全文获取类型
收费全文 | 509篇 |
免费 | 22篇 |
国内免费 | 53篇 |
专业分类
化学 | 437篇 |
晶体学 | 2篇 |
力学 | 19篇 |
综合类 | 4篇 |
数学 | 44篇 |
物理学 | 78篇 |
出版年
2024年 | 2篇 |
2023年 | 16篇 |
2022年 | 11篇 |
2021年 | 28篇 |
2020年 | 16篇 |
2019年 | 21篇 |
2018年 | 27篇 |
2017年 | 5篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 13篇 |
2013年 | 27篇 |
2012年 | 34篇 |
2011年 | 50篇 |
2010年 | 22篇 |
2009年 | 23篇 |
2008年 | 36篇 |
2007年 | 43篇 |
2006年 | 39篇 |
2005年 | 24篇 |
2004年 | 12篇 |
2003年 | 7篇 |
2002年 | 9篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1999年 | 8篇 |
1998年 | 9篇 |
1997年 | 10篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 1篇 |
排序方式: 共有584条查询结果,搜索用时 0 毫秒
51.
Fluoroethylene carbonate (FEC) is investigated as the electrolyte additive to improve the electrochemical performance of high voltage LiNi0.6Co0.2Mn0.2O2 cathode material. Compared to LiNi0.6Co0.2Mn0.2O2/Li cells in blank electrolyte, the capacity retention of the cells with 5 wt% FEC in electrolytes after 80 times charge-discharge cycle between 3.0 and 4.5 V significantly improve from 82.0 to 89.7%. Besides, the capacity of LiNi0.6Co0.2Mn0.2O2/Li only obtains 12.6 mAh g?1 at 5 C in base electrolyte, while the 5 wt% FEC in electrolyte can reach a high capacity of 71.3 mAh g?1 at the same rate. The oxidative stability of the electrolyte with 5 wt% FEC is evaluated by linear sweep voltammetry and potentiostatic data. The LSV results show that the oxidation potential of the electrolytes with FEC is higher than 4.5 V vs. Li/Li+, while the oxidation peaks begin to appear near 4.3 V in the electrolyte without FEC. In addition, the effect of FEC on surface of LiNi0.6Co0.2Mn0.2O2 is elucidated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The analysis result indicates that FEC facilitates the formation of a more stable surface film on the LiNi0.6Co0.2Mn0.2O2 cathode. The electrochemical impedance spectroscopy (EIS) result evidences that the stable surface film could improve cathode electrolyte interfacial resistance. These results demonstrate that the FEC can apply as an additive for 4.5 V high voltage electrolyte system in LiNi0.6Co0.2Mn0.2O2/Li cells. 相似文献
52.
53.
We will be mainly concerned with some important fiber spaces over Teichmüller spaces, including the Bers fiber space and Teichmüller
curve, establishing an isomorphism theorem between “punctured” Teichmüller curves and determining the biholomorphic isomorphisms
of these fiber spaces. 相似文献
54.
The rod–coil diblock copolymers in which the donor–acceptor alternating structures served as the rod segment were synthesized.
The supramolecular self-assembly property of the copolymers was investigated in the methanol atmosphere. By changing the assembly
condition, well-defined vesicles and porous films were produced, respectively. Pores with different size dispersions were
obtained by tuning the methanol atmosphere. Moreover, porous films were also decorated on diverse substrates with nonplanar
structures. The investigation on self-assembly properties of this rod–coil copolymer is the complementarity to the self-assembly
of rod–coil copolymers. This is a very useful self-assembly method that can be used to prepare the self-assembly nanostructures
with donor–acceptor alternating copolymers. 相似文献
55.
Sun Z Wang Y Wei Y Liu R Zhu H Cui Y Zhao Y Gao X 《Chemical communications (Cambridge, England)》2011,47(43):11960-11962
Silver cluster-aptamer hybrids were mineralized via an artificially designed aptamer. The hybrids gave red emission when excited by light, and they successfully targeted the nucleus of live cells. This method is an effective approach to make cell target probes. 相似文献
56.
Enhanced white-light emission was achieved by loading green- and red-light-emitting donor-acceptor pairs in the separate micellar cores and blue-light-emitting polymers around their periphery. Fluorescence resonance energy transfer was enabled between a donor and an acceptor in cores, but was suppressed among these three light-emitting species by micellar coronas, which resulted in their enhanced simultaneous emissions. 相似文献
57.
Xuchen Zheng Han Wu Dr. Yang Gao Siao Chen Prof. Yurui Xue Prof. Yuliang Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(9):e202316723
The manufacture of nitric acid (HNO3) consumes large amounts of energy and causes serious environmental pollution. Electrochemical synthesis is regarded as a key way to eliminate carbon emissions from the chemicals industry. The selective electrosynthesis of HNO3 from nitrogen was achieved by controllable assembly of cobalt metal on graphdiyne surface using a powerful tool of electrochemistry at ambient conditions. As an advanced material, graphdiyne (GDY) has a large conjugated structure on its surface and is rich in sp-C triple bond skeleton, which can achieve strong interaction with metal atoms, resulting in incomplete charge transfer between graphdiyne and cobalt atoms. The experimental and theoretical calculation results show that the highly oxidized cobalt on graphdiyne (HOCo/GDY) can selectively and efficiently activate and convert the nitrogen into the key intermediate *NO, which promotes the efficient overall conversion performance of nitrogen to nitric acid. Thus, the highest nitric acid yield (192.0 μg h−1 mg−1) and Faradaic efficiency (21.5 %) were achieved at low potentials. 相似文献
58.
Yuliang Zhao 《中国科学:化学(英文版)》2021,(12):2055-2056
Immunotherapy such as immune checkpoint blockade (ICB)and adoptive cell transfer is a revolutionary advance in the field of cancer therapy by providing clinical... 相似文献
59.
SOI全内反射型光波导电光开关模型研究 总被引:1,自引:1,他引:0
根据受抑全反射的光学隧道效应和Goos-Hanchen位移分析SOI全内反射型光波导开关中导模的传输和反射特性。在讨论等离子体色散效应,p-n结大注入效应的基础上,分析了全内反射光波导开关的电学性质。设计了该器件的结构以数和电学参数。 相似文献
60.