新型固相微萃取涂层直接检测样品中的3种多氯酚

利用聚乙二醇2000(PEG 2000)合成了聚乙二醇硅酯预聚物,并通过溶胶-凝胶法制备了含键合聚乙二醇硅酯的固相微萃取涂层,其使用最高温度为340℃。无需衍生化的情况下,采用顶空固相微萃取结合GC/FID的方法测定3种多氯酚的检出限为0.11~0.18 ng/L;线性范围达0.1~103μg/L,相对标准偏差(RSD,n=5)为4.24%~6.44%。土样中痕量多氯酚的加标回收率分别为108%、93.5%和73.7%。     

Impairment-aware QoS provisioning in dual-header OBS networks

Signal degradation due to physical impairments may result in unacceptable bit-error rates of received signals at the destination. Based on earlier work, we study the impairment-aware quality of service (QoS) provisioning problem in dual-header optical burst switching (OBS) networks that employ two control packets for each data burst. At an OBS node, the proposed algorithm schedule bursts for transmission by searching for available resources using admission control and preemption. The algorithm also verifies signal quality. Simulation results show that this algorithm is effective in providing QoS support in OBS networks while considering physical impairment effects.     

一种改进的2n因子乘积形式的逆矩阵求解算法

复杂结构的有限元分析需要耗费巨大的内存和计算机时间。在此过程中，有限元线性方程组的求解时间占很大比例，因此，发展高效的线性方程组求解算法是提高有限元分析效率的关键，针对矩阵求逆问题，该文将有限元方程组的系数矩阵视为等分块矩阵，并基于等分块矩阵的概念推广了传统的逆矩阵的n因子和2n因子乘积形式。推广后得到的这组乘积形式在适当条件下又分别可以退化到传统的逆矩阵的n因子2n因子乘积形式，应用基于推广后得到的这组乘积形式的求逆算法来求解板材冲压成形有限元数值模拟中的大型有限元线性方程组，结果表明，该算法可以显著地提高大型有限元线性方程组的求解效率。     

板材冲压成形变形局部化与动边界摩擦约束

提出适于具有强烈弯曲效应的大应变，大位移与界面摩擦三重非线性空间曲壳有限元列式。给出一种动边界摩擦约束的元级代数消元方法，就板材在方盒型冲头作用中压胀形过程，引入几种现代非经典塑性本构理论以及空单元技术，研究了成形过程中的变形局部化与断裂问题。     

全自动自适应网格细化

本文利用弹塑性误差估计模型，预示出金属成形数值模拟过程中网格细化时新网格尺寸，提出补角法修正锻件边界构形并利用三次Ｂ样条统一表达边界构形，实现了对边界细化并进而产生自适应细化网格。     

金属材料平面应变拉伸变形局部化有限元分析

本文对于涉及韧性金属大变形中颈缩与剪切带断裂一类高度非线性变形局部化问题进行了弹塑性有限元数值模拟。采用改进的Ｊ２形变理论微分形式公式与交叉三角形四边形单元有限元网格，详细研究了应变硬化指数及初始表面不均匀特性的平面应变拉伸颈缩和剪切带形成的综合影响，给出此类问题的断裂机制图。     

Identification of metabolites of adonifoline,a hepatotoxic pyrrolizidine alkaloid,by liquid chromatography/tandem and high‐resolution mass spectrometry

Hepatotoxic pyrrolizidine alkaloid (HPA)‐containing plants have always been a threat to human and livestock health worldwide. Adonifoline, a main HPA in Senecio scandens Buch.‐Ham. ex D. Don (Qianli guang), was used officially as an infusion in cases of oral and pharyngeal infections in China. In this study in vivo metabolism of adonifoline was studied for the first time by identifying the metabolites of adonifoline present in bile, urine and feces of rats using liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI‐MSⁿ) (ion trap) as well as liquid chromatography/electrospray ionization high‐resolution mass spectrometry (LC/ESI‐HRMS) (quadrupole‐time of flight). In total 19 metabolites were identified and, among them, retronecine‐N‐oxides were confirmed by matching their fragmentation patterns with their fully characterized synthetic compounds. These metabolites are all involved in both phase I and phase II metabolic processes and the principal in vivo metabolism pathways of adonifoline were proposed. Copyright © 2009 John Wiley & Sons, Ltd.     

矩阵正态统计分布的一个性质

对于服从相同统计分布的两个 n维随机向量 X和 Y,若 X关于 Y的条件概论分布为多元正态分布Nn(ATy+ b,φ0 ) ,则由 X和 Y构成的 2 n维随机向量也服从多元正态分布 ,并且︳(A) <1;利用条件分布和特征函数的唯一性定理 ,证明了矩阵正态分布也存在类似结论 .     

Biomimetic Peptide‐Gated Nanoporous Membrane for On‐Demand Molecule Transport

The controllable molecule transport is crucial to realize many highly valuable applications both in vivo and in vitro. Nanoporous membranes, with nanoscopic pores, high porosity, uniform pore dimensions, and controllable surface chemical properties, hold tremendous potential to achieve this function. Herein, we report a nano‐gating system for on‐demand molecule transport based on a peptide‐gated nanoporous membrane. Acting as gatekeeper, the peptides introduced to the nanoporous membrane provide an opportunity to realize on‐demand on–off states via reversible conformational switching of the peptides. This nano‐gating system offers sustained release and can be used as a sophisticated molecule transport platform for localized drug delivery with a feedback function.     

Ring-opening polymerization of lactide using salen–aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine

Three aluminum complexes supported by salen ligands derived from cis-1,2-cyclohexanediamine and salicylaldehyde derivatives were synthesized. They were characterized by ¹H, ¹³C NMR spectra, and elemental analysis. X-ray diffraction analysis revealed that aluminum was in distorted square pyramidal geometry in 2. These complexes were employed as catalysts for the ring-opening polymerization (ROP) of L-lactide and rac-lactide. Complex 2 showed the highest activity among these complexes with isopropanol for the ROP of L-lactide and 3 showed the highest stereoselectivity for the ROP of rac-lactide attaining partially isotactic polylactide with a P_m of 0.75. The kinetic data of the polymerization utilizing 3 as catalyst showed that the polymeric rate was first order to the monomer and catalyst.