Microwave-assisted Regioselective 1-O-Deacylation of Peracylated Glycopyranoses on Alumina

A facile, rapid and regioselective method for the 1-O-deacylation of peracylated glycopyranoses is described which occurs under mild conditions by absorption onto alumina using microwave irradiation.     

Interface Optical Phonon Modes and Frohlich Electron-Phonon Interaction Hamiltonian in a Multi-shell Spherical Nanoheterosystem

Under dielectric continuum approximation, interface optical (IO) phonon modes and the Frohlich electron-IO phonon interaction Hamiltonian in a multi-shell spherical nanoheterosystem were derived and studied. Numericalcalculations on three-layer and four-layer CdS/HgS spherical nanoheterosystems have been performed. Results revealthat there are four IO phonon modes for the three-layer system and six IO phonon modes for the four-layer system.On each interface, there are two IO phonon modes, the frequency of one is between WTO,CdS and WLO,CdS, and that ofthe other is between WTO,HgS and WLO,HgS. With the increasing of quantum number l, the frequency of each IO modeapproaches one of the two frequency values of the single CdS/HgS heterostructure, and the potential for each IO modeis more and more localized at a certain interface, furthermore, the coupling between the electron-lO phonons becomes weaker.     

Comment on “A Hierarchy of Integrable Nonlinear Lattice Equations and New Integrable Symplectic Map“

Comment on a recent paper on Commun. Theor. Phys. (Beijing, China) 38 (2002) pp. 523-528.     

马科维兹资产组合选择模型的旋转算法

提出线性不等式组的一种旋转算法，并用其求解马科维兹资产组合选择模型，此算法每次迭代约需n^2次乘法和加法，其中n是模型中变量的数目，在微机上运行Delphi程序的实验结果表明，从上海和深圳股市1072支股票70期周末收盘价计算出20个最优投资组合仅需314次迭代和45s。     

风冷热泵冷热水机组动态过程仿真

本文给出了风冷热泵冷热水机组动态过程模型。系统的高、低压段被分成制冷剂侧、管壁、以及水或空气侧三个控制容积。针对每个控制容积建立了质量和能量平衡的微分方程。由于压缩机、热力膨胀阀阀体、以及四通换向阀具有较小的热惯性,因而采用稳态模型描述压缩过程、膨胀过程、以及内泄露过程。膨胀阀感温包中的制冷剂温度对于蒸发器出口温度的延迟用一阶惯性环节来描述。通过“预测-校正”和“自适应步长”方法实现系统仿真。仿真结果与测试数据吻合良好。     

An Improved Synthesis of Retinoic Acid from β-Ionone

A convenient and large-scale preparation of retinoic acid 1 from β-ionone in five steps with 38% overall yield is described.The key steps are the epoxidization of 2 with a new methylated agent and the condensation 4 with tetraethyl methylenediphophonate in one-pot procedure to prepare 6.     

原子的吸收光谱和发射光谱的演示

介绍了利用光学多道分析仪和投影仪在课堂上实时演示原子的吸收光谱和发射光谱的实验方法。     

Hydrothermal Synthesis and Structure of [（PbCl2）μ-PyZ）1/2]n （Pyz = Pyrazine）

1 INTRODUCTION Because of the flexibility of Pb(II) coordination sphere and the nonstereospecific nature of halide anions[1], the chemistry of lead halide complexes has been developed in recent years. Especially PbX2- based coordination polymers with nitrogen-contain- ing Lewis bases have attracted renewed interest[2～11]. The choice of ligand and the reaction condition are of great importance in determining the final topo- logy of the supramolecular materials. But the avail- able struc…     

高压沿面放电烟气脱硫技术动态实验研究

本文针对高压沿面放电活化气体的烟气脱硫技术,在静态实验研究的基础上进行了实验室冷态动态的实验研究。设计了便于反应和测量的动态实验装置。实验解释了电子束法脱硫技术中导致氨气泄漏的部分原因,验证了高压沿面放电脱硫技术可以在较低的运行电压下,达到提高脱硫效率,减少氨气泄漏的作用。     

Fe-V-N稀合金中空位复合体特性的研究(Ⅱ)

本文利用离散变分法,集团模型和三维数值弛豫技术,研究了Fe-V-N稀合金中V-N-空位复合体的几何构型,正电子湮没特性和电子结构。根据正电子湮没寿命实验的结果和总能量极小原理,确定了V和N在V-N-空位复合体中的最佳占据位置。分析了V-N-空位复合体的成键特性和电荷转移情况。 关键词：