铜(Ⅱ)-2,2′-联吡啶-铬天菁S三元络合物极谱吸附波及应用

本文提出了一个灵敏的具有选择性的溶出伏安法测超痕量铜的方法。在0.01mol／LNH3·H2O-NH4Cl溶液中（pH＝9．3），铜（Ⅱ）－2，2′-联吡啶（Dipy）-铬天菁S（CAS）能生成具吸附性的电活性三元络合物，在＋0.1V（vs．SCE）电位下富集，阴极溶出峰电位是一0．18V，峰电流与Cu（Ⅱ）的浓度在9．0×10－9～7.0×10－7mol／L范围内成正比，检测限是3．0×10－9mol／L，这一方法已用于测定环境水中痕量铜，回收率在98．5％，102．5％之间。     

Tris(2,2''''-bipyridyl)ruthenium(Ⅱ) electrochemiluminescence (ECL) enhanced by rutin on platinum electrode

Ru(bpy)_(3~(2 )) electrochemiluminescence (ECL) was applied to determination of rutin. ECL intensity of Ru(bpy)_(3~(2 ))could be enhanced in the presence of rutin in basic solution on platinum electrode. At pH 9.9, light emission intensity was found to be linear with rutin in the range of 1-50 mmol/L.     

Raman spectroscopic analysis of supersaturated aqueous solution of MgO.B2O3-32%MgCl2-H2O during acidification and dilution

Raman spectra of supersaturated aqueous solution of MgO.B2O3-32%MgCl2-H2O during acidification/alkalization and dilution have been studied. The assignments of the recorded Raman shift are given. The main existing forms of polyborate anions and their interaction in borate aqueous solution have been proposed through spectroscopic analysis. The experimental results indicate that the higher concentration of cation are beneficial not only to the dissolution of boric acid but also to the polymerization of polyborate anions. The existing forms and interaction among them also depend on the concentration of boron and the pH value in solution.     

HPLC–MS Analysis of Isoniazid in Dog Plasma

A simple, rapid, and sensitive liquid chromatography–mass spectrometric (LC–MS) method was developed and validated for the determination of isoniazid in dog plasma. Plasma samples were deproteined with methanol and separated on a C₁₈ column interfaced with a single quadrupole mass spectrometer, using 0.1% formic acid–acetonitrile (91:9 v/v) as mobile phase. Detection was performed by positive electrospray ionization with selected ion monitoring at m/z 138 for isoniazid and 152 for entecavir maleate internal standard. Linearity was obtained over the range of 25–5,000 ng mL^?1, with a lower limit of quantification of 25 ng mL^?1. The intra- and inter-day precision was less than 2.7% in terms of relative standard deviation. Accuracy, expressed as relative error, ranged from ?2.0 to 8.0%. Plasma samples were analysed within 5 min. The method was successfully applied to the evaluation of the pharmacokinetics of isoniazid in dog plasma.     

N－取代硫代磷酰胺二乙酯合成新方法的研究

以ＰＥＧ作相转移催化剂，在无机碱（Ｋ＿２ＣＯ＿３或Ｎａ＿２ＣＯ＿３）存在下，用乙基氯化物（Ｏ，Ｏ－二乙基硫代磷酰氯）与不同的胺反应，合成了六种Ｎ－取代硫代磷酰胺二乙酯，其结构经ＩＲ、ＮＭＲ和元素分析证实。     

有机激光染料-1,4-双[5’-(2’-苯基恶唑基)]苯及其2’-(3”-取代苯基)衍生物的光性能研究(Ⅱ)

本文报导了1,4-双[5’-(2’-苯基恶唑基)]苯及其2’-(3”-取代苯基)衍生物共八个化合物,其中除母体化合物外,其余化合物至今尚未见报导。测定了它们的红外光谱、质谱、紫外光谱、荧光光谱、荧光量子产率和激光转换效率。     

A novel trilinear decomposition algorithm： Three-dimension non-negative matrix factorization

Non-negative matrix factorization(NMF)is a technique for dimensionality reduction by placing non-negativity constraints onthe matrix.Based on the PARAFAC model,NMF was extended for three-dimension data decomposition.The three-dimension non-negative matrix factorization(NMF3)algorithm,which was concise and easy to implement,was given in this paper.The NMF3algorithm implementation was based on elements but not on vectors.It could decompose a data array directly without unfolding,which was not similar to that the traditional algorithms do.It has been applied to the simulated data array decomposition andobtained reasonable results.It showed that NMF3 could be introduced for curve resolution in chemometrics.     

Synthesis of aza-, oxa-, and thiabicyclo[3.1.0]hexane heterocycles from a common synthetic intermediate

[reaction: see text] An efficient and stereospecific approach to the synthesis of structurally constrained aza-, oxa-, and thiabicyclo[3.1.0]hexane heterocycles has been achieved through application of the intramolecular cyclopropanation reaction of diazoacetates. The various constrained heterocycles (X = N, O, or S) are conveniently prepared from a common diol intermediate accessible from readily available cinnamyl alcohols. Application of the methodology to the synthesis of conformationally constrained oxazolidinone antibacterials is also discussed.     

超临界状态下炭基材料的储氢

评介了目前各种储氢方法，指出了炭基材料作为储氢材料的优势，综述了近年来纳米炭材料在储氢方面的进展，详细探讨了超临界状态下氢气在纳米孔隙中的吸附机理，并在此基础上提出了研究中的问题及进一步的研究方向。     

低硫可膨胀石墨的制备

低硫可膨胀石墨的制备宋克敏，路文义，高淑英，阎秋燕（河北教育学院石家庄０５００９１）关键词低硫可膨胀石墨，制备，过氧化氢，硫酸柔性石墨具有耐高温、耐酸碱、抗拉、抗压、抗辐射、回弹性等优良性能，被广泛应用于化工、机械、肮天、原子能等领域。但其原材料可膨...