Exchange model of displacement in porous media

A displacement model constructed on the assumption of the exchange of components between the volumes of the pore space moving and not moving in the direction of displacement is considered. The theoretical solution is shown to be in good agreement with the actual results of the displacement of oil by water. Criterial equations for predicting the interphase exchange coefficient and the relation between the nonmoving and moving volumes of the pore space are constructed on the basis of a series of experiments in uncemented porous media.Translated from Izvestiya Akademii Nauk SSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 91–97. January–February, 1991.     

Mutual coupling of elements in finite microstrip antennas

The mutual coupling of the radiating elements in microstrip antennas is studied using a rigorous electrodynamic approach in which the field singularities at the radiator edges are taken into account with analytic accuracy. A spectral method is employed in combination with a method of semi-inversion by extraction of the Green-function singularity. The degree of interaction of the elements of microstrip structures at the fundamental and higher current harmonicsis determined, and the applicability of various approximations is assessed.Radio-Astronomy Institute, Academy of Sciences of Ukraine. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 35, No. 8, pp. 688–701, August, 1992.     

Quantification of stable minor species in confined flames by cavity ring-down spectroscopy: application to NO

Cavity ring-down spectroscopy (CRDS) is used to measure the NO mole fraction formed in the burnt gases of low-pressure premixed flames. It is shown that the line-of-sight absorption is greatly increased by the contribution of the NO molecules surrounding the burner. This contribution has been quantified by developing a mathematical procedure taking into account the spatial and spectral features of the CRDS measurement. Calculations have been undertaken in the general case of a stable species not consumed in the flame. The most sensitive parameter is the temperature both in the flame and outside the flame. Simulations allow the selection of the best spectroscopic transitions for a given flame (i.e. a given temperature profile), ensuring the weakest influence of the inaccuracy affecting the temperature determination. High quantum states belonging to the A–X (0–1) band of NO have been found to be the most valuable and have led to a NO mole fraction determination with an accuracy of ±13%. NO absorption in the flame was completely masked using the A–X (0–0) band. Finally, the prompt-NO mole fraction formed in a methane/air flame stabilized at 33 Torr is obtained by combining CRDS and laser induced fluorescence techniques. Received: 12 October / Revised version: 1 February 2002 / Published online: 14 March 2002     

Mobile phase versus stationary phase approaches to the direct injection of biological fluids in liquid chromatography

The liquid chromatographic analysis of drugs in urine through direct injection without any sample pretreatment was extended to micellar chromatography with nonionic surfactants, the Pinkerton ISRP column and the shielded hydrophobic phase (Hisep) column. The feasibility of using each was demonstrated through the determination of the diuretic, hydrochlorothiazide, in urine. Good separation, recovery, precision and linearity, and adequate limits of detection were obtained for this analysis with all three techniques. The advantages and limitations of the mobile phase approach of micellar chromatography and the two stationary phase approaches are discussed for the direct injection of urine as well as other biological fluids.     

Transport properties of a side-chain liquid-crystalline polymer. Poly(4-acryloyloxy biphenyl)

The transport properties of a side-chain liquid-crystalline polymer forming a smectic A phase have been investigated using dichloromethane as a permeant. Samples differing in the isotropization enthaoly were analyzed. A. Correlation between this thermal parameter and sorption has been found, while the diffusion coefficient is substantially the same in all samples. The results obtained can be explained in terms of a biphasis model in which a disordered permeable phase is present within the liquid-crystalline phase, which is impermeable to the diffusant molecules.     

The structure of the nematic-isotropic interface in polymer systems

The structure of the nematic-isotropic interfacial layer is studied theoretically for systems formed by rod-like and persistent macromolecules. It is shown that the width of interfacial layer is normally of the order of the straight part of a molecule. This allows us to use the approach which describes intermolecular interactions phenomenologically (i.e. it allows us to consider all interactions), at the same time this approach describes molecular flexibility microscopically (i.e. it allows us to study the effects of flexibility correctly). It was found, that non-monotonic gradient profiles in the surface layer of the order parameter or of the concentration of molecules as a function of the coordinate perpendicular to the interface are possible. For example, a thin layer with abnormal ordering of molecules along the surface may exist near the interface for some systems.     

Deformation of doped NaCl crystals during uniaxial compression at temperatures of 4.2–293 K

The impurity weakening of crystalline NaCl:Mg and NaCl:Mn associated with purification of the matrix in a melt is demonstrated. This effect is manifested in a consistent change in the yield strength and mobility of dislocations. Its unusual temperature dependence is determined: in a number of cases weakening becomes greater as the temperature is lowered within the interval 293–4.2 K. A deviation in the elastic region of the stress-strain curves is observed to increase as the temperature is lowered. Plasticizing of crystalline NaCl is established: when the deformation temperature is lowered from 293 to 77 and 4.2 K the rate of rise in the yield strength of Cd²⁺ and Sr²⁺ doped samples is lower than that of undoped samples. An explanation for this fact is proposed. Fiz. Tverd. Tela (St. Petersburg) 39, 313–317 (February 1997) Deceased.     

Short-range order in miscible polymer blends: A monte carlo study

Local ordering in miscible binary polymer blends with strong attractive interactions between the two types of chains was investigated by computer simulation of allowable conformations on an incompressible cubic lattice. A tendency toward maximum ordering (in which chains pack in alternate parallel rows) is shown by the calculation of pair correlations and in “snapshots” of the mixtures. A specific directional interaction is not necessarily required for ordering. A comparison of these results with those recently obtained using mean-field theory is presented. The heat capacity of mixing was also calculated and found to be positive, with a value close to that reported experimentally.     

Intersegmental interaction and critical concentrations in PET–HFIP solutions

Spectroscopic determinations of the concentrations associated with the onset of intermolecular interaction in solutions of poly(ethylene terephthalate) (PET) are described. The intersegment forces perturb the electronic spectra and induce ground-state aggregation. These phenomena become observable at different chain densities, reflecting the influence of concentration on the coil dimensions, as well as the dynamical nature of the interactions. An estimate of the equilibrium constant for PET dimer formation in hexafluoroisopropanol is reported.