The study of the stability of aqueous three-phase fire-resistant foam in typical liquidus hydrocarbons

The utilization of solid particles in aqueous foam has a great potential in improving fire fighting efficiency. In this study, aqueous foam supported by micro fly-ash (FA) was prepared and its stability in a specific type of oil was characterized. Firstly, different amount of FA was added to study the influence of FA concentration on foamability. It showed that within a specific extent, foam expansion ratio increased with the increasing of FA concentration. And compared with conventional foams, oil resistance of FA stabilized foams, which was investigated by analyzing drainage rate and evolution process with a self-made apparatus, was remarkably improved when FA concentration exceed 4.8wt.%. Secondly, SiO₂ and Al₂O₃ particles with different median sizes were used to study the effect of particle size on stability. However, the smaller hydrophilic particles didn’t behave better as expected. Moreover, the foam stability in three hydrocarbons was evaluated in the same way. The results indicated that the short chain hydrocarbons had much stronger detrimental effect to both two-phase foam and three-phase foam. But overall, the three-phase foam stabilized by FA exhibited much better oil resistance, so it can be used as a promising material for pool fire extinguishing and prevention.GRAPHICAL ABSTRACT     

“One pot” homogeneous synthesis of thermoplastic cellulose acetate-graft-poly(l-lactide) copolymers from unmodified cellulose

Using native cellulose as the starting material, cellulose acetate-graft-ploy (l-lactide) (CA-g-PLA) copolymers were successfully synthesized by “one-pot” process in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). In this process, cellulose was first reacted with acetic anhydride, yielding cellulose acetate (CA), and then ring opening graft copolymerization of l-lactide was carried out from the residual hydroxyl groups of CA in the same solution using 4-dimethylaminopridine (DMAP) as the catalyst. Both acetyl and ploy (l-lactide) contents in CA-g-PLA copolymers could be well controlled by changing reaction conditions. The structures and thermal properties of CA-g-PLA copolymers were characterized. The glass transition temperature T_g of copolymers decreased with increasing PLA content. Compared to the pure PLA and cellulose-graft-PLA copolymers, the CA-g-PLA copolymers possessed better thermo mechanical properties in a temperature range of 60–130 °C. When the molar substitution of PLA (MS_PLA) was above 1.71, the CA-g-PLA copolymers exhibited thermoplastic behavior and could be processed by conventional thermal processing methods, such as injection molding and melt spinning.     

Low-molecular-weight photoresponsive supramulecular hydrogel based on a dicationic azobenzene-bridged pyridinium hydrogelator

Photoresponsive supramolecular hydrogel was fabricated from a small azobenzene-bridged dicationic pyridinium salt in the aqueous solution. The UV-vis light triggered reversible gel-sol transformation of such low-molecular-weight supramolecular hydrogel was systematically investigated through various analytical techniques.     

Electrochemical codeposited polypyrrole–tungsten oxide composite materials with wide potential windows

The three-dimensional morphology has sufficient interface contact and can be in favor of the electronic transport process. In this work, the demand for high-performance electrodes such as energy storage devices has been designed. Polypyrrole and tungsten oxide composite materials (PPy-WO₃) have been synthesized by cyclic voltammetry (CV) technology at −0.6 to 0.9 V versus saturated calomel electrode (SCE) for 20 cycles. The PPy-WO₃^{20 mV/s}, PPy-WO₃^{60 mV/s}, and PPy-WO₃^{120 mV/s} electrodes have been prepared by CV technology at sweep rates of 20, 60, and 120 mV/s. The influences of scan rate on morphologies and charge storage properties of the composites are discussed. Among them, a three-dimensional flake structure for PPy-WO₃^{20 mV/s} with a size of up to several micrometers was synthesized. PPy-WO₃^{20 mV/s} composites as electrode materials exhibit a wide charge storage potential window of 1.4 V (between −0.9 and 0.5 V vs. SCE) and a specific capacitance of 145.13 F/g at 1 mA/cm². Moreover, the long-term stability of PPy-WO₃^{20 mV/s} and PPy has been investigated in 5 M LiCl aqueous electrolyte. The stability of the materials can be improved by inorganic and organic composites.     

Effects of Self—coiling of Organic Molecules on Intramolecular Exciplex Formation and Fluoresscence Quenching in DX—H2O Solvent System

Effects of self-coiling of organic molecules on intramolecular exciplex formation of compound I,in which the carbazole chromophore and terephthalic acid methylester acceptor group are linked by one (CH2)10 chain,and the decrease of the fluorescence intensities of compounds Ⅱ，Ⅲ，and Ⅳ,in which the carbazole chromophore and 3,5-dinitrobenzoate are connected by one aliphatic chain of (CH2)10 (Ⅱ），（CH2）12（Ⅲ）,or (CH2)4(Ⅳ）,have been studied in the dioxane (DX)-H2O binary system.The results show that self-coiling of organic molecules in DX-H2O facilitates intramolecular exciplex formation of I and induces the decrease of fluorescence intensities of Ⅱ,bacause of the proximity effect brought about by selfcoiling of organic molecules under hydrophobic-lipophilic interaction(HLI) between the excited carbazole chromophore and the acceptor.Since the similar effects are observed even when the concentration of the probes are less than their CAgCs(critical aggregate concentrations )in the DX-H2O mixture with the same φ values,formation of the intermolecular exciplex has been excluded.The effects are found to be strongly depended on φ values,indication that they are mainly driven by HLI.The properties of the acceptors can also affect the intramolecular exciplex formation.With terephthalic acid methylester moiety as the acceptor,the carbazole chromophore exhibits the fluorescence spectra of the exciplex,while with 3,5-dinitrobenzoate moiety as the acceptor,only the fluorescence spectra of excited carbazolyl chromophore are observed.     

Headgroup effect on silane structures at buried polymer/silane and polymer/polymer interfaces and their relations to adhesion

Sum frequency generation (SFG) vibrational spectroscopy was used to study the effect of silane headgroups on the molecular interactions that occur between poly(ethylene terephthalate) (PET) and various epoxy silanes at the PET/silane and PET/silicone interfaces. Three different silanes were investigated: (3-glycidoxypropyl) trimethoxysilane (γ-GPS), (3-glycidoxypropyl) methyl-dimethoxysilane (γ-GPMS), and (3-glycidoxypropyl) dimethyl-methoxysilane (γ-GPDMS). These silanes share the same backbone and epoxy end group but have different headgroups. SFG was used to examine the interfaces between PET and each of these silanes, as well as silanes mixed with methylvinylsiloxanol (MVS). We also examined the interfaces between PET and uncured or cured silicone with silanes or silane-MVS mixtures. Silanes with different headgroups were found to exhibit a variety of methoxy group interfacial segregation and ordering behaviors at various interfaces. The effect of MVS was also dependent upon silane headgroup choice, and the interfacial molecular structures of silane methoxy headgroups were found to differ at PET/silane and PET/silicone interfaces. Epoxy silanes have been widely used as adhesion promoters for polymer adhesives; therefore, the molecular structures probed using SFG were correlated to adhesion testing results to understand the molecular mechanisms of silicone-polymer adhesion. Our results demonstrated that silane methoxy headgroups play important roles in adhesion at the PET/silicone interfaces. The presence of MVS can change interfacial methoxy segregation and ordering, leading to different adhesion strengths.     

Dummy molecularly imprinted polymers as the coating of stir bar for sorptive extraction of bisphenol A in tap water

A unique stir bar coated with dummy molecularly imprinted polymers for bisphenol A was prepared by sol-gel technique. The scanning electron microscopic image of the coating presented a homogeneous surface with a thickness of about 57 ± 2.5 μm. The Fourier transform infrared spectrum of the coating proved the incorporating of dummy molecularly imprinted polymers with the sol-gel network. When used to extract bisphenol A from aqueous solution containing bisphenol A and its three analogs (4-tert-butylphenol, 4,4'-dihydroxybiphenyl, and 3,3',5,5'-tetrabromo-bisphenol A). Dummy molecularly imprinted polymers-coated stir bar showed better selectivity than the bars coated with polydimethylsiloxane or non-imprinted polymers. The extraction conditions including stirring speed, pH, and extraction time were optimized. After back extraction with methanol, the extracts were analyzed by high-performance liquid chromatography-fluorescence detection. The linear range was 0.0228-0.456 ng/mL with correlation coefficient of 0.9994 and the detection limit was about 5.70 × 10(-3) ng/mL based on three times ratio of signal-to-noise. The method was applied to the determination of trace bisphenol A in tap water.     

新型苯并噁唑侧基聚酰亚胺的合成、结构与性能研究

为了改善聚酰亚胺的不溶不熔性, 一类可溶性苯并噁唑侧基聚酰亚胺树脂被成功制备. 从合成的新型二元胺单体出发, 制备了侧链为邻羟基苯胺酰胺结构的聚酰亚胺体系, 进一步催化环化邻羟基苯胺酰胺为苯并噁唑结构, 并对这两类不同结构的聚合物树脂进行了红外光谱的结构表征, 以及最终成膜的力学性能和耐热性能测试. 研究结果表明: 苯并噁唑侧基聚酰亚胺的力学性能优于相应的主链型聚酰亚胺, 且TGA分析表明, 其初始分解温度高达597 ℃, 有望用于航空航天方面高强、高模、耐高温的结构材料.     

磷酸二酯酶2 (PDE2)结构及其选择性抑制剂的研究进展

磷酸二酯酶2 (PDE2)主要分布在大脑、心脏细胞中, 作为潜在的药物靶标, 通过水解细胞内第二信使cAMP和cGMP, 对维持cAMP和cGMP的水平起着重要的作用, 其选择性抑制剂有望在内皮渗透性和改善记忆力等方面发挥作用. 综述了PDE2的组织分布、生理功能、催化区域和调节区域晶体结构的特点以及选择性的抑制剂. 最后, 根据药物设计发展的趋势对未来PDE2抑制剂的设计进行了展望.