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11.
Zinicovscaia Inga Culicov Otilia A. Duliu Octavian G. Yushin Nikita S. Gundorina Svetlana F. 《Journal of Radioanalytical and Nuclear Chemistry》2018,316(2):629-634
Journal of Radioanalytical and Nuclear Chemistry - To evidence the efficiency of cigarette filter we have determined the content of 27 major and trace elements in two brands of filter and... 相似文献
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Photocyclization of 1, 1′-Polymethylene-di-2-pyridones . Benzophenone sensitized irradiation of the four dipyridones 1-4 gave the internal photocyclization products 6 (64%, Scheme 4), 7 (60%, Scheme 5), 8 (Scheme 6), and 11 (26%, Scheme 7), respectively. The decamethylene compound 5 yielded only polymeric material. The primary [2+2] photoproduct 8 from dipyridone 3 (Scheme 6) is relatively unstable. Further irradiation or heating to 65° induced a Cope rearrangement to give compound 9 which, on heating to 137°, was converted into the isomeric compound 10 . This product, as well as the other photoproducts mentioned, are rearranged back to their respective starting materials upon direct irradiation with 254 nm light or by heating to higher temperatures. The various possibilities for cycloadditions of pyridones are discussed as well as the possible factors which are responsible for the highly regioselective photoreactions of the dipyridones 1–4 . 相似文献
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Ishimatsu R Izadyar A Kabagambe B Kim Y Kim J Amemiya S 《Journal of the American Chemical Society》2011,133(40):16300-16308
Here, we report on the first electrochemical study that reveals the kinetics and molecular level mechanism of heterogeneous ion-ionophore recognition at plasticized polymer membrane/water interfaces. The new kinetic data provide greater understanding of this important ion-transfer (IT) process, which determines various dynamic characteristics of the current technologies that enable highly selective ion sensing and separation. The theoretical assessment of the reliable voltammetric data confirms that the dynamics of the ionophore-facilitated IT follows the one-step electrochemical (E) mechanism controlled by ion-ionophore complexation at the very interface in contrast to the thermodynamically equivalent two-step electrochemical-chemical (EC) mechanism based on the simple transfer of an aqueous ion followed by its complexation in the bulk membrane. Specifically, cyclic voltammograms of Ag(+), K(+), Ca(2+), Ba(2+), and Pb(2+) transfers facilitated by highly selective ionophores are measured and analyzed numerically using the E mechanism to obtain standard IT rate constants in the range of 10(-2) to 10(-3) cm/s at both plasticized poly(vinyl chloride) membrane/water and 1,2-dichloroethane/water interfaces. We demonstrate that these strongly facilitated IT processes are too fast to be ascribed to the EC mechanism. Moreover, the little effect of the viscosity of nonaqueous media on the IT kinetics excludes the EC mechanism, where the kinetics of simple IT is viscosity-dependent. Finally, we employ molecular level models for the E mechanism to propose three-dimensional ion-ionophore complexation at the two-dimensional interface as the unique kinetic requirement for the thermodynamically facilitated IT. 相似文献
14.
Shunrui Luo Dr. Kostiantyn Turcheniuk Ah-Young Song Aashray Narla Doyoub Kim Dr. Alexandre Magasinsky Prof. Gleb Yushin 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(1):411-416
Technologically important composites with enhanced thermal and mechanical properties rely on the reinforcement by the high specific strength ceramic nanofibers or nanowires (NWs) with high aspect ratios. However, conventional synthesis routes to produce such ceramic NWs have prohibitively high cost. Now, direct transformation of bulk Mg-Li alloys into Mg alkoxide NWs is demonstrated without the use of catalysts, templates, expensive or toxic chemicals, or any external stimuli. This mechanism proceeds through the minimization of strain energy at the boundary of phase transformation front leading to the formation of ultra-long NWs with tunable dimensions. Such alkoxide NWs can be easily converted in air into ceramic MgO NWs with similar dimensions. The impact of the alloy grain size and Li content, synthesis temperature, inductive and steric effects of alkoxide groups on the diameter, length, composition, ductility, and oxidation of the produced NWs is discussed. 相似文献
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Gogotsi Y Dash RK Yushin G Yildirim T Laudisio G Fischer JE 《Journal of the American Chemical Society》2005,127(46):16006-16007
The poor performance of hydrogen storage materials continues to hinder development of fuel cell-powered automobiles. Nanoscale carbons, in particular (activated carbon, exfoliated graphite, fullerenes, nanotubes, nanofibers, and nanohorns), have not fulfilled their initial promise. Here we show that carbon materials can be rationally designed for H2 storage. Carbide-derived carbons (CDC), a largely unknown class of porous carbons, are produced by high-temperature chlorination of carbides. Metals and metalloids are removed as chlorides, leaving behind a collapsed noncrystalline carbon with up to 80% open pore volume. The detailed nature of the porosity-average size and size distribution, shape, and total specific surface area (SSA)-can be tuned with high sensitivity by selection of precursor carbide (composition, lattice type) and chlorination temperature. The optimum temperature is bounded from below by thermodynamics and kinetics of chlorination reactions and from above by graphitization, which decreases SSA and introduces H2-sorbing surfaces with binding energies too low to be useful. Intuitively, pores of different size and shape should not contribute equally to hydrogen storage. By correlating pore properties with 77 K H2 isotherms from a wide variety of CDCs, we experimentally confirm that gravimetric hydrogen storage capacity normalized to total pore volume is optimized in materials with primarily micropores ( approximately 1 nm) rather than mesopores. Thus, in agreement with theoretical predictions, a narrow size distribution of small pores is desirable for storing hydrogen, while large pores merely degrade the volumetric storage capacity. 相似文献
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M.V. Rybin A.B. Khanikaev M. Inoue A.K. Samusev M.J. Steel G. Yushin M.F. Limonov 《Photonics and Nanostructures》2010,8(2):86-93
We present a study of a Fano resonance between a narrow Bragg band and disorder-induced continuum in photonic crystals where the continuum is either of the broad band Fabry-Pérot scattering in an imperfect one-dimensional photonic crystal or Mie scattering in an imperfect three-dimensional photonic crystal. Our experimental studies of synthetic opals have demonstrated how the Fano resonance may lead to a transmission spectrum exhibiting a Bragg dip with an asymmetric profile or a Bragg rise. 相似文献
20.
Channel coordination through a revenue sharing contract in a two-period newsboy problem 总被引:1,自引:0,他引:1
This paper studies channel coordination through revenue sharing contract between a single retailer and a single wholesaler in a two-period newsboy problem. Two models are discussed, a single-buying-opportunity model and a two-buying-opportunity model. We discuss how the revenue sharing ratio and the wholesale prices are to be determined in order to achieve channel coordination and a win–win outcome. We find that the wholesale prices are set to be lower than the retail prices and the optimal revenue sharing ratio is linearly increasing in the wholesale prices. The proposed revenue sharing contract has more flexibility than price protection, in that the optimal revenue sharing ratio can be settled reasonably through negotiation between the retailer and wholesaler. 相似文献