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141.
In this paper we study a key example of a Hermitian symmetric space and a natural associated double flag variety, namely for the real symplectic group G and the symmetric subgroup L, the Levi part of the Siegel parabolic PS. We give a detailed treatment of the case of the maximal parabolic subgroups Q of L corresponding to Grassmannians and the product variety of G/PS and L/Q; in particular we classify the L-orbits here, and find natural explicit integral transforms between degenerate principal series of L and G.  相似文献   
142.
The deformation and breakup processes of a particle-cluster aggregate under shear flows are investigated by the two-phase lattice Boltzmann method. In the simulation the particle is modeled by a hard droplet with large viscosity and strong surface tension. The van der Waals attraction force is taken into account for the interaction between the particles. Also, the Brownian motion is considered for nano-particles. Two important dimensionless parameters are introduced in order to classify calculated results. One is the ratio of fluid force to the maximum inter-particle force, Y, and the other is the Péclet number which is the ratio of the rate of diffusion by a shear flow to the rate of diffusion by Brownian motion. It is found that Y is the key factor in dispersion and that the Brownian motion retards the dispersion.  相似文献   
143.
Ultrasound intensity microscopy was developed for in vivo imaging. This paper describes the preliminary results obtained using 300 MHz ultrasound intensity microscopy for in vitro characterization of cell cultures. The novelty of the approach lies in the fact that it allows remote, non-contact and disturbance-free imaging of cultured synovial cells and the changes in the cells’ properties due to external stimulants such as transforming growth factor beta-1 (TGF-β1). The intensity imaging method has potential for extracting mechanical cell properties and monitoring the effects of drugs.Ultrasound propagates through a thin specimen such as cultured cells and is reflected at the interface between the specimen and substrate. A two-dimensional distribution of the ultrasonic intensity, which is closely related to the mechanical properties, is visualized to analyze cell organs, such as the nucleus at the central part and the cytoskeleton at the peripheral zone. After stimulation with TGF-β1, the ultrasonic intensity at the actin zone was significantly increased compared with the control.  相似文献   
144.
A high-speed quantum key distribution system was developed with the wavelength-division multiplexing (WDM) technique and dedicated key distillation hardware engines. Two interferometers for encoding and decoding are shared over eight wavelengths to reduce the system's size, cost, and control complexity. The key distillation engines can process a huge amount of data from the WDM channels by using a 1 Mbit block in real time. We demonstrated a three-channel WDM system that simultaneously uses avalanche photodiodes and superconducting single-photon detectors. We achieved 12 h continuous key generation with a secure key rate of 208 kilobits per second through a 45 km field fiber with 14.5 dB loss.  相似文献   
145.
A solid state NMR method is presented for determination of a backbone dihedral angle φ in peptides, being based on the previously reported method, relayed anisotropy correlation (RACO) NMR [Y. Ishii et al., Chem. Phys. Lett. 256 (1996) 133]. In the present method, the and the dipolar tensors in the system are two-dimensionally (2D) correlated via polarization transfer from to under magic angle spinning (MAS). This method was applied to N-acetyl , -valine, and the H–C–N–H dihedral angle was determined to be 154.0±1.4° or 206.0±1.4°, the former agreeing with the X-ray value of 154±5°.  相似文献   
146.
Ground-state phase diagram of the one-dimensional bond-random S=1 Heisenberg antiferromagnet is investigated by means of the loop-cluster-update quantum Monte-Carlo method. The random couplings are drawn from a rectangular uniform distribution. We found that even in the case of extremely broad bond distribution, the magnetic correlation decays exponentially, and the correlation length is hardly changed; namely, the Haldane phase continues to be realized. This result is accordant with that of the exact-diagonalization study, whereas it might contradict the conclusion of an analytic theory founded in a power-law bond distribution instead. The latter theory predicts that a second-order phase transition occurs at a certain critical randomness, and the correlation length diverges for sufficiently strong randomness. Received: 31 March 1998 / Revised and Accepted: 7 July 1998  相似文献   
147.
Synthesis, structures, and magnetic properties of ternary rare earth oxides ALnO2 (A=Cu or Ag; Ln=rare earths) have been investigated. CuLnO2 (Ln=La, Pr, Nd, Sm, Eu) were synthesized by the direct solid state reaction of Cu2O and Ln2O3, and AgLnO2 (Ln=Tm, Yb, Lu) were obtained by the cation-exchange reaction of NaLnO2 and AgNO3 in a KNO3 flux. These compounds crystallized in the delafossite-type structure with the rhombohedral 3R type (space group: R-3m). Magnetic susceptibility measurements showed that these compounds are paramagnetic down to 1.8 K. Specific heat measurements down to 0.4 K indicated that CuNdO2 ordered antiferromagnetically at 0.8 K.  相似文献   
148.
Acid-base equilibria between 2,5-dichlorophenol (DCP) and various bases (LiOH, NaOH, and KOH) were studied in ambient to supercritical methanol, by measuring the absorption spectrum of DCP at alkali metal hydroxide molalities ranging up to 10 mmol⋅kg−1, at temperatures up to 250 °C and a pressure of 25.0 MPa. The spectrum was deconvoluted into contributions for the acidic (HA) and basic (A) forms of DCP, taking into account a blue shift of the phenolate (A) spectrum due to the effect of ion pairing with an alkali metal cation. Degrees of dissociation of DCP determined from the spectra suggested that the dissociation constant of DCP has a maximum around 150 °C, whereas that of KOH decreases with temperature. The phenolate-alkali metal ion pairing was examined from the peak shift of the phenolate spectrum in the presence of Li+, Na+, and K+. A smaller cation radius and higher temperature (thus a lower dielectric constant for methanol) give rise to stronger electrostatic interaction in the ion pair. The basicities of the alkali metal hydroxides in supercritical methanol were compared using DCP as an indicator, and were shown to follow the order LiOH < NaOH ≤ KOH. This order is the same as that for the catalytic effect of alkali metal hydroxides on the methylation of phenol in supercritical methanol (Takebayashi et al.: Ind. Eng. Chem. Res. 47:704–709, 2008). Electronic Supplementary Material  The online version of this article () contains supplementary material, which is available to authorized users.  相似文献   
149.
    
Organogallium and ‐indium compounds are useful reagents in organic synthesis because of their moderate stability, efficient reactivity and high chemoselectivity. Carbogallation and ‐indation of a carbon‐carbon multiple bond achieves the simultaneous formation of carbon‐carbon and carbon‐metal bonds. Heterogallation and ‐indation construct carbon‐heteroatom and carbon‐metal bonds. Therefore, these reaction systems represent a significant synthetic method for organogalliums and ‐indiums. Many chemists have attempted to apply various types of unsaturated compounds such as alkynes, alkenes, and allenes to these reaction systems. This minireview provides an overview of carboindation and ‐gallation as well as heteroindation and ‐gallation.  相似文献   
150.
    
Quadruply BN-fused tetrathia[8]circulenes were synthesized through four-fold electrophilic borylation. The single-crystal X-ray diffraction analysis revealed that the BN-fused tetrathia[8]circulene with peripheral phenyl groups exhibits crystal polymorphism, in which the circulene core adopts both planar and saddle conformations in the solid state. The experimental and theoretical studies revealed that the weaker aromaticity of azaborine compared with benzene renders the flexibility of the BN-fused tetrathia[8]circulenes.  相似文献   
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