Jones 矩阵在偏振光实验中的应用

将Jones矩阵应用于偏振光实验研究,通过偏振光的Jones矢量表示和偏振器件的Jones矩阵,分析了偏振光通过偏振器件后偏振态的变化,准确方便地解释了偏振光实验中的实验现象。     

医用加速器二极磁铁的非单一工作模式电源控制器设计

近年来,离子治疗技术在国内外发展迅速.为满足加速器调试和不同治疗方案对医用回旋加速器装置的不同束流能量要求,二极磁铁电源要求工作在可相互切换的直流、有序触发和周期脉冲三种模式.使用中国科学院近代物理研究所自主研发的集成盒装式控制器,实现了对电源的控制和保护功能.为了适应调试和治疗两种不同场合的需求,控制器还支持本地和远...     

Cover Picture: Facile Synthesis and in situ TEM Observation of Nanoporous Pd for Enhanced Catalytic Applications (Chin. J. Chem. 6/2019)

The cover picture shows facile photochemical synthesis, direct in situ TEM characterization, and effective catalytical applications of sponge‐like porous Pd nano particles. In situ liquid cell TEM observation not only confirms the actual existence of the sponge‐like Pd in a liquid solution, but also shows such Pd nanostructure is in a dynamic stable state, which is beneficial for the material exchange and the catalytic performance improvement. The expected catalytic activity improvement is supported by such as the 4‐nitrophenol reduction reactions, which is important both for the environment and the industry. More details are discussed in the article by Chen et al. on page 565–569.

     

Studies on intermolecular interactions of metal chelate complexes. Part X. Interactions of metal chelates with ozone

Summary The interactions of more than forty metal chelate complexes, dithiocarbamates, dithiophosphates and acetylacetonates, with ozone are studied in homogeneous phase and the stoichiometry and the rate constants of the reactions estimated. Most powerful ozone deactivators are nickel(II) and copper(II) dithiocarbamate and dithiophosphate complexes interacting with 6.5 moles ozone per mole of the ligand with rate constant >0⁶m · I^–1 · s^–1. The remote ligand substituents do not influence the reaction parameters. Other sulphur-containing complexes of iron(III), cobalt(II), cobalt(III), zinc(II), manganese(III), bismuth(III), antimony(III), arsenic(III), cadmium(II), platinum(II), palladium(II) and chromium(III) deactivate 3–4 moles ozone per mole ligand with rate constants of 10²–10⁴ m · I^–1 · s^–1. Acetylacetonate complexes of copper(II), nickel(II), cobalt(III), iron(III), chromium (III), and oxovanadium(II) deactivate 1–3 moles ozone per mole ligand with a rate constant of 10–10⁴ m · I^–1 · s^–1. Using e.p.r. and electronic spectra, some intermediate products are detected and the mechanism of the reaction is discussed. The reported data are compared with other widely used antiozonants and the metal chelates are shown to have several advantages.     

Fabrication of highly crystalline covalent organic framework for solid-phase extraction of three dyes from food and water samples

Herein, a covalent organic framework, which was fabricated at room temperature by using 1,3,5-tris(p-formylphenyl) benzene and 1,3,5-tris(4-aminophenyl)benzene as building blocks, was employed as an adsorbent for solid-phase extraction of dyes including congo red, methyl blue and direct red 80 for the first time. The prepared covalent organic framework was properly characterized by different techniques and the results revealed that it had a uniform spherical structure, high crystallinity, satisfactory surface area, and good thermal stability. Moreover, the adsorption performance of the material was explored by using static and dynamic adsorption experiments and the results indicated that the material showed good adsorption capacities for three dyes with adsorption capacities in the range of 55.25–284.10 mg/g and the adsorption equilibrium can be achieved in 15 min. Further, to achieve the best adsorption effects of the material, the influence parameters such as pH, ionic strength, type of desorption solvent, and the material dosage in the solid-phase extraction column, were optimized in turn. Finally, under optimal conditions, the solid-phase extraction coupled with HPLC was applied to the analysis of dyes in food and water samples. The recoveries of dyes in actual samples were satisfactory, revealing the unique applicability of the material in the sample pretreatment field.     

Synthesis and study of the structure of new 3d-metal coordination compounds with substituted 2-amino-4(5H)-ketothiophens

A series of new 3d-metal complexes based on 2-amino-3-(1-methylbenzimidazol-2-yl)-4(5H)-ketothiophen (HL¹) and 2-amino-3-(2-benzothiazolyl)-4(5H)-ketothiophen (HL²) were synthesized. Compounds of the general formulas [ML₂] and [M(HL¹)₂Cl₂] (where M = Co²⁺, Ni²⁺, Zn²⁺, Cu²⁺) were prepared by the reaction of the above mentioned ligands with the corresponding acetate (for [ML₂]) or chloride (for [M(HL¹)₂Cl₂]) salts in a methanol or a methanol–chloroform medium. The choice of the anion in the initial metal salt, as well as the selection of the ligand, is crucial for obtaining coordination compounds with a neutral or deprotonated form of the 2-amino-4(5H)-ketothiophens. Thus, in contrast to HL¹, complexes with the neutral form of HL² cannot be obtained under the same conditions. All the complexes were studied by spectroscopic methods and X-ray crystallography (for [CuL¹₂] · H₂O). The coordination polyhedron of the copper atom is formed by four nitrogen atoms from two ligand anions and the geometry of the coordination sphere is intermediate between tetrahedral and square-planar.     

液压舱口盖甲板支撑结构的优化设计研究

液压油缸启闭舱口盖时甲板支撑结构负荷很大,采用常规的设计方法无法满足强度与稳定要求.本文根据启闭液压缸的载荷作用点,应用二次规划的准解析法,在多种工况下优化了液压舱口盖甲板支撑结构,使优化后的结构满足强度与稳定性要求.     

A new error estimation approach based on fuzzy logic system for H-R adaptive boundary element method

Conventional adaptive boundary element method cannot be universally applied to solve many more problems than the subject it discussed, and different error estimation formulas need to be designed for varied problems. This paper put forward a new error analysis method based on the fuzzy logic system, which is able to make error estimation effectively using human expert experience, and solve the two classical elasticity problems in conjunction with the H-R adaptive boundary element method. Numerical examples have illustrated the effectiveness, superiority and potential of a fuzzy logic approach in the adaptive boundary element method.     

微球透镜对亚波长表面结构的显微成像研究

为了研究微球透镜对亚波长物体的成像特性,利用直径为3.4μm的二氧化硅微球透镜对刻录蓝光光碟的亚波长表面结构进行了显微成像实验,观察了不同排列方式和液体浸没深度下微球透镜的成像特性。实验结果表明:微球透镜在不同浸没深度下对亚波长表面结构具有放大作用,放大率为1.2~1.8倍,并且通过微球透镜的密排列,可以获得更大的视场;浸没液体深度增大时,图像的放大率减小,视场增大。基于时域有限差分的电场仿真表明,微球透镜可以将光场汇聚成半高全宽为260nm,纵向可持续几个微米的高强度光区域,引起强的背景散射,从而获得普通光学显微镜不能分辨的亚波长表面结构图像。     

Novel Benzothiazine Derivatives via Formylation of 2,3‐Dihydro‐4H‐benzo[e][1,4]thiazin‐3‐on‐1,1‐dioxide

A simple, efficient, and clean protocol for the formylation of 2,3‐dihydro‐4H‐1,4‐benzo[e][1,4]thiazin‐3‐on‐1,1‐dioxide is developed. Novel benzothiazine derivatives are synthesized by the reactions of aminovinyl derivative 6 and carbaldehyde 7 with nucleophiles.