Mechanism transition of self-pumped phase conjugation in KTa1 −xNbxO3:Fe crystals

Mechanism transitions of Self-Pumped Phase Conjugation (SPPC) with wavelength and doping concentration are observed in KTN:Fe (KTa_{1 –x} Nb _x O₃:Fe with _x = 0.48) crystals. The SPPC mechanism in KTN: Fe (0.4 wt. %) crystal transforms from Stimulated Photorefractive Backscattering and Four-Wave Mixing (SPB-FWM) to cat (or total internal reflection) as the wavelength increases from 514.5 nm to 620 nm. SPPC at 514.5 nm is formed with the cat mechanism in a 0.2 wt. % doped KTN:Fe crystal, while with the SPB-FWM mechanism in a 0.4 wt. % doped one. These mechanism transitions are discussed with respect to the dependence of the backscattering gain coefficient of the crystals on wavelength and doping concentration.     

掺杂8-羟基喹啉铝薄膜的电致发光特性研究

在具有电致发光(EL)的有机整合染料8-羟基喹啉铝(Alq3)中接以染料罗丹明6G(R6G),用真空热蒸发的方法制备器件,获得了峰值波长575nm的黄色直流薄膜电致发光,从而通过掺杂改变了发光颜色.并在Alq3发光层不同区域插入一掺杂薄层(Alq3:R6G),利用其发光波长与未掺杂部分(Alq3)的不同,以此作为“探测层”,通过对器件光谱及电学特性的测量与分析,探讨了有关发光区域,发光机理,界面对发光影响等基本问题.     

Origin and manifestation of the anharmonic potential felt by an ion-cloud in an actual Paul trap

The anharmonic potential felt by a single-species ions confined in a rf quadrupole trap which results from a non-ideal trap configuration and the charge distribution of the ion cloud is studied. The rf resonance-absorption spectra are explained by a Duffing oscillator and a representation of the line-shape parameter is derived. For > 0.77, the electric signals will exhibit hysteresis. The relation with the anharmonic potential is discussed.     

Observation of Δn=1 dielectronic recombination resonances of boronlike argon

We report here an observation ofn=1 dielectronic recombination resonances of boron-like argon in the energy region 140–195 eV. With the cooler's electron beam as a target, a resolution of approximately 0.6 eV FWHM was obtained in the observed energy range. The energies of the doubly excited states were estimated with a Hartree-Fock calculation, which indicates that the observed resonances are from Ar¹³⁺(1s²2s²2p) to Ar¹²⁺(1s²2s²3l3l) and Ar¹²⁺(1s²2s2p3l3l) transitions.     

Oligodeoxyfluorosides: Strong Sequence Dependence of Fluorescence Emission

We describe the properties of a series of oligomeric polyfluorophores assembled on the DNA backbone. The 11 oligomers (oligodeoxyfluorosides, ODFs), 4-7 monomers in length, were composed of only two fluorescent monomers and a spacer in varied sequences, and were designed to test how fluorescent nucleobases can interact electronically to yield complexity in fluorescence emission. The monomer fluorophores were deoxyribosides of pyrene and perylene, which emit light in violet and blue wavelengths, respectively. The experiments show that simple variation in sequence and spacing can dramatically change fluorescence, yielding emission maxima ranging from 380 to 557 nm and visible colors from violet to orange-red. Fluorescence lifetime data, excitation spectra, and absorption data point to a number of multi-fluorophore electronic interactions, including pyrene-pyrene and perylene-perylene excimers, pyrene-perylene exciplexes, as well as monomer dye emissions, contributing to the final spectral outcomes. Thus, two simple fluorophores can be readily combined to give emissions over much of the visible spectrum, all requiring only a single excitation. The results demonstrate that fluorescent nucleobases in oligomeric form can act cooperatively as electronic units, and that fluorophore sequence in such oligomers is as important as fluorophore composition in determining fluorescence properties.     

稀土—4—（2—吡啶偶氮）间苯二酚螯合物的高效液相色谱分离和测定

本文讨论了反相离子对液相色谱法分离和检测稀土-4-(2-吡啶偶氮)间苯二酚螯合物的各种条件,在12 min内完成了9种稀土螫合物的分离,校正曲线的线性范围是(ppm):La(0.01～3.20),Ce(0.03～2.8),Pr(0.06～3.5),Nd(0.05～3.8),Sm(0.01～3.0),Eu(0.05～3.4),Tb(0.02～3.0),Ho(0.01～3.4),Er(0.06～4.0).变异系数小于1.2％.