首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   13408篇
  免费   2221篇
  国内免费   1444篇
化学   9223篇
晶体学   124篇
力学   902篇
综合类   92篇
数学   1640篇
物理学   5092篇
  2024年   47篇
  2023年   286篇
  2022年   487篇
  2021年   531篇
  2020年   546篇
  2019年   486篇
  2018年   471篇
  2017年   407篇
  2016年   583篇
  2015年   647篇
  2014年   743篇
  2013年   989篇
  2012年   1132篇
  2011年   1161篇
  2010年   800篇
  2009年   747篇
  2008年   822篇
  2007年   777篇
  2006年   697篇
  2005年   569篇
  2004年   416篇
  2003年   353篇
  2002年   326篇
  2001年   284篇
  2000年   237篇
  1999年   285篇
  1998年   267篇
  1997年   192篇
  1996年   218篇
  1995年   216篇
  1994年   186篇
  1993年   162篇
  1992年   129篇
  1991年   143篇
  1990年   143篇
  1989年   108篇
  1988年   92篇
  1987年   78篇
  1986年   59篇
  1985年   62篇
  1984年   28篇
  1983年   33篇
  1982年   26篇
  1981年   20篇
  1980年   13篇
  1979年   10篇
  1978年   8篇
  1977年   10篇
  1974年   6篇
  1973年   9篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
In this paper, a new method of boundary reduction is proposed, which reduces thesteady-state heat transfer equation with radiation. Moreover, a boundary element method is pre-sented for its solution and the error estimates of the numerical approximations are given.  相似文献   
32.
Applied Biochemistry and Biotechnology - A novel, anaerobic fermentation process is developed to produce calcium magnesium acetate (CMA) from cheese whey. CMA can be used as a noncorrosive road...  相似文献   
33.
Great interests have been accumulated in recent years in the chemistry and biochemistry of nitric oxide (NO) since the remarkable discoveries of its key roles in a wide range of human physiological processes. To elucidate the mechanistic details of NO migration from its donor to its acceptor, it is necessary to determine the Y-NO bind energy that registers the thermodynamic driving force for NO release and capture. In this paper the heterolytic and homolytic N-NO bond dissociation energies [ i. e., △Hhet(N-NO) and △Hhomo(N-NO)] for ten N-nitroso-p-substituted-benzensulfonyl methylamines in acetonitrile are offered, which were obtained from titration calorimetry and thermodynamic cycles, respectively (Scheme 1).  相似文献   
34.
工程上对片筏的力学分析,通常采用温克勒地基模型,且假定床基系数是常量。本则认为床基系数是坐标的函数,考虑了具有线性变化床基系数的地基上的片筏,利用伽辽金法求得周边固支片筏在均布荷载作用下的挠度。所得结果颇具一般性且实用价值更高。  相似文献   
35.
For improved mechanical and water‐swelling properties of chitosan films, a series of transparent films were prepared with dialdehyde starch as a crosslinking agent. Fourier transform infrared and X‐ray analysis results demonstrated that the formation of Schiff's base disturbed the crystallization of chitosan. The mechanical properties and water‐swelling properties of the films were significantly improved. The best values of the tensile strength and breaking elongation were 113.1 MPa and 27.0%, respectively, when the dialdehyde starch content was 5%. All the crosslinked films still retained obvious antimicrobial effects toward S. aureus and E. coli, and they showed potential for biomedical applications. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 993–997, 2003  相似文献   
36.
The millimeter wave spectrum of the isotopically substituted CO dimer, (13C16O)2, has been studied for the first time, confirming and extending a recent infrared study. Eighty-seven transitions in the 77-180 GHz region have been assigned and analyzed in terms of a model-independent term value scheme involving 57 rotational levels with J=0-8. The levels can be classified into 7 “stacks” which have symmetry classifications of either A/B+ or A+/B and K-values of either 0 or 1. For the normal isotope, symmetry and nuclear spin statistics cause alternate rotational levels to be missing, but for (13C16O)2 all levels are present with an intensity alternation of 1:3 between A and B symmetries. The four A/B+ stacks have not previously been observed, and the lowest of them establishes the tunneling splitting of (13C16O)2 to be 3.769 cm−1, slightly larger than the (12C16O)2 value of 3.731 cm−1. A large amount of precise experimental data is now available for the CO dimer, which should lead to greater theoretical insight into its structure and tunneling dynamics.  相似文献   
37.
The synthesis of three new series of chiral Schiff's bases containing benzilideneaniline and 2-hydroxybenzilideneaniline moieties as mesogenic cores is presented. Differential scanning calorimetry, optical polarizing microscopy and X-ray diffraction measurements were used to study the phase transition temperatures and behaviour. The results reveal that most of these materials show chiral smectic mesomorphism.  相似文献   
38.
Consideringsystem:x=φ(y)-F(x),y=-g(x){(E)inwhichF(x)=∫x0f(t)dt,f(x),g(x),φ(y)arecontinuous,andsatisfytheconditionswhichensur...  相似文献   
39.
Most papers in scheduling research have treated individual job processing times as fixed parameters. However, in many practical situations, a manager may control processing time by realloeating resources. In this paper, authors consider a machine scheduling problemwith controllable processing times. In the first part of this paper, a special case where the pro-cessing times and compression costs are uniform among jobs is discussed. Theoretical results are derived that aid in developing an O(n^2) algorithm to slove the problem optimally. In the second part of this paper, authors generalize the discussion to general case, An effective heuristic to the genera/ problem will be presented.  相似文献   
40.
Results from a systematic experiment on isolated perfused rat heart and isolated myocytes of adult rat showed that the mechanism of calcium influx during myocardial ischemia-reperfusion is due to the development of intracellular sodium overload during ischemic period; on reperfusion, the high intracellular Na+ content activated the reverse direction of Na(+)-Ca2+ exchange over myocardial sarcolemma (SL), thus a large quantity of extracellular Ca2+ fluxed over the SL to the intracellular space, forming a condition of intracellular Ca2+ overload, which leads to irreversible damage of the myocardium.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号