型进行了研究,当泵浦功率达800 W时,在V型腔上实现了脉宽为80 ns、重复频率为10 kHz、发散角为6 mrad、绿光功率为112 W的输出;在Z型腔上实现了脉宽为95 ns、重复频率为10 kHz、发散角为4 mrad、绿光功率为120 W的输出.比较两种腔型的实验结果可看出,Z型腔由于插入的光学元件较多,腔长较长,输出激光的脉宽较宽,但输出激光的光束质量有明显的提高.