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601.
Suwa K. Yamamoto K. Akashi M. Takano K. Tanaka N. Kunugi S. 《Colloid and polymer science》1998,276(6):529-533
We examined the effects of salt on the lower critical solution temperature (LCST) and lower critical solution pressure (LCSP)
of aqueous solutions of poly (N-vinylisobutyramide), polyNVIBA, and compared them with those on poly(N-isopropylacrylamide), polyNIPAAm. We found that the addition of salt (such as Na2SO4, NaCl, or KCl) decreased the LCST of aqueous polyNVIBA from 45 °C to below 20 °C, almost linearly with the salt concentrations
and dependent on the type of salt. We observed a similar concentration-dependent decrease in LCST for polyNIPAAm. When KI
or NaSCN was added to each aqueous polymer solution, some smaller increases in LCST were observed at relatively low salt concentrations;
higher concentrations of salt gave an almost linear decrease in LCST. As for LCSP, the addition of most types of salt lowered
the transition pressure, but the effects were much more dependent on the type and the valence of the salt (especially of anion)
in both polymers. Salt with divalent anion showed a larger decrease in LCSP, but those with mono valent anion showed a relatively
small decrease, even showed a slight increase at lower salt concentrations in the case of polyNVIBA. Salt with I- or SCN- showed evident increases in LCSP up to 1 M and was maintained higher than the control even at 2 M. We discuss the interactions
of the amide group in the side chains of polymers and water and their perturbation by ions.
Received: 13 November 1997 Accepted: 22 January 1998 相似文献
602.
Exchange bias measurements of ferromagnetic/antiferromagnetic (F/AF) bilayers are typically performed with the magnetization of the F layer parallel to the AF interface. We describe measurements of Co/Pt multilayers with out-of-plane magnetic easy axis that are exchange biased with CoO. Field-cooling experiments with the applied field perpendicular and parallel to the sample plane exhibit loop shifts and enhanced coercivities. Modeling and comparison to biasing of samples with planar easy axis suggests such measurements provide a way to probe the spin projections at F/AF interfaces. 相似文献
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Hanjun Zhao Prof. Dr. Yuta Takano Dr. Devika Sasikumar Dr. Yukiko Miyatake Prof. Dr. Vasudevanpillai Biju 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(71):e202202014
The present study provides design guidance for unique multipotent molecules that sense and generate singlet oxygen (1O2). A rhodamine 6G-aminomethylanthracene-linked donor-acceptor molecule ( RA ) is designed and synthesized for demonstrating wavelength-dependent functionalities as follows; (i) RA acts as a conventional fluorogenic 1O2 sensor molecule like the commercially available reagent, singlet oxygen sensor green (SOSG), when it absorbs ultraviolet (UV)-visible light and reacts with 1O2. (ii) RA acts as a temporally controlled 1O2 sensing reagent under the longer wavelength (∼700 nm) photosensitization. RA enters an intermediate state after capturing 1O2 and does not become strongly fluorescent until it is exposed to UV, blue, or green light. (iii) RA acts as an efficient photosensitizer to generate 1O2 under green light illumination. The spin-orbit charge transfer mediated intersystem crossing (SOCT-ISC) process achieves this function, and RA shows a potential cancer-killing effect on pancreatic cancer cells. The wavelength-switchable functionalities in RA offer to promise molecular tools to apply 1O2 in a spatiotemporal manner. 相似文献