Coupling Reaction of 4-Chloro-7-H-Pyrrolo[2,3-d]Pyrimidine with 2,3,5-Tri-O-Acetyl-β-D-Ribofuranosyl Chloride

Tubercidin (4-amino-7--D-riobofuranosyl-7-H-pyrrolo[2,3-d]pyrimidine) 1, an antibio-tic substance produced in the culture broth of Streptomyces tubericidus1, is an adenosine analog in which N-7 is replaced by a carbon atom. It has attracted much attention due to the biological activities for the growth inhibition of certain tumors, and many derivatives of tubercidin have been synthesized2-5.For the synthesis of tubercidin analogs, 4-chloro-7-H-pyrrolo[2,3-d]pyrimidine-2,3,5-tri-O-acetyl--D-r…     

"铁和铁的化合物"教学中新手-成手型教师课堂语言行为的比较研究

采用"弗氏语言互动分析方法"(FIAC)对"铁和铁的化合物"新手-成手型教师的课堂进行数据处理和分析,比较新手型与成手型教师的课堂语言行为的特点;为了弥补"弗氏语言互动分析方法"强烈定量化的局限性,本文还借助板块理论、课堂语音实录等材料与弗兰德斯互动分析的主要参数和语言动态曲线相结合,深入地分析了新手型教师与成手型教师...     

D[X2m]的下界估计与X2m矩阵的快速构造

本文利用有向图理论研究了Xn矩阵的特性，给出了X2m矩阵类的快速构造方法，证明了拉丁方矩阵D[X2m]数目的下界估计是：2m(2m)! ∑^mi=2[(2m)!]^2/П^ij=1Kj!П^rj=1bj!。     

C2H4的微波场助气相光催化氧化

用溶胶-凝胶法制备了多孔性TiO     

Quantum dynamics of dissociative adsorption of H_2 on Ni(100) using the dynamical Lie algebraic method

A dynamical Lie algebraic method has been applied to treating the quantum dynamics of dissociative adsorption of H_2 on a static flat metal surface. An LEPS potential energy surface has been used to describe the interaction of H_2 with Ni(100) surface. The dependence of the initial state-selected dissociation probability was obtained analytically on the initial kinetic energy and time. A comparison with other theoretical calculations and experiments is made. The results show that the method can be effectively used to describe the dynamics of reactive gas-surface scattering.     

Some Alternating Double Binomial Sums

We consider some new alternating double binomial sums. By using the Lagrange inversion formula, we obtain explicit expressions of the desired results which are related to a third-order linear recursive sequence. Furthermore, their recursive relation and generating functions are obtained.     

可瓷化硅橡胶材料的研究

研究了一种可瓷化硅橡胶,其特点是在火灾发生时可在金属线外形成瓷化绝缘保护层,600℃的成瓷温度大幅度低于目前文献报道的成瓷温度。实验得到的优化瓷化填料配方为:相对于100份混炼胶,氧化铝10份、硅灰石15份、结构控制剂9份、碳酸锂3份。在此配方条件下,未瓷化硅橡胶的断裂伸长率316%、拉伸强度10.79MPa、体积电阻率134×10~(12)Ω·cm,其在600℃、800℃瓷化后的抗压强度分别为3.47MPa、10.13MPa、体积电阻率≥28×10~(12)Ω·cm,满足电缆用硅橡胶的力学和绝缘要求。经热重分析及SEM分析可知加入瓷化填料后,试样烧蚀重量减少了39.4%,烧蚀残留率大大提高,且成瓷试样结构致密。     

Sensitive fluorescence probes for dihydrogen phosphonate anion based on calix[4]arene bearing naphthol-hydrazone groups

t-Butyl and t-pentylcalix[4]arenes bearing two 2-naphthol-1-hydrazone groups at the lower rim were synthesized,and showed excited-state intermolecular proton transfer fluorescent signal with basic anion.They are more sensitive to dihydrogen phosphate anion than to fluoride anion,although the latter has stronger basicity.Compared with t-butylcalix[4]arene bearing two 2-naphthol-1-hydrazone groups,t-pentylcalix[4]arenes derivative has a larger fluorescent difference between dihydrogen phosphate and fluoride a...     

光漏斗聚光定向传光中央接收太阳能集热系统

提出了一种新型中央接收式太阳能高温集热系统,介绍了系统的运行原理,分析了系统的热效率影响因素。这个新型的太阳能高温集热系统具有如下特点:可将多个光漏斗和偏光器组成一个太阳能聚光器阵列,每个聚光器都能将低能流密度的太阳光束会聚成高能流密度的平行光束,并由偏光器传送到中央接收器,于是中央接收器可获得很高的太阳光照射能流,转化为热能后将产生很高的温度,从而实现太阳光高温聚能。本系统的中央接收器无需建在高塔上,节省了建设费用,而且所有光漏斗跟踪太阳的方式相同,控制策略简单,定向偏光器的出光方向设定后可以固定不变,因而使整个系统结构简单,技术上易于实现。     

Study on the Crystal Structure of RS-1-(2-methoxyphenyl)-4-〔3-(1-naphthyloxy)-2-hydroxypropyl〕-piperazine

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