Dynamic analysis of rotating double-tapered cantilever Timoshenko nano-beam using the nonlocal strain gradient theory

Based on the nonlocal strain gradient theory, the coupling nonlinear dynamic equations of a rotating double-tapered cantilever Timoshenko nano-beam are derived using the Hamilton principle. The equation of motion is discretized via the differential quadrature method. The effects of the angular velocity, nonlocal parameter, slenderness ratio, cross-section parameter, and taper ratios are examined and discussed. It is shown that taper ratios and cross-section parameter play a significant role in the vibration response of a rotating cantilever nano-beam. Further as rotational angular velocity increases, the taper ratios and cross-section parameter effect on the frequency response are increased for first modes of vibration.     

R~N上一类p(x)-Laplacian方程的无穷多解问题

该文主要讨论了如下p(x)-Laplacian算子方程的解.其中1P-≤p(x)≤P+N.得到了上述方程在变指数Sobolev空间W~(1,p(x))(R~N)中的一列能量值趋向正无穷的解.     

Functional perovskite hybrid of polyacetylene ammonium and lead bromide: Synthesis, light emission, and fluorescence imagining

A highly photoresponsive perovskite hybrid containing an electroactive organic component (H1) was fabricated. A disubstituted polyacetylene (PA) with a hidden amino functionality (P3) was synthesized, hydrolysis and quaternization of which afforded the desired PA ammonium salt (P5). Mixing P5 with lead bromide readily yielded H1, which was stable, soluble, and film-forming. The inorganic framework induced the polymer chains to align in an ordered fashion, which helped to populate the chain segments with long conjugation lengths. The hybrid emitted a blue light (457 nm) in a high quantum yield (62%), thanks to the enhanced electronic conjugation, the weakened interaction between the layer-segregated chains, and the efficient energy transfer from the inorganic sheets to the organic layers. P3 exhibited a half-discharge time as short as approximately 0.7 s, representing the first example of an efficient photoconductive disubstituted PA. While stable to normal light illumination, H1 was rapidly bleached upon exposure to high-power UV irradiation, enabling facile generation of two-dimensional luminescent photopatterns. After the UV irradiation, the emissions of P9 and P9/H12 were enhanced and weakened, respectively, proving that the inorganic perovskite framework works as a photocatalyst for accelerating the bleaching process of the conjugated PA chains.     

Existence of Nonnegative Solutions for a Class of Systems Involving Fractional(p,q)-Laplacian Operators

The authors study the following Dirichlet problem of a system involving fractional(p, q)-Laplacian operators:{(-△)_p~su=λa(x)|u|+~(p-2)u+λb(x)|u|~(α-2)|u|~βu+μ(x)/αδ|u|~(γ-2)|v|~δu in Ω,(-△)_p~su=λc(x)|v|+~(q-2)v+λb(x)|u|~α|u|~(β-2)v+μ(x)/βγ|u|~γ|v|~(δ-2)v in Ω,u=v=0 on R~N\Ω where λ 0 is a real parameter, ? is a bounded domain in RN, with boundary ?? Lipschitz continuous, s ∈(0, 1), 1 p ≤ q ∞, sq N, while(-?)s pu is the fractional p-Laplacian operator of u and, similarly,(-?)s qv is the fractional q-Laplacian operator of v. Since possibly p = q, the classical definitions of the Nehari manifold for systems and of the Fibering mapping are not suitable. In this paper, the authors modify these definitions to solve the Dirichlet problem above. Then, by virtue of the properties of the first eigenvalueλ_1 for a related system, they prove that there exists a positive solution for the problem when λ λ_1 by the modified definitions. Moreover, the authors obtain the bifurcation property when λ→λ_1~-. Finally, thanks to the Picone identity, a nonexistence result is also obtained when λ≥λ_1.     

一类新的宽间隔跳频码的实现

基于ＧＦ（Ｐ）上的ｍ序列,提出了一类新的宽间隔跳频码序列,并在计算机上进行了模拟研究．其模拟结果表明：该跳频码序列的相关性和游程特性均优于最佳的跳频码序列．     

铜含量对La2/3Sr1/3MnO3的电输运及磁电阻的影响

先用溶胶-凝胶法制备出La2/3Sr1/3MnO3的颗粒系统, 然后用化学的方法将Cu材料引入到La2/3Sr1/3MnO3的颗粒表面, 形成(1-x)La2/3Sr1/3MnO3/xCu (x≤0.05)的复合样品. 实验表明 Cu含量较低(x＜0.02)时, 复合样品电阻率较大, 仅在低温区表现出大的磁电阻效应, Cu含量较高(x＞0.025)时, 复合样品的电阻率较小(～10-2 Ω·cm), 在室温附近(270～300 K)、 3 T的磁场下, 表现出较大的不随温度变化的磁电阻效应～10%.     

锰基催化剂催化燃烧VOCs

锰基催化剂作为一种催化活性高、稳定性强、价格低廉的非贵金属类材料,在催化燃烧VOCs领域显示出了广阔的应用前景。然而,该材料存在表面电子传递能力弱,比表面积低等缺点须通过掺杂改性等方式得到优化。本文分别对单一锰氧化物、贵金属掺杂、负载以及钙钛矿型的锰基催化剂近年来从制备方法、催化剂的化学组分、形貌结构等方面提高催化剂活性的最新研究进展进行综述,并对锰基催化剂整体化、工业化的发展提出展望。     

miR-19b enhances osteogenic differentiation of mesenchymal stem cells and promotes fracture healing through the WWP1/Smurf2-mediated KLF5/β-catenin signaling pathway

Bone marrow mesenchymal stem cell (BMSC)-derived exosomes have been found to enhance fracture healing. In addition, microRNAs contributing to the healing of various bone fractures have attracted widespread attention in recent years, but knowledge of the mechanisms by which they act is still very limited. In this study, we clarified the function of altered microRNA-19b (miR-19b) expression in BMSCs in fracture healing. We modulated miR-19b expression via mimics/inhibitors in BMSCs and via agomirs in mice to explore the effects of these changes on osteogenic factors, bone cell mineralization and the healing status of modeled fractures. Through gain- and loss-of function assays, the binding affinity between miR-19b and WWP1/Smurf2 was identified and characterized to explain the underlying mechanism involving the KLF5/β-catenin signaling pathway. miR-19b promoted the differentiation of human BMSCs into osteoblasts by targeting WWP1 and Smurf2. Overexpression of WWP1 or Smurf2 degraded the target protein KLF5 in BMSCs through ubiquitination to inhibit fracture healing. KLF5 knockdown delayed fracture healing by modulating the Wnt/β-catenin signaling pathway. Furthermore, miR-19b enhanced fracture healing via the KLF5/β-catenin signaling pathway by targeting WWP1 or Smurf2. Moreover, miR-19b was found to be enriched in BMSC-derived exosomes, and treatment with exosomes promoted fracture healing in vivo. Collectively, these results indicate that mesenchymal stem cell-derived exosomal miR-19b represses the expression of WWP1 or Smurf2 and elevates KLF5 expression through the Wnt/β-catenin signaling pathway, thereby facilitating fracture healing.Subject terms: Diseases, Biotechnology     

IRC analysis of methanol carbonylation reaction catalyzed by rhodium complex

In the reaction cycle for methanol carbonylation catalyzed by Rh complex, the structure geometries of the reactant, intermediates, transition states and product of each elemental reaction have been studied by using the energy gradient method at HF/LANL2DZ level, and the changes of their potential profiles have also been calculated. Through IRC analyses of the transition states for each elemental reaction, it is confirmed that the various structure geometries obtained are stationary points on the cycle reaction pathway of methanol carbonylation catalyzed by Rh complex, and the changes are given in energies and structure geometries of the reactant molecules along the reaction pathway of lowest energy. It has been proposed that the geometrical conversions of intermediates play an important role during the cycle reaction. Through analyses of structure geometries, it has been suggested that, in addition to cis- and trans-structure exchange linkage of catalysis reactive species, the two pathways, cis- and tra     

Structural control of the photoluminescence of silole regioisomers and their utility as sensitive regiodiscriminating chemosensors and efficient electroluminescent materials

We synthesized a group of silole regioisomers 1(x,y), whose photoluminescence varied dramatically with its regiostructure. By internally hindering the intramolecular rotation, we succeeded in creating a novel silole (1(3,4)) that is strongly luminescent in solutions and whose fluorescence quantum yield in acetone is as high as 83%. We revealed that 1(3,4) was a sensitive chemosensor capable of optically discriminating nitroaromatic regioisomers of p-, o-, and m-nitroanilines. Against general belief, crystal formation of 1(2,4) blue-shifted its emission color and boosted its emission efficiency. The light-emitting diode based on the crystal of 1(2,4) emitted a strong blue light (464 nm) in a high current efficiency (5.86 cd/A).