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271.
Juanzi Shi HongXia Shen Lisheng Zhang Peijie Wang Yan Fang Guozhen Wu 《Journal of Raman spectroscopy : JRS》2015,46(12):1303-1309
An algorithm is employed to retrieve the differential bond polarizabilities (DBP) of the C‐C bonds from the Raman optical activity spectrum of (‐)β‐pinene. (‐)β‐pinene possesses two stereo centers (chiral centers) and a local mirror reflection that interchanges the S type part and R type part in one molecular. It is demonstrated that this local mirror reflection could induce an approximate (or symmetry breaking) mirror reflection that reverses the signs of the DBP of the pair bond coordinates that are related to each other by the mirror reflection.This can be called intramolecular enantiomerism (IE). More cases of IE are discussed by the analysis of (‐)α‐pinene, (R)‐(+)‐4‐isopropyl‐1‐methylcyclohexene and (R)‐(+)‐3‐methylcyclohexanone together with previously studied limonene case. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
272.
273.
Li Yang Fu Xuan Li Xu-Xin Zhang Fang Wu Qiang Wang Yun Yan Ze-Yi 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):877-888
Journal of Radioanalytical and Nuclear Chemistry - In this study, the imidazole-based poly(ionic liquid)s (PILs) synthesized by one step method has been applied for the enrichment and recovery of... 相似文献
274.
In order to reduce greenhouse gas emissions, developing flame retardants from bio-based resources has aroused extensive interest in recent years. In this work, we utilized furfural(biomass) and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO) to synthesize a biobased co-curing agent(FGD) to combine with 4,4'-diaminodiphenyl methane(DDM) for obtaining a low-phosphorus loading flame-retardant epoxy thermosets. The introduction of FGD decreased the activation energy of the curing progress, enhanced the mechanical properties of the epoxy thermosets, and did not affect the glass transition temperature of the epoxy thermosets. EP-5.0 had a lower thermal degradation rate and a doubled char yield compared with EP-0. The phosphorus content of EP-5.0 was only 0.45 wt%, while EP-5.0 reached the UL-94 V-0 rating with a high LOI value of 32%. Compared with EP-0, the PHRR of EP-2.5 and EP-5.0 decreased by 22.3% and 31.3%, respectively. The SEM results showed that the addition of FGD made the char residues more uniform and denser, which could effectively prevent combustible volatiles from escaping from the degradation area to the flame area and isolate the heat transfer so that the epoxy thermosets had an excellent flame-retardant performance. 相似文献
275.
Li Tingting Wang Fang Xia Liangshu 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(6):2655-2665
Journal of Radioanalytical and Nuclear Chemistry - Uranium, as a highly toxic radioactive contaminant existing in mine wastewater and contaminated groundwater, has sparked widespread alarm in... 相似文献
276.
Research on Chemical Intermediates - A new method has been developed for the synthesis of a cage-like sulfuryl-bridged triazinane molecule HEXS by acidic condensation of a glycoluril analog with... 相似文献
277.
Ding Congming Yuan Meini Cao Xiaochen Zheng Lirong Wang Kai 《Journal of Solid State Electrochemistry》2022,26(11):2445-2455
Journal of Solid State Electrochemistry - In order to meet the growing energy demand, it is of great significance to develop high-performance electrochemical energy storage materials. In this... 相似文献
278.
Science China Chemistry - 相似文献
279.
Fang Sheng Bangyan Hu Qiang Jin Jiangbo Wang Cuiyun Wu Zhengrong Luo 《Molecules (Basel, Switzerland)》2021,26(10)
Husk and pellicle as the agri-food waste in the walnut-product industry are in soaring demand because of their rich polyphenol content. This study investigated the differential compounds related to walnut polyphenol between husk and pellicle during fruit development stage. By using ultra-high performance liquid chromatography-quadrupole-orbitrap (UHPLC-Q-Orbitrap), a total of 110 bioactive components, including hydrolysable tannins, flavonoids, phenolic acids and quinones, were tentatively identified, 33 of which were different between husk and pellicle. The trend of dynamic content of 16 polyphenols was clarified during walnut development stage by high-performance liquid chromatography (HPLC). This is the first time to comprehensive identification of phenolic compounds in walnut husk and pellicle, and our results indicated that the pellicle is a rich resource of polyphenols. The dynamic trend of some polyphenols was consistent with total phenols. The comprehensive characterization of walnut polyphenol and quantification of main phenolic compounds will be beneficial for understanding the potential application value of walnut and for exploiting its metabolism pathway. 相似文献
280.