高比表面积CuPc/TiO2纳米管复合材料的制备及其可见光光催化活性

以P25为前驱体,在碱性条件下采用水热法制备了TiO2纳米管(NT),然后通过浸渍法将敏化剂酞菁铜(CuPc)附着于TiO2NT表面,制得可见光响应的CuPc/TiO2NT复合光催化材料,并对其进行了表征,考察了它在可见光下降解罗丹明B的光催化活性.结果表明,在NaOH碱性条件下水热法制备的TiO2NT具有较大的比表面...     

近十年来流动测量技术的新发展

流动是一种跨行业、跨部门、跨学科的现象。现代空气动力学、流体力学、热力学、水力学以及航空航天工程、水利水电工程、热能工程、流体机械工程都提出了一系列复杂流动问题，其中包括高速流、低速流、管道流、燃烧流、冲击流、振荡流、涡流、湍流、旋转流、多相流等等。这些流动都需要人们提供新的测量方法和新的量测仪器、使之能够适应单点向多点、平面向空间、稳态向瞬态、单相向多相方向发展，这就促使人们不断利用新技术，发展新原理，采用新结构和新工艺，以改善食品性能，增强讯号处理能力，提高仪器的测量精度。同时简化操作技术，使之便于推广应用。近10年来，伴随着光纤技术、芯片技术、激光技术、数字信号处理技术，图形、图像处理技术以及计算机技术的日益成熟和完善，流速测量技术也随之得到了新的发展。本文就这些发展作一扼要介绍。     

一类分块矩阵的谱包含域

给出了一类复分块矩阵的谱包含域，推广与改进了文[1～5]的相应结果．     

A Switching Algorithm Based on Modified Quasi-Newton Equation

In this paper, a switching method for unconstrained minimization is proposed. The method is based on the modified BFGS method and the modified SR1 method. The eigenvalues and condition numbers of both the modified updates are evaluated and used in the switching rule. When the condition number of the modified SR1 update is superior to the modified BFGS update, the step in the proposed quasi-Newton method is the modified SR1 step. Otherwise the step is the modified BFGS step. The efficiency of the proposed method is tested by numerical experiments on small, medium and large scale optimization. The numerical results are reported and analyzed to show the superiority of the proposed method.     

Fast image enhancement using multi-scale saliency extraction in infrared imagery

We propose a multi-scale saliency extraction based fast infrared image enhancement approach. A local frequency-tuned based saliency extraction technique is designed for highlighting the salient regions, firstly. Then, multi-scale saliency extraction is demonstrated, introducing multi-scale local windows with different sizes to extract regions of interest at different scales. Finally, the original image is enhanced with combining multi-scale salient image regions into one image. The experimental results prove the proposed approach is robust and efficient for infrared image enhancement.     

基于面阵CCD的时间延时积分模式的空间相机自动对焦

空间面阵相机在轨运动会产生运动模糊,影响自动对焦准确率。为解决该问题,提出行间转移面阵CCD的时间延时积分(TDI)模式实现去运动模糊。选取行间转移面阵CCD KAI-1003作为成像器件,利用可编程逻辑器件(PLD)控制时序信号,匹配CCD的行转移速度与目标运动速度,实现去运动模糊。实验表明该成像系统不仅能去运动模糊而且还大幅提高图像信噪比。去运动模糊后,根据较短时间间隔内空间相机拍摄的图像有重叠区域的特点提出一种空间相机自动对焦方法。通过配准算法找出序列图像间的重叠区域,并计算重叠区域的清晰度评价值,然后根据传递特性将评价值映射到同一个评价体系中,最后找到最佳对焦位置。实验表明该成像系统对高速运动的目标能够实现自动对焦。     

Exact analysis of the orientation-adjusted adhesive full stick contact of layered structures with the asymmetric bipolar coordinates

The adhesion failure has become one dominant factor in determining the reliability and service life of miniaturized devices subject to loadings with arbitrary orientations. This article establishes an adhesive full stick contact model between an elastic half-space and a rigid cylinder loaded in any direction. Using the Papkovich-Neuber functions, the Fourier integral transform, and the asymmetric bipolar coordinates, the exact solution is obtained. Unlike the Johnson-Kendall-Roberts (JKR) model, the present adhesive contact model takes into account the effects of the load direction as well as the coupling of the normal and tangential contact stresses. Besides, it considers the full stick contact which has large values of the friction coefficient between contacting surfaces, contrary to the frictionless contact supposed in the JKR model. The result shows that suitable angles can be found, which makes the contact surfaces difficult to be peeled off or easy to be pressed into.

     

Enhancement of Visible-Light-Driven Hydrogen Evolution Activity of 2D π-Conjugated Bipyridine-Based Covalent Organic Frameworks via Post-Protonation

Photocatalytic hydrogen (H₂) evolution represents a promising and sustainable technology. Covalent organic frameworks (COFs)-based photocatalysts have received growing attention. A 2D fully conjugated ethylene-linked COF (BTT-BPy-COF) was fabricated with a dedicated designed active site. The introduced bipyridine sites enable a facile post-protonation strategy to fine-tune the actives sites, which results in a largely improved charge-separation efficiency and increased hydrophilicity in the pore channels synergically. After modulating the degree of protonation, the optimal BTT-BPy-PCOF exhibits a remarkable H₂ evolution rate of 15.8 mmol g⁻¹ h⁻¹ under visible light, which surpasses the biphenyl-based COF 6 times. By using different types of acids, the post-protonation is proved to be a potential universal strategy for promoting photocatalytic H₂ evolution. This strategy would provide important guidance for the design of highly efficient organic semiconductor photocatalysts.     

Multi-frame partially saturated images blind deconvolution

When blurred images have saturated or over-exposed pixels, conventional blind deconvolution approaches often fail to estimate accurate point spread function (PSF) and will introduce local ringing artifacts. In this paper, we propose a method to deal with the problem under the modified multi-frame blind deconvolution framework. First, in the kernel estimation step, a light streak detection scheme using multi-frame blurred images is incorporated into the regularization constraint. Second, we deal with image regions affected by the saturated pixels separately by modeling a weighted matrix during each multi-frame deconvolution iteration process. Both synthetic and real-world examples show that more accurate PSFs can be estimated and restored images have richer details and less negative effects compared to state of art methods.     

A Network-Pharmacology-Combined Integrated Pharmacokinetic Strategy to Investigate the Mechanism of Potential Liver Injury due to Polygonum multiflorum

Polygonum multiflorum (PM) has been used as a tonic and anti-aging remedy for centuries in Asian countries. However, its application in the clinic has been hindered by its potential to cause liver injury and the lack of investigations into this mechanism. Here, we established a strategy using a network pharmacological technique combined with integrated pharmacokinetics to provide an applicable approach for addressing this issue. A fast and sensitive HPLC-QQQ-MS method was developed for the simultaneous quantification of five effective compounds (trans-2,3,5,4′-tetrahydroxystilbene-2-O-β-d-glucoside, emodin-8-O-β-d-glucoside, physcion-8-O-β-d-glucoside, aloe-emodin and emodin). The method was fully validated in terms of specificity, linearity, accuracy, precision, extraction recovery, matrix effects, and stability. The lower limits of quantification were 0.125–0.500 ng/mL. This well-validated method was successfully applied to an integrated pharmacokinetic study of PM extract in rats. The network pharmacological technique was used to evaluate the potential liver injury due to the five absorbed components. Through pathway enrichment analysis, it was found that potential liver injury is primarily associated with PI3K-Akt, MAPK, Rap1, and Ras signaling pathways. In brief, the combined strategy might be valuable in revealing the mechanism of potential liver injury due to PM.