利用电化学微分质谱在燃料电池的阴极研究碳载体的氧化

利用电化学微分质谱,在双薄层流动电解池中,通过检测二氧化碳产物的信号研究氧气与铂纳米粒子对碳载体氧化机理与动力学的影响．研究发现,碳载体可以在不同的电位区间内被氧化;氧气可以加速碳的氧化,在相同的电位下碳氧化生成二氧化碳产物的速率在氧气饱和溶液中是在氮气饱和溶液中的两倍;铂纳米粒子可以催化碳的氧化,在碳电极上,担载的铂纳米粒子可以大大降低碳氧化的过电势．讨论了铂与氧气促进碳氧化的机理．     

类铜离子的电子碰撞参数及其规律

用准相对论扭曲波方法系统地计算了Ｂａ、Ｎｄ、Ｇｄ、Ｙｂ、Ａｕ、Ｐｂ类铜离子组态能级之间的电子碰撞激发强度Ω（ｎｌ－ｎｌ），３≤ｎ≤７，４≤ｎ≤７，同时给出了高能极限的碰撞强度和外推到阈值的碰撞强度，用最小二乘样条方法拟合了全能域碰撞强度及热平均速率系数。对于一个激发过程，用１０个参数可以得到碰撞电子在任意能量下的碰撞强度以及任意温度下的速率系数。     

爆炸磁压缩发生器爆炸管运动研究

 报导了对爆炸磁压缩发生器(MFCG)的爆炸管进行的爆轰试验结果。用电子学方法测试了爆炸管采用的粉状RDX炸药的爆轰速度;采用高速分幅摄影方法,观测了爆炸管在管内RDX炸药爆轰产物驱动下的膨胀运动过程,测试了膨胀角、对称性和膨胀速度。试验表明,爆炸管在膨胀至 3倍初始半径内未发现破裂现象,其性能满足MFCG的设计要求。     

Molecular Dynamics Simulation of Temperature-dependent Flexibility of Thermophilic Xylose Isomerase

构建了嗜热栖热菌木糖异构酶与底物木糖的复合物模型,并运用NAMD2.5软件对其在300 和360 K下进行了10 ns的分子动力学模拟. 对该酶的回旋半径、亚基间相互作用及残基柔性进行了计算与统计分析,确定了该酶在360 K时柔性残基及区域. 研究发现与300 K相比,360 K时木糖异构酶中B-因子增幅较大的残基主要可分为两组：一组位于催化结构域,是由残基55～80组成的helex-loop-helix区域,另一组位于其亚基界面上. 研究表明高温下该酶催化结构域回旋半径增加,可能加速了活性中心的运动从而有利于D-木糖的异构化反应.在360 K时亚基界面上减少了8个氢键和5个离子对,这可能也是高温下其整体结构刚性下降并且活性升高的主要原因,该结果也对文献报道的该酶E372G突变体冷适应的实验现象进行了解释. 研究结果揭示了嗜热栖热菌木糖异构酶温度和结构柔性之间的关系.     

Retrieval of water cloud characteristic from active sensor data using the analytical solution of radiative transfer equation

An analytical forward model and numerical algorithm for retrieving the parameters of water cloud of earth atmosphere from optical measurements carried out by satellite-based lidars is presented. The forward model, based on the analytical solution of the radiative transfer equation, is used to fit the temporal profile of the laser light pulses backscattered from the cloud layers. The cloud parameters extracted from the analysis at each position on earth include the transport mean free path, the average radius of water drops, the density of drops, the scattering length, the scattering cross section, the anisotropy factor, and the altitude of top level of major clouds. Also estimated is the possible thickness of cloud layers. The efficacy of the approach is demonstrated by generating parameters of water cloud using the data collected by NASA's cloud-aerosol lidar and infrared pathfinder satellite observations (CALIPSO) satellite when it passed through North America on August 7, 2007.     

Bohmian mechanics to high-order harmonic generation

This paper introduces Bohmian mechanics (BM) into the intense laser-atom physics to study high-order harmonic generation. In BM, the trajectories of atomic electron in an intense laser field can be obtained with the Bohm--Newton equation. The power spectrum with the trajectory of an atomic electron is calculated, which is found to be irregular. Next, the power spectrum associated with an atom ensemble from BM is considered, where the power spectrum becomes regular and consistent with that from quantum mechanics. Finally, the reason of the generation of the irregular spectrum is discussed.     

Deep level transient spectroscopy investigation of deep levels in CdS/CdTe thin film solar cells with Te:Cu back contact

Deep levels in Cds/CdTe thin film solar cells have a potent influence on the electrical property of these devices. As an essential layer in the solar cell device structure, back contact is believed to induce some deep defects in the CdTe thin film. With the help of deep level transient spectroscopy (DLTS), we study the deep levels in CdS/CdTe thin film solar cells with Te:Cu back contact. One hole trap and one electron trap are observed. The hole trap H1, localized at E_v+0.128~eV, originates from the vacancy of Cd (V_Cd. The electron trap E1, found at E_c-0.178~eV, is considered to be correlated with the interstitial Cu_i⁼ in CdTe.     

Generation of millimeter-wave sub-carrier optical pulse by using cascaded all-pass cavities

A novel scheme is proposed to transform an ultra-short optical pulse to a millimeter-wave frequencymodulated pulse by using the cascaded all-pass cavities （APCs）. The envelope waveform of the generated pulse train is calculated, showing effective improvement by APC cascading. The extinction ratio is analyzed with different input pulses, different cavity reflectivities, and different cascading numbers. It is shown that the cascading does not introduce much effect on the extinction ratio. Two designs by using Gires-Tournois cavity and waveguide ring resonators are proposed to realize the cascaded APC.     

等离子体微带开关特性

 提出一种基于微放电等离子体的微带开关。它是以“时变等离子体”取代微带线射频微机电开关的“金属悬臂”,利用等离子体的导体或介质特性使电磁波沿其表面进行传输或截止,从而实现微带线上电磁波传输的动态控制。等离子体微带开关的基本结构包括用以隔断电磁波的微带间隙和产生片状等离子体的放电装置。放电产生时,电磁波因等离子体导体性通过开关,形成“开”状态;放电停止后,电磁波被微带间隙反射,形成“关”状态。利用CST软件仿真研究了等离子体开关特性,结果表明：这种开关的带宽由等离子体密度决定,隔离度由间隙决定,而工作插损与等离子体密度和电子碰撞频率有关。等离子体位形（宽度、厚度等）对于开关性能也非常重要。     

模拟研究碳纳米管的热稳定性质

运用分子动力学方法具体模拟研究单个碳纳米管（CNTs）在加热过程中的结构变化．选择多组不同结构的单壁碳纳米管（SWCNTs）和双壁碳纳米管（DWCNTs）作为研究对象,加热温度从室温开始到4000 K,压强保持为1 atm．结果表明单壁碳管中手性型结构热稳定性最好,其次是扶手椅型和锯齿型,当手性角相同时,直径大的热稳定性更高;对于双壁碳管,研究表明当双壁中至少之一为手性结构时其热稳定好,而内外壁均为锯齿结构的稳定性最差,该结果进一步支持了有关单壁碳管的结论;还从理论上探索了描述结构热稳定性的方式,并在键层 关键词： 单壁碳纳米管 双壁碳纳米管 分子动力学方法 热稳定性能