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491.
Hideo Kigoshi Yoshikazu Shizuri Haruki Niwa Hiyoyuki Yamada 《Tetrahedron letters》1982,23(14):1475-1476
Isolation and structural elucidation of two new acetylenic polyenes, -laurencenyne and -neolaurencenyne from the marine red alga were carried out, the former compound very recently being proposed to be a biosynthetic precursor of the C15 halogenated cyclic ethers, and . 相似文献
492.
Kanako Miyachi Kenzo Moriyama Takako Yamaguchi Hiroshi Tominaga Shinichiro Kamino Yoshikazu Fujita 《Analytical sciences》2007,23(9):1103-1107
A simple and highly sensitive spectrophotometric method for the determination of spermine (Spm) was established based on the ternary complex formation reaction of Spm with o-hydroxyhydroquinonephthalein (QP) as a xanthene dye and manganese(II) as a metal ion in the presence of a dispersion agent. The apparent molar absorptivity at 555 nm and the relative standard deviation of the proposed method were 1.4 x 10(5) dm(3) mol(-1) cm(-1) and 0.50% (n = 10), respectively. In the method for flow-injection analysis (FIA), which employs a single-channel flow manifold system, a good linear relationship was observed over the 2 - 20 pg microl(-1) range of Spm by direct injection. 相似文献
493.
Abe N Ito T Oyama M Sawa R Takahashi Y Chelladurai V Iinuma M 《Chemical & pharmaceutical bulletin》2011,59(2):239-248
Investigation of the highly polar chemical constituents in the stem of Hopea parviflora (Dipterocarpaceae) resulted in the isolation of four new resveratrol derivatives, hopeasides A and B (1, 2) (resveratrol pentamers), C (3) (resveratrol trimer), and D (4) (resveratrol dimer) together with nine known resveratrol oligomers (5-13). The new structures have a common partial structure of the 1-hydroxy-1-(3,5-dihydroxy-2-C-glucopyranosylphenyl)-2-(4-hydroxyphenyl)ethane-2-yl group after oxidative condensation of (E)-resveratrol-10-C-β-glucopyranoside (14). The structures were determined by spectroscopic analysis including 2D-NMR and computer-aided molecular modeling. The biogenetic relationship of the isolates and NMR characteristics caused by steric hindrance are also discussed in this paper. 相似文献
494.
Hoshino M Matsushita M Samma M Asano M Yamaguchi T Fujita Y 《Chemical & pharmaceutical bulletin》2011,59(6):721-724
Spectrophotometric determination of cobalt(II) was accomplished with vanillilfluorone (VF) in the presence of dimethylbenzyltetradecylammonium chloride (Zephiramine, Zep). In the determination of cobalt(II), Beer's law was obeyed in the range of 24-470 ng/ml, with an effective molar absorption coefficient (at 575 nm) and relative standard deviation of 1.35×10(5) l mol(-1) cm(-1) and 0.66% (n=5), respectively. The composition ratio of the colored complex was determined by the mole ratio and continuous variation methods, and it was found to be Co(II) : VF : Zep=1 : 2 : 4. Analysis of cyanocobalamin by the same procedure showed that cyanocobalamin could be determined in the concentration range of 0.5-0.11 μg/ml using the proposed method. 相似文献
495.
We establish a Liouville type result for a backward global solution to the Navier-Stokes equations in the half plane with the no-slip boundary condition. No assumptions on spatial decay for the vorticity nor the velocity field are imposed. We study the vorticity equations instead of the original Navier-Stokes equations. As an application, we extend the geometric regularity criterion for the Navier-Stokes equations in the three-dimensional half space under the no-slip boundary condition. 相似文献
496.
Wakisaka M Mitsui S Hirose Y Kawashima K Uchida H Watanabe M 《The journal of physical chemistry. B》2006,110(46):23489-23496
CO tolerance at pure Pt, Pt-Co, and Pt-Ru alloys was investigated by X-ray photoelectron spectroscopy combined with an electrochemical cell (EC-XPS) in order to discover a hint for designing higher performance anode catalysts. After the electrochemical stabilization and/or CO adsorption, these electrodes were immediately transferred to the XPS chamber without exposure to air to avoid contamination of the surfaces. It was revealed that alloying with Co or Ru modified the electronic structures of Pt atoms, resulting in a positive core level (CL) shift of Pt 4f(7/2) which could weaken the Pt-CO interaction. For the Pt-Co alloy electrode, the Pt 4f(7/2) CL shift remained after the electrochemical stabilization despite Co dissolution and formation of a Pt skin layer. Changes in surface core level shifts (DeltaSCLSs) induced by CO adsorption were evaluated and related to the CO adsorption energy. The values of DeltaSCLS at these alloys were smaller than that of pure Pt, indicating that Ru and Co are effective elements to weaken the bond strength of Pt-CO. 相似文献
497.
Yamamoto Y Koizumi T Katagiri K Furuya Y Danjo H Imamoto T Yamaguchi K 《Organic letters》2006,8(26):6103-6106
[Structure: see text] Bis(phosphine)boronium salts 3a-c were designed and prepared as key building blocks for the synthesis of highly congested diphosphinobenzenes. The preparation of sterically hindered ortho-phenylene-bridged diphosphines 1a-c was achieved by the reaction of the bis(phosphine)boronium salts 3a-c with difluorobenzenechromium complex 2 and subsequent removal of the BH2 group. The steric nature of diphosphine 1a was revealed in single-crystal X-ray analysis of its Rh complex. 相似文献
498.
Keiji Fushimi Kota Anzai Shinji Tokuyama Yoshikazu Kiriiwa Noriyuki Matsumoto Atsushi Sekiya Daisuke Hashizume Kazuo Nagasawa Hirofumi Hirai Hirokazu Kawagishi 《Tetrahedron》2012,68(4):1262-1265
Five novel compounds (1–3, 5, and 6), and two known ones (4 and 7) were isolated from the culture broth of Agrocybe praecox. Their structures were determined by the interpretation of spectroscopic data. Compounds 1–4 inhibited hypocotyl growth of lettuce, and 1, 3, and 4 inhibited the root growth. 相似文献
499.
Tetsuro Ito Masayoshi Oyama Hironao Sajiki Ryuichi Sawa Yoshikazu Takahashi Munekazu Iinuma 《Tetrahedron》2012,68(14):2950-2960
A rotational isomeric shoreaketone (1), identified as a skeletal member of resveratrol tetramers, was isolated from three species of Dipterocarpaceaeous plants: Shorea uliginosa, Shorea hemsleyana, and Vateria indica. The structure was elucidated by spectroscopic analysis including NMR experiments and their absolute configurations determined based on circular dichroism data. Shoreaketone has 10 asymmetric carbons and a framework of fused heptacyclic ring system including a spiro ring and an α,β-unsaturated carbonyl group that has not been reported in any other natural product. NMR experiments using shoreaketone indicate the presence of two conformers due to restricted rotation of a C–C bond in solution. The complex stereochemistry is due to its skeleton, 10 asymmetric carbons, and a chiral axis. The conformations of rotational isomeric stilbenoid were studied by variable-temperature NMR, ROESY, a skeletal conversion. The coexistence of two conformers for shoreaketone (1) was confirmed to be 1a and 1b, in which the diaryl-dihydrobenzofuran moiety (unit 1B) is extended below or above the plane of the cyclopentane ring (unit 1A), respectively. 相似文献
500.
T. Mizuguchi M. Yomosa N. Fujiwara M.U. Kobayashi 《The European Physical Journal B - Condensed Matter and Complex Systems》2012,85(7):1-8
We propose a method to detect the approach to a specific unstable symmetric mediating solution, which characterises the symmetry restoration process close to a bifurcation point of an attractor merging crisis. This method captures a temporary restoration of the symmetry, and it does not require neither the exact parameter value of the bifurcation point nor the mediating solution. We study a forced XY model as an example and show that this method figures out the singularity caused by the approach from the asymmetric side of the crisis. An analysis of the repulsively coupled Stuart Landau system suggests the feasibility of this method even when the mediating solution is a symmetric torus. 相似文献