全文获取类型
收费全文 | 509篇 |
免费 | 22篇 |
国内免费 | 53篇 |
专业分类
化学 | 437篇 |
晶体学 | 2篇 |
力学 | 19篇 |
综合类 | 4篇 |
数学 | 44篇 |
物理学 | 78篇 |
出版年
2024年 | 2篇 |
2023年 | 16篇 |
2022年 | 11篇 |
2021年 | 28篇 |
2020年 | 16篇 |
2019年 | 21篇 |
2018年 | 27篇 |
2017年 | 5篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 13篇 |
2013年 | 27篇 |
2012年 | 34篇 |
2011年 | 50篇 |
2010年 | 22篇 |
2009年 | 23篇 |
2008年 | 36篇 |
2007年 | 43篇 |
2006年 | 39篇 |
2005年 | 24篇 |
2004年 | 12篇 |
2003年 | 7篇 |
2002年 | 9篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1999年 | 8篇 |
1998年 | 9篇 |
1997年 | 10篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 1篇 |
排序方式: 共有584条查询结果,搜索用时 0 毫秒
61.
62.
Hui Chen Kean Chen Laibing Luo Dr. Xingwei Liu Zhi Wang Dr. Along Zhao Dr. Hui Li Prof. Xinping Ai Yongjin Fang Prof. Yuliang Cao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(10):e202316966
LiPF6 as a dominant lithium salt of electrolyte is widely used in commercial rechargeable lithium-ion batteries due to its well-balanced properties, including high solubility in organic solvents, good electrochemical stability, and high ionic conductivity. However, it suffers from several undesirable properties, such as high moisture sensitivity, thermal instability, and high cost. To address these issues, herein, we propose an electron-donation modulation (EDM) rule for the development of low-cost, sustainable, and electrochemically compatible LiNO3-based electrolytes. We employ high donor-number solvents (HDNSs) with strong electron-donation ability to dissolve LiNO3, while low donor-number solvents (LDNSs) with weak electron-donation ability are used to regulate the solvation structure to stabilize the electrolytes. As an example, we design the LiNO3-DMSO@PC electrolyte, where DMSO acts as an HDNS and PC serves as an LDNS. This electrolyte exhibits excellent electrochemical compatibility with graphite anodes, as well as the LiFePO4 and LiCoO2 cathodes, leading to stable cycling over 200 cycles. Through spectroscopy analyses and theoretical calculation, we uncover the underlying mechanism responsible for the stabilization of these electrolytes. Our findings provide valuable insights into the preparation of LiNO3-based electrolytes using the EDM rule, opening new avenues for the development of advanced electrolytes with versatile functions for sustainable rechargeable batteries. 相似文献
63.
Yuliang Yang 《Macromolecular theory and simulations》1998,7(5):521-549
The spring-and-bead model proposed by Rouse and Zimm can theoretically treat the viscoelastic behaviour of polymers. In this paper, we first point out that the Rouse and Zimm matrices in the molecular theory of polymer viscoelasticities are equivalent to the adjacency matrix and admittance (or Kirchhoff) matrix in graph theory, respectively. In order to solve the eigen-value problems of Rouse and Zimm matrices, the matrices are first represented by their corresponding eigen-graphs, which reflect the topological structure of the real chain. Starting from the eigen-graph, instead of tedious mathematics, the eigen-value problems are solved by a series of simple graphic operations, such as cutting-off the bonds, removing the closed pathways, etc. The eigen-polynomial of Rouse and Zimm matrices and the viscoelastic properties of the chain are obtained by using the theorems given in this paper. It is also shown that the eigen-polynomial of the chain can be greatly reduced if the chain graph has elements of symmetry. As the Rouse theory of viscoelasticity is closely related to the conformational statistics of Gaussian chains, it is demonstrated that the graph-theoretic approach developed here can also be applied to solve the configurational properties of Gaussian chains, such as the distribution function of the radius of gyration and its moments, the shape of a Gaussian chain, etc. We have also demonstrated that the graph-theoretic approach developed here is also applicable to copolymeric chains. 相似文献
64.
65.
66.
We present a novel reference compensation method for eliminating environmental noise in interferometric wavelength shift demodulation for dynamic fiber Bragg grating (FBG) sensors. By employing a shielded wavelength-division-multiplexed reference FBG in the system, the environmental noise is measured from the reference channel, and then subtracted from the demodulation result of each sensor channel. An approximate 40 dB reduction of the environmental noise has been experimentally achieved over a frequency range from 20 Hz to 2 kHz. This method is also suitable for the elimination of broadband environmental noise. The corresponding FBG sensor array system proposed in this paper has shown a wavelength resolution of . 相似文献
67.
为高效求解球床高温气冷堆物理-热工耦合问题,发展改进节块展开法求解圆柱几何下的对流扩散方程.针对圆柱几何和对流扩散方程的特殊性,采用三阶多项式和指数函数作为r向横向积分方程的展开函数,在节块展开法的框架下高效求解对流扩散方程.数值验证表明,改进的节块展开方法具有固有的迎风特性,在使用粗网节块时依然能保持稳定性和较高的计算精度. 相似文献
68.
69.
Qian X Ning Z Li Y Liu H Ouyang C Chen Q Li Y 《Dalton transactions (Cambridge, England : 2003)》2012,41(3):730-733
GDNWs (graphdiyne nanowires) have successfully been constructed which exhibit a very high quality defect-free surface using the VLS growth process. Measurement of electrical properties showed that the GDNWs produced are excellent semiconductors with a conductivity of 1.9 × 10(3) S m(-1) and a mobility of 7.1 × 10(2) cm(2) V(-1) s(-1) at room temperature. The results have confirmed that GDNW is indeed a promising and key novel material in electronic and photoelectric fields for both fundamental and potentially practical applications. 相似文献
70.
Dr. Yongjun Li Zhihong Qing Yanwen Yu Taifeng Liu Runsheng Jiang Prof. Yuliang Li 《化学:亚洲杂志》2012,7(8):1934-1939
The synthesis of 1,10‐dihydroxyperylene bisimides by nucleophilic substitution of brominated perylene bisimide is described. 1,10‐Dihydroxyperylene bisimides formed J aggregates in nonpolar solvents and showed a clearly redshifted absorption band. The solvent polarity also influenced the hydrogen bond with the hydroxyl group, and thus, the photophysical properties of perylene bisimide. The photophysical properties of these dihydroxyperylene perylene bisimides can also be tuned by changing charge transfer from the hydroxyl groups to the perylene core through the introduction of metal ions. 相似文献