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951.
Mengyu Yuan Hui Xu Cheng Wang Prof. Yong Wang Yuan Wang Prof. Xiaomei Wang Prof. Yukou Du 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(50):12851-12856
Optimizing the electronic and synergistic effect of hybrid electrocatalysts based on Pt and Pt-based nanocatalysts is of tremendous importance towards a superior hydrogen evolution performance under both acidic and alkaline conditions. However, developing an ideal Pt-based hydrogen evolution reaction (HER) electrocatalyst with moderated electronic structure as well as strong synergistic effect is still a challenge. Herein, we fabricated boron (B)-doped PtNi nanobundles by a two-step method using NaBH4 as the boron source to obtain PtNi/Ni4B3 heterostructures with well-defined nanointerfaces between PtNi and Ni4B3, achieving an enhanced catalytic HER performance. Especially, the PtNi/Ni4B3 nanobundles (PtNi/Ni4B3 NBs) can deliver a current density of 10 mA cm−2 at the overpotential of 14.6 and 26.5 mV under alkaline and acidic media, respectively, as well as outstanding electrochemical stability over 40 h at the current density of 10 mA cm−2. Remarkably, this approach is also universal for the syntheses of PtCo/Co3B and PtFe/Fe49B with outstanding electrocatalytic HER performance. 相似文献
952.
A nucleophilic substitution reaction of an α‐ferrocenyl alcohol with various amines, indoles and thiols was successfully developed by using a catalytic amount of Bi(NO3)3.5H2O at room temperature without the aid of phase transfer catalyst. The reactions proceeded in aqueous media, leading to the formation of new C=C, C=N and C=S bonds bearing ferrocenyl substituent with high efficiency. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
953.
Dr. Lihui Chen Haifeng Hu Yuzhou Chen Yuan Li Prof. Jing Gao Prof. Guohua Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(3):1057-1065
For plasmonic copper-deficient Cu2−xS nanoparticles (NPs), accurate control of the crystal phase and morphology is highly desirable as both of which are known to determine the localized surface plasmon resonance (LSPR) wavelength and amplitude. Here, how the sulfur precursor reactivity in the synthesis of Cu2−xS NPs affects the resulting crystal phase and morphology is examined. Djurleite Cu1.94S, roxbyite Cu1.8S, digenite Cu1.8S as well as covellite CuS nanodisks were synthesized by using 1-dodecanethiol, N,N-dibutylthiourea, and crystal sulfur 1-octadecene/oleylamine solutions and their crystal phase dependent LSPR properties were exhaustively discussed. In addition, crystal phase interconversion between covellite CuS and djurleite/roxbyite Cu2−xS was realized in the presence of the above sulfur precursors. On the other hand, djurleite Cu1.94S nanorods rather than nanodisks were prepared by replacing 1-dodecanethiol with more reactive tert-dodecanethiol. The structural and morphological Cu2−xS NPs here holds great promise in the application of photothermal therapy, photocatalysis, surface-enhanced Raman scattering (SERS), and many others. 相似文献
954.
DETERMINATION OF QUADRICEPS FORCES IN SQUAT AND ITS APPLICATION IN CONTACT PRESSURE ANALYSIS OF KNEE JOINT 总被引:1,自引:0,他引:1
While the quadriceps muscles of human body are quite important to the daily activities of knee joints,the determination of quadriceps forces poses significant challenges since it cannot be measured in ... 相似文献
955.
Ta2O5/SiO2 dielectric mirrors deposited by ion beam sputtering (IBS) are studied. The multi-shot laserinduced damage threshold (LIDT) and its dependence on the number of shots are investigated, after which we find that the multi-shot LIDT is lower than that of single-shot. The accumulation effects of defects play an important role in the multi-shot laser damage. A simple model, which includes the conduction band electron production vsa multiphoton and impact ionizations, is presented to explain the experimental phenomena. 相似文献
956.
Jian Ni Lap Keung Chu Feng Wu Domenic Sculli Yuan Shi 《European Journal of Operational Research》2012
This paper addresses the problem of mitigating procurement risk that arises from volatile commodity prices by proposing a hedging strategy within a multi-stage time frame. The proposed multi-stage hedging strategy requires a commodity futures position to be correctly initialised and rebalanced with adequate volumes of short/long positions, so as to reduce the volatility in the total procurement cost that would otherwise be generated by varying commodity spot prices. The novelty in the approach is the introduction of the rebalancing of commodity futures position at defined intermediate stages. To obtain an efficient or near optimal multi-stage hedging strategy, a discrete-time stochastic control model (DSCM) is developed. Numerical experiments and Monte Carlo simulation are used to show that the proposed multi-stage hedging strategy compares favourably with the minimal-variance hedge and the one-stage hedge. A close-form optimal solution is also presented for the case when procurement volume and price are independent. 相似文献
957.
Synthesis of multi‐functionalized carbonyl compounds by palladium–catalysed γ‐substitution of MBH adducts with activated amides
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Gao Pei‐Sen Zhang Jin‐Lei Li Ning Zheng Zhan Jiang Yuan Yang Gao Zi‐Wei Zhang Weiqiang Xu Li‐Wen 《应用有机金属化学》2018,32(3)
Catalytic allylic γ‐substitution with Morita‐Baylis‐Hillman (MBH) adducts for creating a new family of unsymmetrical dicarbonyl compounds was presented in this work, in which a variety of allylated amide products were achieved in good yields and high regioselectivity with excellent linear‐to‐branched ratios. Especially, it was found that the Pd/HZNU‐Phos complex exhibited remarkably high activity (with a TON up to 16800) in this transformation between dicarbonyl amides and MBH adducts. In addition, the possibly multisite interaction between multifunctional Pd/HZNU‐Phos catalyst system and substrates might responsible for its exceptionally high efficiency in this reaction. 相似文献
958.
In this work, a projection algorithm is considered for treating strongly continuous semigroups of demicontinuous pseudocontractions. Theorems of strong convergence of fixed points are established in the framework of real Hilbert spaces. 相似文献
959.
A novel inorganic-organic hybrid supramolecular compound,[(3-nitroanilinium~+)(18-crown-6)][IO_4](CH_3OH)(1),was discovered as phase-transition materials displaying dielectric anomalous behaviors.The yellow block crystal formed by N-H…O hydrogen bonding that made contact through the cavity of 18-crown-6 was characterized by single-crystal X-ray diffraction,elemental analysis,infrared analysis,thermogravimetric analysis,differential scanning calorimetry,and potential-energy calculations.Differential scanning calorimetry measurements indicate that the compound experiences a reversible phase transition at around 220 K.Temperature-dependent dielectric measurements further confirm the phase transitions.Potential-energy calculations demonstrate that the phase transition occurs due to the molecular order-disorder rotation of CH_3OH,whereas the space grouping of the crystal remains unchanged. 相似文献
960.