偶氮类化合物热相变动态过程的二维相关拉曼光谱研究

利用变温傅里叶变换拉曼光谱（ＦＴ－Ｒａｍａｎ）研究含偶氮苯基长链脂肪酸化合物８Ａ５Ｈ固体的热相变。二维相关光谱分析技术被应用到以温度为变量的同步和异步相关计算，目的在于研究该化合物中不同基团在热相变过程中取向变化过程以及变化趋势、步骤等一系列的动态结构变化。展示了研究偶氮类化合物热致相变过程中结构动态新的研究方法，同时也为二维相关光谱的应用拓宽了新的研究领域。     

光干涉现象的演示

采用传统方法演示孔(双孔、三孔)和缝(双缝、三缝)的干涉图像,与由传感器采集图像信息后由计算机得出干涉光强分布曲线进行比较,两种方法获得的实验图像符合较好.     

关于拟Einstein场方程

In this paper some properties of a symmetric tensor field T(X, Y) = g(A(X), Y) on a Riemannian manifold (M,g) without boundary which satisfies the quasi-Einstein equation Rij-S/2gij=Tij+bξiξj are given. The necessary and sufficient conditions for this tensor to satisfy the quasi-Einstein equation are also obtained.     

一种新型面阵CCD航天立体摄影测量光学系统

采用一台大面阵CCD和广角摄影物镜的组合，研制成功一种新型的单面阵CCD航天立体摄影测量系统.该系统焦距为23.3 mm;视场角为40°;在空间分辨率为36 lp/mm时，MTF均值达到0.8以上;光谱适应范围为0.5 μm~0.75 μm.和国内外常用的三线阵CCD遥感立体测量相机相比，本系统结构更简单、体积更小，重量更轻，更加适用于航天遥感应用环境.     

Solvent-free Synthesis, Crystal Structure and Thermal Stability of Ionic Liquid 1-Hexadecyl-3-methylimidazolium Bromide

Ionic liquid 1-hexadecyl-3-methylimidazolium bromide [C16mim]Br was synthesized by solvent-free alkylation of N-methylimidzole with hexadecyl bromide. A large transparent single crystal of 1-hexadecyl-3-methylimidazolium bromide monohydrate （[C16mim]Br·H2O）, 4 mm in length, was firstly obtained in the water-trichloromethane-toluene growth system （Vwater＇Vtrichloromethane＇Vtoluene = 0.1：1：2）. The crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in the triclinic system, space group P1, with a = 5.4962（15）, b = 7.839（2）, c = 27.279（8） A, α = 94.375, β = 91.500, γ = 101.999°, Z = 2, V = 1145.2（5） A3, C20H41BrN2O, Mr = 405.46, Dc = 1.176 Mg/m3, μ = 1.804 mm^-1, F（000） = 436, the final R = 0.0523 and wR = 0.1345. The 3D supramolecular structure is constructed through weak interactions between imidazolium cations, Br- anions and lattice water molecules. The long alkyl chain to the imidazolium ring and lattice water molecules play an important role in the self-assembly process. Moreover, it is proposed that [C16mim]Br in water has aggregation behavior and the possible self-assembled structure is the interdigitated pattern. Finally, thermal stability of [C16mim][Br]·H2O was also studied by DSC and TGA analysis.     

多元体系中谐波对EXAFS振幅的影响

本文给出了多元体系中谐波对EXAFS振幅的影响的计算方法,并以实例计算和测量了这种影响,两者结果相符。 关键词：     

A NEW POLYMER-BOUND 1,2-DIOL AS A PROTECTING AGENT FOR SYMMETRICAL DIALDEHYDE

A novel polymer-bound 1,2-diol, 3-polystyrylsulfonyl-1,2-propanediol (6) had been prepared by the reaction of sodium polystyrylsulfinate with allyl bromide, followed by oxidation and. hydrolysis or directly with 3-chloro-1,2-propanediol in the presence of a phase transfer catalyst, n-tetrabutylammonium iodide. The capacity of resin 6 for terephthaidehyde reached 1.43 mmol/g. The aldehydic groups attached to polymer 6 reacted with hydroxylamine hydrochloride or reduced by sodium borohydride giving p-formylbenzaldoxime (yield: 89%)and p-formyl-benzalcohol (yield: 734%), respectively. The high yields of these polymer-supported reactions showed that the polymer 6 possessed the effective isolation of its reactive sites.     

质子与裂变核238U反应的理论计算

利用球型光学模型、耦合道理论、核内级联、激子模型、蒸发模型、带宽度涨落修正的Hauser-Feshbach模型,Bohr-Wheeler裂变理论,对入射能量从阈能到200 MeV的p+²³⁸U各种反应进行了计算,计算结果和实验符合较好.     

Ce(Ⅳ)和Ce(Ⅲ)化合物系列的X射线光电子能谱研究

用XPS研究了标称四价铈盐系列:硫酸铈铵、硫酸铈、二苯基羟乙酸铈、碘酸铈、过氧化铈、二氧化铈以及三价铈盐系列:草酸亚铈、硫酸亚铈、二苯基羟乙酸亚铈、碘酸亚铈和氯化亚铈.结果表明,上述标称四价铈盐都属于混合价化合物,其Ce3d电子能谱呈现Ce⁴⁺和Ce³⁺的二组谱线结构的混合.在真空中加热后CeO₂的Ols电子能谱有两个氧峰,这说明 Ce(4f⁰)O(2p^π)←→Ce(4f¹)O(2p^n-1) 类型价态波动的可能性较大.三价铈盐的3d谱线的低结合能端约3.5—4eV处则存在摔落伴峰.     

非自治单种群时滞Kolmogorov系统的持续性和灭绝性

研究非自治单种群时滞Kolmogorov系统,给出了该系统中种群持续和灭绝的充分条件,这些结果与相应的非自治单种群Kolmogorov系统的有关结果相似.