用概率断裂力学方法预测管状接头的疲劳寿命

本文研究了Ｔ型管状接头在面内和面外弯曲循环载荷作用下的疲劳强度问题，通过将材料常数和初始裂纹尺寸作为随机变量，采用ＭｏｎＣａｒｌｏ模拟方法对疲劳寿命进行了统计分析．同时，对计算结果进行了线性回归，并与实验结果作了比较。     

介质材料二次电子发射特性对微波击穿的影响

以介质填充的平行板放电结构为例,本文主要研究了介质填充后微波低气压放电和微放电的物理过程.为了探究介质材料特性对微波低气压放电和微放电阈值的影响,本文采用自主研发的二次电子发射特性测量装置,测量了7种常见介质材料的二次电子发射系数和二次电子能谱.依据二次电子发射过程中介质表面正带电的稳定条件,计算了介质材料稳态表面电位与二次电子发射系数以及能谱参数的关系.在放电结构中引入与表面电位相应的等效直流电场后,依据电子扩散模型和微放电中电子谐振条件,分别探讨了介质表面稳态表面电位的大小对微波低气压放电和微放电阈值的影响.结果表明,介质材料的二次电子发射系数以及能谱参数越大,介质材料的稳态表面电位也越大,对应的微波低气压放电和微放电阈值也越大.所得结论对于填充介质的选择有一定的理论指导价值.     

Effects of modulation phase of ultrasound-modulated light on the ultrasound-modulated optical image in turbid media

In this paper, our investigations suggest that the modulation phase of ultrasound-modulated light escaping from the different locations in the ultrasonic field is different. In turbid media, the modulation phase causes the ultrasound-modulated light intensity collected outside the media to fluctuate. However, the ultrasound-modulated optical technology uses the ultrasound-modulated light signals to image. Consequently, the modulation phase affects the quality of ultrasound-modulated optical imaging.     

惯性约束聚变装置中靶面光场特性的统计表征方法

在激光驱动的惯性约束聚变装置中,常采用多种束匀滑手段对焦斑的时空特性进行调控.光传输链路中涉及的光学元件众多、传输变换复杂,往往导致光传输模型复杂,且在运用衍射光学方法分析焦斑形态和特征时面临大量的数据处理和计算,致使出现计算量大、计算效率低等问题,亟需寻求快速而简便的新方法来描述焦斑的统计特征.本文利用光场特性的统计表征方法对靶面光场进行表征,采用圆型复数高斯随机变量直接描述靶面光场的统计特征,并基于典型焦斑评价参数对衍射光学方法和统计表征方法得到的远场焦斑进行了对比和分析.结果表明,采用衍射光学方法和统计表征方法获得的焦斑的瞬时特征基本一致,其时间积分的远场焦斑有所不同,但仍可进一步采用相关系数来表征其远场焦斑的时间变化特征.     

镧系离子(Eu3+,Tb3+)氧氟沙星配合物的合成和光谱表征

本文报道了镧系离子Eu3 + ,Tb3 + 同喹诺酮羧酸类衍生物氧氟沙星形成配合物的合成。用元素分析法和ICP确定了配合物的组成为Ln(oflo) 3 Cl3 ·8H2 O。红外光谱表明氧氟沙星配体羧基同中心离子发生螯合 ,并可能与邻位羰基形成六元环稳定结构。荧光光谱表明 ,Eu配合物具有很宽的激发谱带 (2 0 0～ 45 0nm) ,明显区别于其他羧酸类的稀土配合物 ;中心离子Eu3 + 发射谱位于 5 79 0nm(5D0 7F0 ) ,5 92 2nm(5D0 7F1) ,6 12 2nm(5D0 7F2 ) ;而Tb3 + 配合物则同时有配体和中心离子的荧光发射     

Efficient cross polarization with simultaneous adiabatic frequency sweep on the source and target channels

In this work, we propose a new and efficient heteronuclear cross polarization scheme, in which adiabatic frequency sweeps from far off-resonance toward on-resonance are applied simultaneously on both the source and target spins. This technique, which we call as Simultaneous ADIabatic Spin-locking Cross Polarization (SADIS CP), is capable of efficiently locking both the source and target spins with moderate power even in the presence of large spectral distribution and fast relaxation. It is shown that by keeping the time-dependent Hartmann-Hahn mismatch minimal throughout the mixing period, polarization transfer can be accelerated. Experiments are demonstrated in a powder sample of L-alanine.     

Pyrolysis study of poplar biomass by tunable synchrotron vacuum ultraviolet photoionization mass spectrometry

Pyrolysis is one of the most important methods to convert biomass into biofuel, which is a potential substitute for fossil fuel. The pyrolysis process of poplar biomass, a potential biofuel feedstock, has been studied with tunable synchrotron vacuum ultraviolet (SVUV) photoionization mass spectrometry (PIMS). The mass spectra at different photon energies, temperatures, and time-evolved profiles of selected species during poplar pyrolysis process were measured. Our results reveal that poplar is typical of hardwood according to its relative contents of three lignin monomeric precursors. As temperature increases from 300 to 700 °C, the overall intensities of pyrolysis products decrease due to the gas-phase cracking. Observed intensities of syringyl and guaiacyl subunits of lignin in poplar at low temperature present different trends: the intensities of syringyl subunits of lignin undergo an increase firstly and then a decrease, whereas those of guaiacyl subunits of lignin show decrease continuously. Time-dependent data demonstrate that hemicellulose pyrolysis is faster than lignin in poplar. This work reports a new application of SVUV PIMS in biomass pyrolysis, which performs very well in products analysis.     

精确Cosserat弹性杆动力学的分析力学方法

以脱氧核糖核酸和工程中的细长结构为背景, 大变形大范围运动的弹性杆动力学受到关注. 将分析力学方法运用到精确Cosserat弹性杆动力学, 旨在为前者拓展新的应用领域, 为后者提供新的研究方法. 基于平面截面假定, 在弯扭基础上再计及拉压和剪切变形形成精确Cosserat弹性杆模型. 用刚体运动的概念描述弹性杆的变形, 导出弹性杆变形和运动的几何关系; 在定义截面虚位移及其变分法则的基础上, 建立用矢量表达的d’Alembert-Lagrange原理, 在线性本构关系下化作分析力学形式, 并导出Lagrange方程和Nielsen方程, 定义正则变量后化作Hamilton正则方程; 对于只在端部受力的弹性杆静力学, 导出了将守恒量预先嵌入的Lagrange方程, 并讨论了其首次积分. 从弹性杆的d’Alembert-Lagrange原理导出积分变分原理, 在线性本构关系下化作Hamilton原理. 形成的分析力学方法使弹性杆的全部动力学方程具有统一的形式, 为弹性杆动力学的对称性和守恒量的研究及其数值计算铺平道路. 关键词： 精确Cosserat弹性杆 分析动力学方法 变分原理 Lagrange方程     

Topological nodal line semimetals predicted from first-principles calculations

Topological semimetals are newly discovered states of quantum matter, which have extended the concept of topological states from insulators to metals and attracted great research interest in recent years. In general, there are three kinds of topological semimetals, namely Dirac semimetals, Weyl semimetals, and nodal line semimetals. Nodal line semimetals can be considered as precursor states for other topological states. For example, starting from such nodal line states, the nodal line structure might evolve into Weyl points, convert into Dirac points, or become a topological insulator by introducing the spin–orbit coupling (SOC) or mass term. In this review paper, we introduce theoretical materials that show the nodal line semimetal state, including the all-carbon Mackay–Terrones crystal (MTC), anti-perovskite Cu₃PdN, pressed black phosphorus, and the CaP₃ family of materials, and we present the design principles for obtaining such novel states of matter.