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991.
Elastic-plastic analyses on the residual stresses and curvature of the film/substrate bilayer system
During thermal cycling, the residual stresses are often generated in the film/substrate bilayer due to the material mismatch between the substrate and the film. If the thickness of the film is relatively high, the thermal residual stresses in it may be of different signs. When the film is subjected to elastic-plastic deformation, two plastic zones with different thicknesses may be generated in the film at a significantly high temperature difference. In this paper, a theoretical model which reflects the complete history of thermal residual stresses and curvatures in the elastoplastic film/substrate bilayer system is developed. Solutions are derived to estimate the residual stresses and curvature in the film as functions of temperature difference. The case of Al/Si system is used to illustrate the implementation of this model. Results show that the critical temperature difference at which the second plastic zone near the film surface is generated near the Al film surface is dependent on the film thickness. The strain hardening of the film has an obvious influence on the magnitude of residual stresses within the film at high temperature difference. 相似文献
992.
Synthesis of micro- or nano-crystalline diamond films on WC-Co substrates with various pretreatments by hot filament chemical vapor deposition 总被引:4,自引:0,他引:4
Diamond films deposited on tungsten carbide can lead to major improvements in the life and performance of cutting tools. However, deposition of diamond onto cemented tungsten carbide (WC-Co) is problematic due to the cobalt binder in the WC. This binder provides additional toughness to the tool but results in poor adhesion and low nucleation density of any diamond film. A two-step chemical etching pretreatment (Murakami reagent and Caro acid, (MC)-pretreatment) and a boronization pretreatment have both been used extensively to improve adhesion of CVD diamond film on WC-Co substrates. Here we discuss the applicability of MC-pretreatment for a range of Co-containing WC-Co substrates, and demonstrate a controlled synthesis process based on liquid boronizing pretreatment for obtaining smooth and dense micro- or nano-crystalline diamond films on high Co-containing WC-Co substrates. Substrate treatments and deposition parameters were found to have major influences on the smoothness, structure and quality of the diamond films. The best quality diamond films were achieved under conditions of relatively high substrate temperature (Ts) and the best adhesion was achieved at Ts = 800 °C. 相似文献
993.
Zinc peroxide nanoparticles having grain size less than 5 nm were synthesized using pulsed laser ablation in aqueous solution in the presence of different surfactants and solid zinc target in 3% H2O2. The effect of surfactants on the optical and structure of ZnO2 was studied by applying different spectroscopic techniques. Structural properties and grain size of the synthesized nanoparticles were studied using XRD method. The presence of the cubic phase of zinc peroxide in all samples was confirmed with XRD, and the grain sizes were 4.7, 3.7, 3.3 and 2.8 nm in pure H2O2, and H2O2 mixed with SDS, CTAB and OGM respectively. For optical characterization, FTIR transmittance spectra of ZnO2 nanoparticles prepared with and without surfactants show a characteristic ZnO2 absorption at 435-445 cm−1. FTIR spectrum revealed that the adsorbed surfactants on zinc peroxide disappeared in case of CTAB and OGM while it appears in case of SDS. This could be due to high critical micelles SDS concentration comparing with others which is attributed to the adsorption anionic nature of this surfactant. Both FTIR and UV-vis spectra show a red shift in the presence of SDS and blue shift in the presence of CTAB and OGM. The blue shift in the absorption edge indicates the quantum confinement property of nanoparticles. The zinc peroxide nanoparticles prepared in additives-free media was also characterized by Raman spectra which show the characteristic peaks at 830-840 and 420-440 cm−1. 相似文献
994.
A facile, low-temperature, and low-cost chemical route has been developed to prepare ZnO nanowire and nanosphere compound structures. The morphology, structure, and composition of the yielded products have been examined by field-emission scanning electron microscopy, transmission electron microscopy, and X-ray diffraction measurements. We have systematically investigated the optical properties of the ZnO nanostructures by micro-Raman, photoluminescence, and transmission spectroscopy. The results demonstrate that the yielded ZnO nanostructures possess good optical quality with high light absorption. We have further successfully employed the obtained ZnO compound nanostructures in dye-sensitized solar cells. The light-to-electricity conversion results show that the compound nanostructure exhibits a significant enhancement of short-circuit current density due to the increased surface area and light scattering in the compound nanostructures. The present chemical route provides a simple way to synthesize various compound nanostructures with high surface area for nanodevice applications. 相似文献
995.
E2SiO5 thin films were fabricated on Si substrate by reactive magnetron sputtering method with subsequent annealing treatment. The morphology properties of as-deposited films have been studied by scanning electron microscope. The fraction of erbium is estimated to be 23.5 at% based on Rutherford backscattering measurement in as-deposited Er-Si-O film. X-ray diffraction measurement revealed that Er2SiO5 crystalline structure was formed as sample treated at 1100 °C for 1 h in O2 atmosphere. Through proper thermal treatment, the 1.53 μm Er3+-related emission intensity can be enhanced by a factor of 50 with respect to the sample annealed at 800 °C. Analysis of pump-power dependence of Er3+ PL intensity indicated that the upconversion phenomenon could be neglected even under a high photon flux of 1021(photons/cm2/sec). Temperature-dependent photoluminescence (PL) of Er2SiO5 was studied and showed a weak thermal quenching factor of 2. Highly efficienct photoluminescence of Er2SiO5 films has been demonstrated with Er3+ concentration of 1022/cm3, and it opens a promising way towards future Si-based light source for Si photonics. 相似文献
996.
Esmaeil Shahriari W. Mahmood Mat Yunus Kazem Naghavi Z.A. Talib 《Optics Communications》2010,283(9):1929-1932
Nonlinear properties of Au nano-fluid prepared by γ-radiation method at different concentrations were investigated. Measurements of nonlinear refractive index and nonlinear absorption coefficient were carried out using a single beam Z-scan technique. A green CW laser beam operated at 532 nm was used as excitation source. The Au nano-fluid shows a good third order nonlinear response. The sign of the nonlinear refractive index is found to be negative and the magnitude is in the order of 10−7 cm2/W. This nonlinear effect increases as the concentration increases from 3.119 × 10−4 to 2.354 × 10−3 M which correspond to particle sizes of 4.0-30.5 nm, respectively. A good linear relationship was obtained between nonlinear refractive index and concentration. However the relationship between nonlinear refractive index and particle size was nonlinear behavior. 相似文献
997.
Y. H. Zhang X. H. Zhou Q. Z. Zhao X. F. Sun X. G. Lei Y. X. Guo Z. Liu X. F. Chen Y. T. Zhu S. X. Wen G. J. Yuan X. A. Liu 《Zeitschrift für Physik A Hadrons and Nuclei》1996,355(1):335-336
High spin states of the odd-odd162Lu nucleus have been studied via147Sm(19F,4nγ)162Lu reaction at 95 MeV beam energy. Level scheme for yrast band based onπ[h11/2 v[i13/2] quasiparticle configuration was established up to I π = (23?) for the first time. This band shows the signature inversion in energy before backbending generally appeared in this mass region. It is stressed that the signature splitting in162Lu is larger than that in the160Tm nucleus. 相似文献
998.
999.
S. E. Kubatkin A. Ya. Tzalenchuk Z. G. Ivanov P. Delsing R. I. Shekhter T. Claeson 《JETP Letters》1996,63(2):126-132
We report on a successful attempt to fabricate a Coulomb blockade electrometer consisting of an ultrasmall YBa2Cu3O7−δ (YBCO) island coupled to two gold electrodes through a high-resistance native surface tunnel barrier. A third electrode placed
near the island was used as an electrostatic gate. Spectra typical for tunneling into the YBCO superconductor were reproducibly
measured. At temperatures below 0.5 K the low-bias conductance was suppressed by the Coulomb blockade. The blockade could
be periodically varied by the gate potential. An external magnetic field of up to 5 T strongly influenced the transport via
the island but without any change in the period of the Coulomb oscillations.
Pis’ma Zh. éksp. Teor. Fiz. 63, No. 2, 112–117 (25 January 1996)
Published in English in the original Russian journal. Edited by Steve Torstveit. 相似文献
1000.
Ferromanganese nodules from Flysh deposits of West Carpathian Mountains were studied by Mössbauer spectroscopy method. The presence of small-grain goethite and hematite was established and grain sizes roughly estimated. 相似文献