全文获取类型
收费全文 | 6412篇 |
免费 | 1299篇 |
国内免费 | 1089篇 |
专业分类
化学 | 5010篇 |
晶体学 | 173篇 |
力学 | 402篇 |
综合类 | 67篇 |
数学 | 715篇 |
物理学 | 2433篇 |
出版年
2024年 | 33篇 |
2023年 | 218篇 |
2022年 | 382篇 |
2021年 | 337篇 |
2020年 | 392篇 |
2019年 | 369篇 |
2018年 | 299篇 |
2017年 | 259篇 |
2016年 | 332篇 |
2015年 | 384篇 |
2014年 | 395篇 |
2013年 | 487篇 |
2012年 | 598篇 |
2011年 | 554篇 |
2010年 | 365篇 |
2009年 | 369篇 |
2008年 | 421篇 |
2007年 | 381篇 |
2006年 | 319篇 |
2005年 | 290篇 |
2004年 | 189篇 |
2003年 | 185篇 |
2002年 | 184篇 |
2001年 | 160篇 |
2000年 | 144篇 |
1999年 | 119篇 |
1998年 | 85篇 |
1997年 | 75篇 |
1996年 | 90篇 |
1995年 | 66篇 |
1994年 | 55篇 |
1993年 | 48篇 |
1992年 | 39篇 |
1991年 | 28篇 |
1990年 | 31篇 |
1989年 | 19篇 |
1988年 | 14篇 |
1987年 | 12篇 |
1986年 | 12篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 14篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1973年 | 3篇 |
1968年 | 1篇 |
1957年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有8800条查询结果,搜索用时 15 毫秒
41.
42.
The major drawback of liquid chromatography/mass spectrometry (LC/MS) for the analysis of mixtures is the non-quantitative nature of these studies. The ionization efficiency of the various components in the mixture (e.g., a compound and its metabolites) can vary greatly and, therefore, relative intensities of signals cannot be related to relative abundance. A chip-based nanoelectrospray ionization source was used to compare the ionization efficiencies of compounds with different physical-chemical characteristics. The data indicate that the ionization efficiencies vary much less with the chip-based device than by LC/MS. This was ascribed to the generation of a much higher electric field around the nozzles, which supplies a large excess of protons to the small droplets and reduces/eliminates the differences in the ionization efficiency for the analytes. 相似文献
43.
A simple, rapid and sensitive high-performance liquid chromatographic method with fluorescence detection for the simultaneous determination of oxytetracycline, doxycycline, tetracycline and chlortetracycline was developed, and successfully applied to the analysis of commercial tetracycline antibiotics. The separation was performed on a reverse-phase C18 column with a gradient elution composed of methanol and sodium acetate buffer (containing disodium ethylenediaminetetraacetate and calcium chloride, pH 8.10) as the mobile phase, and fluorescence detection at 532 nm (excitation at 380 nm). The detection limits for oxytetracycline, doxycycline, tetracycline and chlortetracycline were 0.1, 0.5, 0.3 and 0.4 g L–1, respectively. Data with respect to precision and accuracy were reported and discussed. 相似文献
44.
45.
以4种甲基取代戊二烯基为配体合成了4个过渡金属钒开环夹心羰基配合物[2,4-(CH3)2C5H5]2VCO(I),[2,3-(CH3)2C5H5]VCO(Ⅱ),[2-CH3C5H6]2VCO(Ⅲ)和[3-CH3C5H6]2VCO(Ⅳ),其中Ⅱ,Ⅲ,Ⅳ为新配合物,用X射线单晶衍射,IR,EPR法对所合成配合物进行了结构表征,发现I具有两种晶相。 相似文献
46.
Three new stephaoxocane‐type alkaloids, stephalonganines A–C ( 1 – 3 ), together with the known eletefine ( 4 ), were isolated from the whole plant of Stephania longa. Their structures were fully characterized spectroscopically, and the absolute configurations of the new alkaloids were assigned by comparison of their circular‐dichroism (CD) data with those of 1,2‐dihydrostephaoxocanine ( 5 ), in combination with 2D‐NMR experiments. 相似文献
47.
Three new alkaloids, longistylumphyllines A–C (1–3), together with the six known alkaloids deoxycalyciphylline B, deoxyisocalyciphylline B, methyl homosecodaphniphyllate, daphnicyclidin A, daphnicyclidin B, and daphnicyclidin F, were isolated from the stems and leaves of Daphniphyllum longistylum. Their structures and relative configuration were elucidated on the basis of spectroscopic data, especially 1D and 2D NMR techniques. 相似文献
48.
The covalent binding of pyrazine on Si(100) have been investigated using high-resolution electron energy loss spectroscopy (HREELS) and x-ray photoelectron spectroscopy. Experimental results clearly suggest that the attachment occurs exclusively through the bonding of the two para-nitrogen atoms with the surface without the involvement of the carbon atoms, as evidenced from the retention of the (sp2) C-H stretching mode in HREELS and a significant down shift of 1.6 eV in the binding energy of N 1s. The binding mechanism for pyrazine on Si(100) demonstrates that reaction channels for heteroatomic aromatic molecules are strongly dependent on the electronic properties of the constituent atoms. 相似文献
49.
ZhiZhiDU NaZHU YueMaoSHEN 《中国化学快报》2003,14(7):707-710
Antifungal assay-guided isolation of the ethanol extract of the aerial parts of Clematis tangutica yielded two novel triterpene saponins. Their structures were determined to be 3-O-α-L-arabinopyranosyl hederagenin 28-O-α-L-rhamnopyranosyl ester (1) and 3-O-β-D-glucopyranosyl-(1→4)-α-L-arabinopyranosyl hederagenin 28-O-α-L-rhamnopyranosyl ester (2) on the basis of spectral data and chemical reactions. 相似文献
50.