两个三维柔性功能化双苯并咪唑金属N-杂环卡宾的合成和结构

由1,1'-双苄基-3,3'-氧双(亚乙基-2,1)-二苯并咪唑六氟磷酸盐(L1)和1,1'-双(吡啶-2-甲基)-3,3'-氧双(亚乙基-2,1)-二苯并咪唑六氟磷酸盐(L2)为配体合成了[Hg(C₃₂H₂₈N₄O)](CH₃COO)(PF₆)₂(1)和[NiCl(C₃₀H₂₈N₆O)](PF₆)₂(2),并对其进行了结构表征。配合物1是一个罕见的三价态Hg配合物,为单斜晶系P2₁/c空间群,配合物2为单斜晶系P2₁/n的配合物。1和2中存在O-H…F,C-H…F,C-H…Cl,C-H…π,P-F…π氢键作用和π-π堆积作用,并以此分别形成了3D超分子结构。     

Local leakage current behaviours of BiFeO3 films

The leakage current behaviours of polycrystalline BiFeO₃ thin films are investigated by using both conductive atomic force microscopy and current-voltage characteristic measurements. The local charge transport pathways are found to be located mainly at the grain boundaries of the films. The leakage current density can be tuned by changing the post-annealing temperature, the annealing time, the bias voltage and the light illumination, which can be used to improve the performances of the ferroelectric devices based on the BiFeO₃ films. A possible leakage mechanism is proposed to interpret the charge transports in the polycrystalline BiFeO₃ films.     

ICF中子发射时间诊断

 对ICF中子发射时间的诊断技术进行了研究,研制了基于快闪烁体和微通道板式光电倍增管的中子发射时间探测器。在某大型激光原型装置上进行了中子发射时间的实验测量,成功获得多发实验的中子发射时间与打靶激光脉冲的时间及中子发射时间之间的关系。实验结果表明：中子发射时间探测器对DT中子和DD中子都能够响应,中子产额测量下限达到10⁷,时间测量不确定度小于20 ps;CH烧蚀层越厚,中子发射时间越长。     

激光驱动气库靶对铝的准等熵压缩实验研究

利用激光驱动气库材料形成的等离子体射流对材料进行斜波加载, 可以获得高应变率的准等熵压缩. 在神光III 原型高功率激光装置上开展了激光驱动铝材料的准等熵压缩实验, 成像型速度干涉仪VISAR记录到样品自由面连续、光滑的速度历史, 采用反积分法得到60 GPa以上的峰值压强, 加载上升沿约10 ns,应变率可达10⁸ s ^-1, 并且观察到了压缩波在样品后表面的反射效应.     

应用大孔吸附树脂从农药废水中回收毕克草

毕克草为一种新型除草剂,通常情况下很难被降解,本文利用物理吸附原理通过自行制备的大孔吸附树脂从农药水中对其进行了回收,回收效果良好,同时也达到了废水处理的目的。优化的最佳实验条件:室温下,pH=1.0以及流速为5BV/h时,对COD为15000mg/L的毕克草废水吸附处理后,其出水可达《污水综合排放标准》(GB89—1996)中的一级排放标准;洗脱再生时,室温下,用95%的乙醇洗脱,流速为2BV/h,(即2倍树脂床体积/h)回收率可达98.4%,纯度达93.7%,总流程一次可处理该废水240mL。     

Bohmian mechanics to high-order harmonic generation

This paper introduces Bohmian mechanics (BM) into the intense laser-atom physics to study high-order harmonic generation. In BM, the trajectories of atomic electron in an intense laser field can be obtained with the Bohm--Newton equation. The power spectrum with the trajectory of an atomic electron is calculated, which is found to be irregular. Next, the power spectrum associated with an atom ensemble from BM is considered, where the power spectrum becomes regular and consistent with that from quantum mechanics. Finally, the reason of the generation of the irregular spectrum is discussed.     

Synthesis and properties of oxetane‐based polysiloxanes used for cationic UV curing coatings

The polysiloxanes end‐capped with oxetane group (PSiO‐H and PSiO‐L) were synthesized via hydrosilylation reaction based on α,ω‐dihydrogen‐terminated polydimethylsiloxanes with a higher (0.23%, PDSi‐H) and lower (0.12%, PDSi‐L) hydrogen amount. The molecular structures were characterized by FT‐IR and ¹H NMR spectroscopy. The polysiloxanes were added into a commercial oxetane‐based resin, 3,3′‐(oxydi(methylene)) bis(3‐ethyloxetane) (DOX), as an additive to prepare a series of cationic UV curable formulations. The photo‐DSC results showed that the maximum photopolymerization rate decreased while the oxetane conversion increased with the polysiloxane content increasing. The surface hydrophobic property of cured films was improved having the water contact angles of 97° and 99° compared with 82° of the cured DOX film with only 1 wt% PSiOs, respectively. The dynamic mechanical thermal analysis results showed that both the storage modulus on the rubbery plateau region and the glass transition temperature decreased with increasing PSiO‐H loading. Moreover, the decrease became more obvious as PSiO‐L was added instead of PSiO‐H due to its lower concentration of oxetane group. The thermal stability of cured films was enhanced by the addition of PSiOs from the thermogravimetric analysis. And the DOX/PSiO‐H film possessed higher thermal degradation temperatures than DOX/PSiO‐L film. Copyright © 2011 John Wiley & Sons, Ltd.     

一种视频图像规则圆目标的超分辨率位置测量方法

介绍了一种用于视频图像规则圆目标的超分辨率位置测量方法。分析了超分辨率测量的原理 ,并提出和完成了测量方案 ,取得了满意的结果。首先在目标静止时 ,连续采集多帧视频图像 ,通过叠加平均进行降噪 ;其次通过罗伯特微分算子进行边界探测 ,求出目标的大致位置 ;最后通过边界重心拟合法、边界圆拟合法和最小二乘法拟合求出目标的精确位置。理论分析和实验表明 ,完整圆目标时 ,测量精度可达 1/4像素 ;而当目标图像有缺陷时 ,边界圆拟合法和最小二乘法拟合测量误差增加较少 ,边界重心法的测量误差增加较多。在具体情况下 ,算法及参数应该作相应的调整