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921.
γ,δ-Epoxy tin compounds underwent divergent reactions depending upon the substitution pattern of the substrates as well as upon Lewis acids used as the indueer. 相似文献
922.
923.
Kimitsuna Watanabe 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2010,86(1):11-39
In animal mitochondria, several codons are non-universal and their meanings differ depending on the species. In addition, the tRNA structures that decipher codons are sometimes unusually truncated. These features seem to be related to the shortening of mitochondrial (mt) genomes, which occurred during the evolution of mitochondria. These organelles probably originated from the endosymbiosis of an aerobic eubacterium into an ancestral eukaryote. It is plausible that these events brought about the various characteristic features of animal mt translation systems, such as genetic code variations, unusually truncated tRNA and rRNA structures, unilateral tRNA recognition mechanisms by aminoacyl-tRNA synthetases, elongation factors and ribosomes, and compensation for RNA deficits by enlarged proteins. In this article, we discuss molecular mechanisms for these phenomena. Finally, we describe human mt diseases that are caused by modification defects in mt tRNAs. 相似文献
924.
925.
H. Matsuoka Y. Watanabe M. Maeda T. Kawakami Y. Kubota 《Physica C: Superconductivity and its Applications》2009,469(15-20):1189-1191
We fabricated MgB2 bulks by an in situ Mg diffusive reaction method from compacted B and compacted mixtures of Mg and B respectively. All samples were sintered at 1100 °C for 2 h. MgO impurity phase, density, and critical current density (Jc) were found to be dependent of the starting amount of mixing Mg powder. We also found that the MgO formation in MgB2 matrix was not mainly attributed to the starting amount of additional Mg powder for Mg diffusive reaction. This indicates that MgO presented in the starting Mg powder is hardly diffused into compacted B. 相似文献
926.
927.
Jorge S. Ayala-Arenas Reneu L. Andrioli Jr S. Watanabe M. Matsuoka B. C. Bhatt 《Radiation Physics and Chemistry》2001,61(3-6):417-419
Morganite, a pink beryl with the chemical formula Be3Al2Si6O18, was investigated in terms of its thermally stimulated luminescence (TL) and electron paramagnetic resonance (EPR) properties due to point defects. Atomic hydrogen H°-centers were induced by γ-radiation and shown to be responsible for a 165°C TL peak. The Fe3+-center concentration was found to increase with γ-dose, observed by both TL and EPR measurements, decreasing with thermal treatments beyond 250°C. A mechanism for emission around 315°C is proposed. 相似文献
928.
Normal-phase HPLC conditions have been developed for separating the C17(3) isoprenoid isomers, which are expected to be formed as biosynthetic intermediates of chlorophyll (Chl) a, Chl a' (C13(2)-epimer of Chl a), pheophytin (Pheo) a and protochlorophyll (PChl). The application of these conditions to pigment composition analysis of greening etiolated barley leaves allowed us to detect, for the first time, the C17(3) isomers of Chl a', a possible constituent of the primary electron donor of photosystem (PS) I, P700, and those of Pheo a, the primary electron acceptor of PS II, in the very early stage of greening. The C17(3) isomer distribution patterns were approximately the same between Chl a and Chl a', but significantly different between Pheo a and Chl a', probably reflecting the similarity and difference, respectively, in the biosynthetic pathways of these pigment pairs. 相似文献
929.
D. Watanabe T. Yoshida C. Allen T. Tanabe 《Journal of Radioanalytical and Nuclear Chemistry》2007,272(3):461-465
This work is devoted to enhance gamma-ray radiolysis of CO2 with the assistance of coexisting metal materials. It is found that lower energy electrons which are generated through interactions
of γ-photons with the coexisting metal materials and ejected to CO2 gas actually enhance decomposition of CO2 to produce CO. The increment of CO production agrees well with the increment of the deposited energy in CO2, given by the lower energy electrons emitted from the materials, which is calculated by a numerical simulations code MCNP.
It is also suggested that the volumetric decomposition of CO2 dominates the decomposition at the material’s surface. 相似文献