Transition metal 1,2-bidentate thiolates as building blocks and their construction into cluster complexes

Simple fragments of transition metal 1,2-bidentate thiolates, the so-called building blocks of the general compositions ML₃, ML₂, ML, M(O)L₂, ML₂L, MLL, etc. have been proposed to constitute the di-, tri- and tetranuclear complexes concerned in this review. Structureal regularities and characteristics have been discussed and summarized according to the thiolato ligands edt and pdt, bdt and tdt, mp, and mpo, and mpp, respectively.Abbreviations H₂mpo o-mercaptophenol - Hmpo 2-mercaptopyridine-N-oxide - R₂dtc N,N-dialkyldithiocarbamate - Haet 2-aminoethanethiol - H₂bdt o-benzenedithiol - H₂pdt 1,2-propanedithiol - H₂tdt toluene-3,4-dithiol - Hmpp-mppH bis-(3-hydroxy-2-pyridyl)disulfide - Hmp-mpH bis-(2-oxyphenyl)disulfide - H₂edt 1,2-ethanedithiol - dppe 1,2-bis(diphenylphosphino)ethane - H₂tedt 3,4,5,6-tetrachlorobenzene-1,2-dithiol - H₂tpdt 3-thiapentane-1,5-dithiol - H₂mnt maleonitriledithiol - Him imidazole - Bz benzyl - py pyridine     

聚氨酯分子印章的制备和表征

“软平板印刷”微结构制备技术为微米和亚微米器件的制备提供了一条新的途径 [1] ,已被电子学家和材料学家所应用 ,近年来进入了生物学领域[2 ] .本实验室将这一方法与生物分子电子学相结合 ,提出了用于 DNA芯片在片合成的分子印章法 [3,4 ] .分子印章法的实质是接触压印与组合化学相结合的固相界面反应 .聚二甲氧基硅氧烷 ( PDMS)是一种软印刷的优良材料 [5] ,但是由于其疏水性和较差的机械性能 ,必须对其进行改性才能用来制备 DNA分子印章 [6 ] .　　聚氨酯作为一种功能材料 ,由于分子中交替的软、硬链段及其不同的热动力学性能而形成…     

Unlabeled Fluoroimmunoassay with a Europium Chelate

Unlabeled fluoroimmunoassay with a europium chelate is described. The recommended method is simple because the complicated labeling process is omitted. The recovery of some samples ranges from 91 to 111%. The relative standard deviation of the method is less than 10%. The detection limit is about 10⁻¹⁰mol liter⁻¹antigen.     

LC-MS/MS定量测定大鼠和人肝微粒体孵育液中丁苯酞浓度方法的建立

正丁苯酞(n-butylphthalide,NBP),又名芹菜甲素,是我国心脑血管领域第一个拥有自主知识产权的药物,它具有很强的抗脑缺血损伤作用,而毒副作用较低[1-2].     

Anderson-B-型多金属氧酸盐[Co(2,2''-bipy)3]H-[Al(OH)6(Mo6O18)]·5H2O的合成及晶体结构

以AlCl3·6H2O、Na2MoO4·2H2O、CoCl2·6H2O和2,2'-联吡啶为主要原料合成了Anderson-B-型多金属氧酸盐[Co(2,2'-bipy)3]H[Al(OH)6(Mo6O18)]·5H2O,进行了红外光谱、紫外光谱、差热分析和单晶结构测定.晶体学测定结果表明,化合物属于三斜晶系,Pi空间群,晶胞参数:a=1.216 0(2),b=1.221 5(2),c=1.780 0(4)nm,α=86.83(3)°,β=88.76(3)°,γ=89.82(3)°,V=2.639 4(9)nm3,Z=2,R1=0.079 4,wR2=0.176 6.化合物结构分析表明,在晶体学上,标题化合物分子是由1个[Co(2,2'-bipy)3]2+配阳离子,1个H+离子,2个1/2[Al(OH)6(Mo6O18)]3-多阴离子和5个结晶水分子组成.多阴离子[Al(OH)6(Mo6-O18)]3-借助水分子和金属配离子通过超分子作用形成二维网状结构,网状结构之间又借助超分子作用形成三维无限伸展结构.差热分析表明,标题化合物的失重过程分为2步,多阴离子骨架破坏温度为547.5℃.     

双核镍(Ⅱ)配合物的合成、晶体结构和磁性质

合成了通过N-N键桥联的不对称的N₂O₃席夫碱配体(H₃L)的镍(Ⅱ)配合物[Ni₂(HL)₂]₂(DMF)₈(H₂O)₂ (1)。配合物晶体属于三斜晶系，空间群为P1，a=1.273 5(2) nm，b=1.360 4(3) nm，c=1.427 6(3) nm，α=85.358(4)°，β=63.513(3)°，γ=79.545(4)°，V=2.176 8(7) nm³，Z=1，F(000)=980，R₁=0.073 6。配合物1的不对称单元中含有两个双核结构Ni₂(HL)₂(DMF)₂(H₂O)₂ (Ⅰ)和Ni₂(HL)₂(DMF)₄ (Ⅱ)以及两个DMF溶剂分子。通过酚基氧原子桥联的镍-镍距离分别为：Ni(1)-Ni(1A)，0.308 4 nm；Ni(2)-Ni(2B)，0.310 3 nm(对称操作：A：1-x，2-y，-z；B：1-x，1-y，1-z)。金属镍(Ⅱ)离子采取扭曲的八面体配位构型，一个配体的NO₂三齿配位单元和另一个配体的酚基氧原子位于赤道面位置，两个溶剂分子占据轴向位置。晶体中存在着分子内以及分子与溶剂分子间的两种氢键作用。配合物1的变温磁化率测定表明，Ni(Ⅱ)离子之间的反铁磁耦合作用在它的磁性质中起主导作用。     

用非等温TG、DTG曲线研究由邻香兰素衍生的Cu(Ⅱ)希夫碱配合物的热分解反应动力学

研究表明,许多过渡金属配合物具有抗癌抑菌性能,刃我们在以前工作基础上又合成了三种由邻香兰素衍生的新型希夫碱配合物,对他们进行了非等温热重分析,并采用积分法和微分法相结合的方法,推断出了它们的热分解反应机理.     

STUDIES OF MULTICOMPONENT COMPLEX OXIDE CATALYSTS FOR OXIDATIVE COUPLING OF METHANE VI.SURFACE BASICITY AND SURFACE ACTIVE OXYGEN SPECIES OF LiTi_xLa_(1-x)O_2 λ MULTICOMPONENT OXIDE CATALYSTS

The surface basicity of Ti-La-Li multicoinponent oxides has been investigated by means of CO2-TPD. The experiment results show that C2 (C2H6 C2H4) selectivity is related to surface basic strength. The surface active oxygen species have also been characterized by means of XPS, O2-TPD and so on. It has been indicated that C2 selectivity and CH4 conversion are correlated with lattice oxygen and the adsorbed oxygen on the surface of the catalyst respectively In the O2-TPD experiments, it has also been found that there are three kinds of oxygen species on the surface of the series catalvsts, which are a (100℃ 750℃) Among them α-oxvgen causes deep oxidation whileβand γ oxygen species are related to oxidalive coupling of methane (OCM).     

1,9—双（1′—苯基—3′—甲基—5′—氧代吡唑—4′—基）壬二酮—（1,9）与三？…

研究了１，９－双（１′－苯基－３′－甲基－５′－氧代吡唑－４′－基）壬二酮－（１，９）（ＢＰＭＰＮＤ，Ｈ２Ａ）与三辛基氧膦（ＴＯＰＯ，Ｂ）的氯仿溶液，从硝酸介质中对Ｌａ（Ⅲ），Ｄｙ（Ⅲ）的协同萃取，计算了体系的酸性协萃系数ＲＡ和协萃系数Ｒ，用斜率法测得协萃合物的组成ＬａＡ．ＨＡ．Ｂ和ＤｙＡ．ＨＡ．Ｂ计算了协萃取平衡常数，研究了温度对协萃反应的影响，用萃取法制得了固态协萃合物，并对其组成，ＩＲ及ＴＧ     

亚磺化脱卤试剂在有机合成中的应用

本文综述了亚磺化脱卤试剂在有机合成中的应用。特别是氟烷基化反应中的应用。