Synthesis of Δ-OPC-8:0 and OPC-6:0

CuCN-catalyzed reaction of the (1R)-isomer of 4-cyclopentene-1,3-diol monoacetate with TBDPSO(CH₂)₆MgCl produced an S_N2-type product regioselectively in high yield. Mitsunobu inversion of the product and subsequent Claisen rearrangement furnished aldehyde with the two side chains, from which the title compounds were synthesized efficiently.     

Influence of shearing process on domain structure and magnetic properties of non-oriented electrical steel

The influence of shearing on the magnetic properties and domain structure of 0.5 mm thick non-oriented electrical steel was studied. In the region from 1 to 1.4 mm from the sheared edge, a striped domain pattern that indicated the existence of elastic strain was observed. From the degradation tendency of flux density with respect to shearing width, the width of the degraded region near the edge increased as the magnetic field decreased. These results suggested that the change in the flux density at high magnetic fields over 300 A/m were mainly dependent on the characteristics of the edge vicinity where the domain pattern was influenced by shearing.     

Stable-isotope dilution activation analysis,and determination of Ca,Zn and Ce by means of photon activation

As a new method, stable-isotope dilution activation analysis has been developed. When an element consists of at least two stable isotopes which are converted easily to the radioactive nuclides through nuclear reactions, the total amount of the element (xg) can be determined by irradiating simultaneously the duplicated sample containing small amounts of either enriched isotope (y g), and by using the following equation. $${{x = y\left( {{M \mathord{\left/ {\vphantom {M {M*}}} \right. \kern-\nulldelimiterspace} {M*}}} \right)\left[ {\left( {{{R*} \mathord{\left/ {\vphantom {{R*} R}} \right. \kern-\nulldelimiterspace} R}} \right)\left( {{{\theta _2^* } \mathord{\left/ {\vphantom {{\theta _2^* } {\theta _2 }}} \right. \kern-\nulldelimiterspace} {\theta _2 }}} \right) - \left( {{{\theta _1^* } \mathord{\left/ {\vphantom {{\theta _1^* } {\theta _1 }}} \right. \kern-\nulldelimiterspace} {\theta _1 }}} \right)} \right]} \mathord{\left/ {\vphantom {{x = y\left( {{M \mathord{\left/ {\vphantom {M {M*}}} \right. \kern-\nulldelimiterspace} {M*}}} \right)\left[ {\left( {{{R*} \mathord{\left/ {\vphantom {{R*} R}} \right. \kern-\nulldelimiterspace} R}} \right)\left( {{{\theta _2^* } \mathord{\left/ {\vphantom {{\theta _2^* } {\theta _2 }}} \right. \kern-\nulldelimiterspace} {\theta _2 }}} \right) - \left( {{{\theta _1^* } \mathord{\left/ {\vphantom {{\theta _1^* } {\theta _1 }}} \right. \kern-\nulldelimiterspace} {\theta _1 }}} \right)} \right]} {\left[ {1 - \left( {{{R*} \mathord{\left/ {\vphantom {{R*} R}} \right. \kern-\nulldelimiterspace} R}} \right)} \right]}}} \right. \kern-\nulldelimiterspace} {\left[ {1 - \left( {{{R*} \mathord{\left/ {\vphantom {{R*} R}} \right. \kern-\nulldelimiterspace} R}} \right)} \right]}}$$ Where M and M^* are atomic weights of the element to be determined and the enriched isotope used as a spike,θ ₁ andθ ₂ are natural abundances of two stable isotopes in the element,θ ₁ ^* andθ ₂ ^* are isotopic compositions of the above isotopes in the enriched isotope, and R and R^* are counting ratios of gamma-rays emitted by two radionuclides produced in the sample and the isotopic mixture. Neither calibration standard nor correction of irradiation conditions are necessary for this method. Usefulness of the present method was verified by photon activations of Ca, Zn and Ce using isotopically enriched⁴⁸ca,⁶⁸Zn and¹⁴²Ce.     

Grid-averaged Lagrangian LES model for multiphase turbulent flow

A grid-averaged Lagrangian (GAL) model for dispersed particle motion in multiphase turbulent flow is presented to provide a large eddy simulation (LES) model for multiphase turbulent flow in which a quite large number of particles are involved. The GAL model is based on an averaging operation for a Lagrangian-type equation of motion of a particle over a computational grid volume and a procedure of reallocation of a dispersed particle cloud with its centroid movement to each grid. The model is therefore a mixed Eulerian–Lagrangian model which can effectively reduce computational time compared with existing Lagrangian-type models, without losing the advantage of Lagrangian-type models that they can properly describe the dynamical evolution of particles. Since the GAL model adopts the grid-volume averaging operation it can easily provide an effective SGS model for LES modeling of multiphase turbulent flow. The validity of the multiphase LES model developed, which is named the GAL-LES model, is confirmed through its application to a particle plume, in which the present model is found to simulate large-eddy motion usually observed in a jet and plume, and to give good agreements with experimental data.