Evaluation of Optical Properties of Self-Frequency-Doubling Crystal Yb：GdYAl3（BO3）4 for Laser Applications

Yb：GdYAl3 （B03）4 （Yb：GdYAB） is investigated as a new laser crystal for potential applications in self-frequency doubling. The emission and absorption properties of Yb：GdYAB crystal are studied, and the emission decay times of the upper laser level are measured. The emission cross sections are evaluated using the absorption cross section and principle of reciprocity. The other laser performance parameters, such as the minimum inversion fraction βmin, pump saturation intensity Isat and minimum pump intensity 1rain, are also calculated. The results are discussed in the framework of requirements for an effective diode-pumped Yb^3＋ laser system. Yb：GdYAB is expected to exhibit the most useful laser properties and to be superior to Yb：YAB crystal that has been excellent self-frequency-doubling crystal at present in many key spectroscopic parameter values.     

LD泵浦Nd∶GdVO4晶体Cr4+∶YAG被动调Q激光特性研究

考虑腔内光子数密度的空间高斯分布以及晶体热效应的影响,给出了LD泵浦Nd∶GdVO4晶体Cr4+∶YAG被动调Q 1.06 μm激光的耦合速率方程组.数值求解该方程组获得了输出激光的脉冲宽度、重复率、峰值功率以及单脉冲能量随泵浦功率的变化特性,其理论值与实验结果相符.     

Determination of the calcium species in coal chars by Ca K-edge XANES analysis

Ca-based additives have been widely used as a sulfur adsorbent during coal pyrolysis and gasification. The Ca speciation and evolution during the pyrolysis of coal with Ca additives have attracted great attention. In this paper, Ca species in the coal chars prepared from the pyrolysis of Ca(OH)2 or CaCO3-added coals are studied by using Ca K-edge X-ray absorption near-edge structural spectroscopy. The results demonstrate that Ca(OH)2 , CaSO4 , CaS and CaO coexist in the Ca(OH)2-added chars, while Ca(OH)2 and CaSO4 are the main species in the Ca(OH)2-added chars. Besides, a carboxyl-bound Ca is also formed during both the pyrolysis for the Ca(OH)2-added and the CaCO3-added coals. A detailed discussion about the Ca speciation is given.     

Local hydrated structure of an Fe2+/Fe3+ aqueous solution: an investigation using a combination of molecular dynamics and X-ray absorption fine structure methods

The hydrated shell of both Fe2+ and Fe3+ aqueous solutions are investigated by using the molecular dynamics (MD) and X-ray absorption structure (XAS) methods. The MD simulations show that the first hydrated shells of both Fe2+ and Fe3+ are characterized by a regular octahedron with an Fe-O distance of 2.08 for Fe2+ and 1.96 for Fe3+, and rule out the occurrence of a Jahn-Teller distortion in the hydrated shell of an Fe2+ aqueous solution. The corresponding X-ray absorption near edge fine structure (XANES) calculation successfully reproduces all features in the XANES spectra in Fe2+ and Fe3+ aqueous solution. A feature that is located at energy 1 eV higher than the white line (WL) in an Fe3+ aqueous solution may be assigned to the contribution of the charge transfer.     

The Cross-Section Measurements and Evaluations for 58Ni(n,p),60Ni(n,p),62Ni(n,α) and 54Fe(n,p) Reactions

Activation techniques have been used to measure the cross-section for ⁵⁸Ni(n,p),⁶⁰Ni(n,p) and ⁶²Ni(n,α) reactions in the neutron energy range 13.6—17.8MeV.The uncertainty of measured data has been aculated from 3%—7%.The covariance matrixes for measurement error are calculated.Evaluations for ⁵⁸Ni(n,p),⁶⁰Ni(n,p),⁶²Ni(n,α) and ⁵⁴Fe(n,p) crpss-section are made.     

空气开关等离子体干涉条纹图像的处理

利用Mach-Zehnder干涉仪测量了空气开关中等离子体电子密度分布,使用高速分幅相机拍摄记录不同时延下的干涉条纹图像。针对实验获得的干涉条纹图像的特点,提出了一种首先进行频域FFT滤波去噪,然后进行空域二值化、细化的处理方法。该方法能够很好的消除图像噪声的影响,提取出单像素的亮条纹中心线,从而能够准确读取条纹坐标信息,再通过对干涉条纹偏移量进行Abel逆变换,得到等离子体电子密度分布。     

白光LED用Ba3La（PO4）3∶Dy3+荧光粉的制备与发光性能

通过高温固相法合成了一系列Ba3La1-x(PO4)3∶xDy3+荧光粉材料。利用XRD测量样品的物相,结果显示样品为纯相Ba3La(PO4)3晶体。样品的激发光谱由一系列宽谱组成,峰值分别位于322,347,360,386,424,451 nm。在347 nm激发下,荧光粉在482 nm(4F9/2→6H15/2)和575 nm(4F9/2→6H13/2)处有很强的发射。研究了不同Dy3+掺杂浓度对样品发射光谱的影响,当Dy3+摩尔分数x=0.10时出现猝灭现象,浓度猝灭机理为电偶极-电偶极相互作用。确定了不同Dy3+掺杂浓度的Ba3La(PO4)3∶Dy3+的荧光寿命。Ba3La(PO4)3∶Dy3+荧光粉发射光谱的色坐标位于白光区域。     

比值导数法矿物组分光谱解混模型研究

矿物丰度含量的精确分析是高光谱遥感技术定量分析中的难点。将化学领域的比值导数光谱算法进行总结,将其引入遥感反射率光谱分析,提出了基于线性光谱混合模型的比值导数光谱解混模型,并利用石膏和绿帘石粉末混合物进行了模型的精度分析。实验结果表明,矿物粉末混合物在不同波段其光谱混合特性有所不同,其中部分波段有较强的线性混合特征。采用部分强线性混合波段进行光谱解混,可以取得比全波段解混算法更好的结果。比值导数法光谱解混模型简洁,可以得到高精度的矿物成分反演结果,对于固定端元组成的混合光谱定量分析有较大潜力。     

傅里叶变换轮廓术中滤波窗方位选择研究

在傅里叶变换轮廓术频域滤波过程中通常采用不对称的汉宁窗滤波窗来提取基频信号,当投影呈二维变化的光栅条纹时,采用的滤波窗长短轴方向和载频方向不吻合,会导致被测物体的部分高频信息丢失,从而影响相位展开的难易程度和系统测量的精度。分析比较物体高度的分布与频谱的关系,通过旋转滤波窗使其短轴方向与载频方向一致,可以保留物体的高频信息,降低相位展开的复杂度,提高测量的精确度。计算机模拟和实物实验结果表明滤波窗旋转滤波可以避免相位展开在物体高度突变处的出错,有效地提高测量精度。     

棉花冠层水分含量估算的高光谱指数研究

适宜的光谱指数对于地表参数高光谱诊断模型的估算精度具有决定性作用。通过不同棉花冠层水分含量表征参数冠层等效水厚度EWT_canopy, 植株含水量VWC及其对应的光谱数据分析,构建350～2 500 nm范围内所有波段两两组合的比值指数RVI和归一化指数NDVI,分析水分含量表征参数与所有指数之间的相关关系,筛选最大相关系数对应的指数作为最佳水分指数,利用新指数构建水分含量表征参数的估算模型,并与已知的各种水分指数估算精度进行比较。结果表明：新建比值指数R_{1 475}/R_{1 424}及其归一化指数(R_{1 475}-R_{1 424})/(R_{1 475}+R_{1 424})对EWT_canopy的估算效果最佳,由其得到的估算值与实测值之间的相关系数r值达到0.849;已知指数(R₈₃₅-R_{1 650})/(R₈₃₅+R_{1 650})对VWC的估算效果最佳,由其得到估算值与实测值之间的相关系数r值为0.805。