全文获取类型
收费全文 | 1026篇 |
免费 | 30篇 |
国内免费 | 5篇 |
专业分类
化学 | 825篇 |
晶体学 | 7篇 |
力学 | 17篇 |
数学 | 63篇 |
物理学 | 149篇 |
出版年
2023年 | 7篇 |
2022年 | 10篇 |
2021年 | 14篇 |
2020年 | 17篇 |
2019年 | 17篇 |
2018年 | 15篇 |
2017年 | 15篇 |
2016年 | 27篇 |
2015年 | 23篇 |
2014年 | 27篇 |
2013年 | 55篇 |
2012年 | 62篇 |
2011年 | 79篇 |
2010年 | 34篇 |
2009年 | 33篇 |
2008年 | 69篇 |
2007年 | 86篇 |
2006年 | 77篇 |
2005年 | 64篇 |
2004年 | 58篇 |
2003年 | 50篇 |
2002年 | 47篇 |
2001年 | 15篇 |
2000年 | 10篇 |
1999年 | 10篇 |
1998年 | 12篇 |
1997年 | 8篇 |
1996年 | 7篇 |
1995年 | 13篇 |
1994年 | 9篇 |
1993年 | 9篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1956年 | 1篇 |
排序方式: 共有1061条查询结果,搜索用时 15 毫秒
121.
122.
123.
124.
Hiroko Nakagawa Kumiko Ohtsuka Katsuhito Sugahara Chika Kobayashi Yuichi Masuoka Koh-ichi Yamada Masami Kawase 《Tetrahedron: Asymmetry》2010,21(6):659-664
Helical [5]thiaheterohelicene 5HM, which rapidly interconverts between P and M enantiomers in solution, was connected to helical l-phenylalanine oligomers with an ester linkage to give peptidehelicenes (5Fn, where n: number of bonded phenylalanines). The characteristics of 5F4 and 5F5 with two types of helixes in a molecule were investigated, particularly in comparison with those of 5F1–5F3 with an incomplete coil of a peptide moiety. l-Phenylalanine peptide chains induced a shift in the equilibrium between the P and M helixes of 5HM toward the P side for all the 5Fns examined. The enantiomeric excess (ee) of the P form increased with a decrease in temperature, together with an elongation of the peptide chains. 5F4 and 5F5 in hot solutions of some solvents formed a gel at room temperature, whereas 5F1–5F3 showed no such behavior. In this gel, the stable helical form of the 5HM moiety in 5F4 and 5F5 was observed to be the M form in contrast to that in their solutions. 相似文献
125.
126.
127.
Takano Yuichi Ishii Nobuaki Muraki Masaaki 《Central European Journal of Operations Research》2017,25(2):303-323
Central European Journal of Operations Research - In competitive bidding for project contracts, contractors estimate the cost of completing a project and then determine the bid price. Accordingly,... 相似文献
128.
Hiroshi Kimura Koichiro Aikawa Yuichi Masubuchi Jun-ichi Takimoto K. Koyama Keiji Minagawa 《Rheologica Acta》1998,37(1):54-60
The mechanism of the electrorheological (ER) effect in two types of liquid crystalline polymer (LCP)/dimethylsiloxane (DMS)
blends was investigated by rheological measurements and by structure observation under electric field and shear flow. The
results show that the phase structures of these immiscible blends can be categorized into slipping (low viscosity) and non-slipping
(high viscosity) states. In the non-slipping state, higher viscosity LCP domains connect the electrodes. In the slipping state,
on the other hand, LCP domains do not connect the electrodes and the shear is mainly confined in the lower viscosity DMS domains.
The ER effect (electrically induced viscosity increase) originates from the electrically induced slipping to non-slipping
transition. In one of the blends, the ER effect occurs only at high shear rate, since this blend is in non-slipping state
even under no field if the shear rate is low.
Received: 29 April 1997 Accepted: 3 November 1997 相似文献
129.
Hideo Nagashima Yuichi KuboMitsunobu Kawamura Takashi NishikataYukihiro Motoyama 《Tetrahedron》2011,67(40):7667-7672
A triruthenium cluster, (μ3, η2, η3, η5-acenaphthylene)Ru3(CO)7 effectively catalyzes primary-alkylation reaction of electron-rich aromatic rings using a combination of hydrosilane and ester as a source of the primary-alkyl group. The reaction involves electrophilic substitution of arenes by carbocationic species stabilized by a neighboring alkoxy or siloxy group generated during the reduction of esters giving alkylated arenes after reductive removal of the alkoxy or siloxy group at the benzylic position. 相似文献
130.
We have developed an efficient method for preparation of triazolamers using a dicobalt hexacarbonyl complex of propargyl azides (CPA) as a synthetic component. Several types of CPAs possessing the side chains found in the natural amino acids were prepared by Nicholas reaction as well as by a reaction of propargyl azides with dicobalt octacarbonyl. Triazolamers with both amino and carboxyl termini were readily synthesized by repetitive reaction sequence involving a copper-catalyzed 1,3-dipolar cycloaddition followed by an oxidative deprotection. 相似文献