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961.
Kim YH Lee DK Cha HG Kim CW Kang YC Kang YS 《The journal of physical chemistry. B》2006,110(49):24923-24928
Cu deposition on the surface of spherical SiO2 nanoparticles was studied to achieve the hybrid structure of Cu-SiO2 nanocomposite. SiO2 nanoparticles served as seeds for continuous Cu metal deposition. The chemical structure and morphology were studied with X-ray photoelectron spectroscopy (XPS), scanning electron microscope energy dispersive X-ray (SEM-EDX), and a transmission electron microscope (TEM). The antibacterial properties of the Cu-SiO2 nanocomposite were examined with disk diffusion assays. The homogeneously formed Cu nanoparticles on the surface of SiO2 nanoparticles without aggregation of Cu nanoparticles showed excellent antibacterial ability. 相似文献
962.
Lopez-Salido I Lim DC Dietsche R Bertram N Kim YD 《The journal of physical chemistry. B》2006,110(3):1128-1136
Au nanoparticles grown on mildly sputtered Highly Ordered Pyrolytic Graphite (HOPG) surfaces were studied using Scanning Tunneling Microscopy (STM) and X-ray Photoelectron Spectroscopy (XPS). The results were compared with those of Ag nanoparticles on the same substrate. By varying the defect densities of HOPG and the Au coverages, one can create Au nanoparticles in various sizes. At high Au coverages, the structures of the Au films significantly deviate from the ideal truncated octahedral form: the existence of many steps between different Au atomic layers can be observed, most likely due to a high activation barrier of the diffusion of Au atoms across the step edges. This implies that the particle growth at room temperature is strongly limited by kinetic factors. Hexagonal shapes of Au structures could be identified, indicating preferential growth of Au nanostructures along the (111) direction normal to the surface. In the case of Au, XPS studies reveal a weaker core level shift with decreasing particle size compared to the 3d level in similarly sized Ag particles. Also taking into account the Auger analysis of the Ag particles, the core level shifts of the metal nanoparticles on HOPG can be understood in terms of the metal/substrate charge transfer. Ag is (partially) positively charged, whereas Au negatively charged on HOPG. It is demonstrated that XPS can be a useful tool to study metal-support interactions, which plays an important role for heterogeneous catalysis, for example. 相似文献
963.
Jeong YG Ramalingam S Archer J Hsu SL Paul CW 《The journal of physical chemistry. B》2006,110(6):2541-2548
The influence of copolymer configuration on the phase behavior of various ternary polymer blends containing a crystallizable polyester, a noncrystallizable polyether, and an acrylic random copolymer of different chain configuration was investigated. In these ternary blends, the acrylic random copolymer is typically added to control rheological properties at elevated temperatures. In fact, the acrylic random copolymers composed of various compositions of MMA and nBMA were found to have different miscibility with polyester as well as polyether, leading to substantially different phase behavior of ternary blends. Remarkable temperature dependence was also found. The mean-field Flory-Huggins theory for the free energy of mixing, extended to ternary polymer blends, was adopted for predicting phase diagrams where the exact spinodal and binodal boundaries could be calculated. Phase diagrams of ternary blends, predicted by the Flory-Huggins formulations and related calculations, were in good agreement with experimental phase diagrams. The differences observed in the rheological processes of various ternary blends with different acrylic copolymers were directly related to changes in miscibility, associated phase behavior, and chain configuration. 相似文献
964.
[reaction: see text] Biologically important N-beta-hydroxyethylaziridine intermediates were conveniently prepared by regioselective ring-opening reactions of diversely substituted epoxides. Ethyleneimine generated in situ under basic conditions from beta-chloroethylamine was used as a nucleophile to open the epoxides in an aqueous environment. 相似文献
965.
Ooya T Inoue D Choi HS Kobayashi Y Loethen S Thompson DH Ko YH Kim K Yui N 《Organic letters》2006,8(15):3159-3162
[Structure: see text] A polypseudorotaxane consisting of cucurbit[7]uril (CB[7])/N,N'-(3-phenylenebis(methylene)dipropargylamine (PMPA), [2]pseudorotaxane, and 2,6-O-dimethyl beta-cyclodextrin (DM-beta-CD)/alpha,omega-bisazidopropylene glycol 400 [2]pseudorotaxane was synthesized using the "click" reaction. The polypseudorotaxane structure was maintained in aqueous solution over a wide range of pH values with the DM-beta-CD units contributing to increased solubilization of the polypseudorotaxane without dethreading. The pH-responsive movement of the CB[7] units in the polypseudorotaxane was also observed. 相似文献
966.
Young L Arms DA Dufresne EM Dunford RW Ederer DL Höhr C Kanter EP Krässig B Landahl EC Peterson ER Rudati J Santra R Southworth SH 《Physical review letters》2006,97(8):083601
We have developed a synchrotron-based, time-resolved x-ray microprobe to investigate optical strong-field processes at intermediate intensities (10(14) - 10(15) W/cm2). This quantum-state specific probe has enabled the direct observation of orbital alignment in the residual ion produced by strong-field ionization of krypton atoms via resonant, polarized x-ray absorption. We found strong alignment to persist for a period long compared to the spin-orbit coupling time scale (6.2 fs). The observed degree of alignment can be explained by models that incorporate spin-orbit coupling. The methodology is applicable to a wide range of problems. 相似文献
967.
968.
We provide explicit constructions of particularly convenient dual pairs of Gabor frames. We prove that arbitrary polynomials
restricted to sufficiently large intervals will generate Gabor frames, at least for small modulation parameters. Unfortunately,
no similar function can generate a dual Gabor frame, but we prove that almost any such frame has a dual generated by a B-spline.
Finally, for frames generated by any compactly supported function φ whose integer-translates form a partition of unity, e.g., a B-spline, we construct a class of dual frame generators, formed
by linear combinations of translates of φ. This allows us to chose a dual generator with special properties, for example, the one with shortest support, or a symmetric
one in case the frame itself is generated by a symmetric function. One of these dual generators has the property of being
constant on the support of the frame generator. 相似文献
969.
Jing-wen Li Zhi-wen Wang Jaeun Lee Moo Young Sohn Zhong-fu Zhang En-qiang Zhu 《应用数学学报(英文版)》2010,26(3):525-528
In this paper we get some relations between α(G), α'(G), β(G), β'(G) and αT(G), βT(G). And all bounds in these relations are best possible, where α(G), α'(G),/3(G), β(G), αT(G) and βT(G) are the covering number, edge-covering number, independent number, edge-independent number (or matching number), total covering number and total independent number, respectively. 相似文献
970.
Zhimin Xie Young‐Jin Yum Chul‐Kyoung Lee 《Journal of Macromolecular Science: Physics》2013,52(3):561-567
It has been known that the carbon black (CB) network is responsible for the electrical and mechanical behaviors of filled rubber. Due to the complexity involved in the filled rubber in relation to the conductive mechanism of the CB network, there has been little work concerned with simulation of the electrical behavior at large strains. Based upon an infinite circuit model, the electrical resistivity of CB filled rubber under elongation is simulated. For CB (N330) filled natural rubber with volume fraction of 27.5%, the simulated electrical resistivity increases with elongation at small stains, corresponding to the breakup of the agglomerates. The reduction in resistivity at larger strains corresponds to the decrease of the junction width, which results in a decrease of the contact resistance. Good agreement is found between the simulations and the experimental data available in the literature. The simulated results confirm the effects of the breakdown of the CB network and the alignment of CB aggregates under strain on the electrical resistivity. 相似文献