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51.
Atsushi Takamizawa Kayoko Mishina Kenzo Hiraoka 《Journal of mass spectrometry : JMS》2012,47(2):221-225
Covalent bonds are often created by a reaction between chemicals and protein before causing various adverse effects in a cell. Dimethylaminoethyl methacrylate (DMAEMA), which has moderate toxicity, causes skin inflammation and throat irritation. For this study, we investigated a reaction mechanism between myoglobin and (DMAEMA) using a new analytical tool developed at our laboratory: laser spray mass spectrometry technique. It was found that initially DMAEMA was added to the amino group of protein by the Michael addition mechanism; the added DMAEMA was hydrolyzed to methacrylic acid using an autocatalytic system. The results of this study indicate the feasibility of the laser spray technique in analyses of reaction dynamics. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
52.
Mishina V. Yu. Abrashina I. V. Teleshev A. T. Vasyanina L. K. Nifant'ev E. E. 《Russian Journal of Organic Chemistry》2002,38(7):977-981
Phosphorous triamides react with aliphatic diols and dibasic phenols: 1,6-hexanediol, 2,2'-(4-hydroxyphenyl)propane, 1,4-hydroquinone, and 4,4'-dihydroxybiphenyl in the temperature range 80-110°C in diethylene glycol dimethyl ether or without a solvent to afford phosphorus-containing regular high-molecular products having an O2P(NR2) moiety in the monomeric unit. The resulting poly(phosphoramidites) are capable of swelling in organic solvents, and they can be used as macroligands in the catalytic hydrogenation of styrene over rhodium(I) complexes. 相似文献
53.
54.
Otani T Takayama J Sugihara Y Ishii A Nakayama J 《Journal of the American Chemical Society》2003,125(27):8255-8263
3,4-Di-tert-butylthiophene 1-oxide (1a) reacted with a series of electron-deficient alkenic dienophiles at its syn-pi-face relating to the S=O bond to give [4+2] adducts in excellent yields. The 1-oxide 1a also reacted even with angle-strained dienophiles acenaphthylene and norbornene at its syn-pi-face to afford [4+2] adducts; in the latter case, norbornene reacted exclusively at its exo-pi-face. The oxide 1a reacted with dimethyl acetylenedicarboxylate to produce dimethyl 4,5-di-tert-butylphthalate in high yield with spontaneous extrusion of SO from the initial adduct even at room temperature. Similarly, 3,4-di-tert-butylthiophene 1-(p-toluenesulfonyl)imide (3a) reacted with alkenic dienophiles at its syn-pi-face relating to the S=N bond to give [4+2] adducts in good yields. The reaction of 3a with 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) afforded a 1,2-thiazetidine 12a, the first example of S-unoxidized 1,2-thiazetidine, in good yield, through rearrangement of the initial [4+2] adduct. The molecular structure of 12a is discussed on the basis of the X-ray crystallographic analysis. Comparison of the foregoing reactions leads to the conclusion that the 1-oxide 1a is more reactive as a diene than the 1-imide 3a, which is more reactive than 3,4-di-tert-butylthiophene 1,1-dioxide. The origin of the syn-pi-face selectivities of 1a and 3a in Diels-Alder reactions is discussed in terms of the orbital mixing rule and steric effect and also based on B3LYP/6-31G(d) calculations. 相似文献
55.
Jun TakayamaSeiko Fukuda Yoshiaki SugiharaAkihiko Ishii Juzo Nakayama 《Tetrahedron letters》2003,44(28):5159-5162
Hetero Diels-Alder reactions of 3,4-di-tert-butylthiophene 1-oxide (1) with thioaldehydes and thioketones take place exclusively, except the reaction with thiobenzophenone, at the syn-π-face of 1 with respect to the SO bond. The π-face selectivity was explained in terms of the extent of conformational changes of 1 that are brought about in the process to the transition states. 相似文献
56.
Two oxinylporphyrins, 5-(8-hydroxy-5-quinolinyl)-10,15,20-( p -tolyl)- porphyrin ( 1 ) and 5,15-bis(8-hydroxy-5-quinolinyl)-10,20-bis( n -heptyl)-porphyrin ( 2 ), were prepared and coordinated with Ga(III) to afford tris(oxinato) complex 3 and poly(oxinato) complex 4 , respectively. The structure of 3 was analyzed by variable temperature NMR study with referring to tris(8-hydroxy-5-quinolinyl)Ga(III) complex 5 to be in a meridional form. Oxinato ligands of 3 and 5 were exchanged with one another, with keeping the meridional structure. UV-Vis and fluorescence spectra of tris(oxinato)complex 3 and poly(oxinato)complex 4 were compared with each monomeric compound 1 and 2 . The absorption spectra showed only a slight broadening of the Soret band, suggesting trivial electronic and excitonic interactions. The fluorescence intensity was increased significantly compared with each monomeric compound 1 and 2 . At the same time, efficient excitation energy transfer among three porphyrins has been observed. 相似文献
57.
Porphyrin macrocycles composed of five and six units of m-gable imidazolylporphyrinatozinc (1-Zn) were synthesized by self-assembled cyclization followed by ring-closing metathesis linkings. Each porphyrin macrocycle was isolated by GPC chromatography, and their molecular weights were determined by MALDI-TOF mass spectroscopy. These structures represent mimics of light-harvesting complexes in photosynthetic bacteria. [structure: see text] 相似文献
58.
Nomoto A Mitsuoka H Ozeki H Kobuke Y 《Chemical communications (Cambridge, England)》2003,(9):1074-1075
Introducing a porphyrin bearing electron acceptor onto a self-assembled monolayer (SAM) using a supramolecular method to form a hetero-dimer increased the photocurrent value compared with using porphyrin without an electron acceptor. 相似文献
59.
Kazuhiko Kandori Kazunao Hayashi Masaki Matsukawa Masao Fukusumi Yoshiaki Morisada 《Colloid and polymer science》2010,288(10-11):1071-1079
The shape and porosity of hematite particles, produced from a forced hydrolysis reaction of acidic FeCl3 solution, were controlled by using Pluronics as nonionic surfactants (0–4 wt.%). Pluronics possess a nominal formula of (PEO) x –(PPO) y –(PEO) x . The effect of Pluronics with low hydrophilicity (PEO contents were less than 50 mol%) was small and provided spherical particles the same as that of the system without Pluronics (control system). However, Pluronics with higher hydrophilicity (PEO contents were over 50 mol%) gave ellipsoidal hematite particles. This effect on the particle morphology was enhanced by an increase in their molecular weight. On the other hand, the Pluronics possessing an opposite nominal formula [(PPO) x –(PEO) y –(PPO) x ] exhibited no effect on the particle shape; it only depressed phase transformation from ?-FeOOH to hematite. Not only the morphology but also the pore size of hematite particles was controlled from nonporous to mesoporous by using Pluronics. The N2 adsorption experiment and t-plot curve analysis revealed that the hematite particles changed from mesoporous to microporous by an increase in the concentration of Pluronics. On the other hand, in the presence of very low amounts of Pluronics molecules (0.1 wt.%), nonporous hematite particles were produced via strong aggregation of PN particles by their hydrogen bonding between hydroxyl and PEO or PPO groups. The dynamic light scattering measurement for the system with Pluronics clarified the existence of polynuclear (PN) particles with a hydrodynamic particle diameter (D a) of ca. 40 nm after these were aged for 6 h. The size of PN particles remained constant at ca. 40 nm during aging time of 12 h~3 days, but the scattering intensity was decreased. This decrease in the scattering intensity reveals that the number of PN particles is reduced by aggregation. The transmission electron microscope, inductively coupled plasma atomic emission spectroscopy, and total organic carbon analysis measurements employed on the systems produced for ellipsoidal particles elucidated that the formation of ellipsoidal hematite particles is attributed to the adsorption of Pluronics on the surfaces of PN and growing hematite particles. 相似文献
60.
Suzhou Li Yoshiaki Kawajiri Jörg Raisch Andreas Seidel-Morgenstern 《Journal of chromatography. A》2010,1217(33):5349-5357
A new improvement based on outlet fractionation and feedback has been developed for simulated moving bed (SMB) chromatography. In this contribution, this fractionation and feedback SMB (FF-SMB) concept is extended to the general scenario which integrates a simultaneous fractionation of both outlet streams. A model-based optimization approach, previously adopted to investigate single fractionation, is extended to consider this flexible fractionation policy. Quantitative optimization studies based on a specific separation problem reveal that the double fractionation is the most efficient operating scheme in terms of maximum feed throughput, while the two existing single fractionation modes discussed in our previous study are also significantly superior to the conventional SMB operation. The advantages of the double fractionation extension are further demonstrated in terms of several more detailed performance criteria. In order to evaluate the applicability of the fractionation and feedback modification, the effect of product purity, adsorption selectivity, column efficiency and column number on the relative potential of FF-SMB over SMB is examined. 相似文献